{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,18]],"date-time":"2026-09-18T19:14:49Z","timestamp":1789758889400,"version":"4.0.1"},"reference-count":49,"publisher":"Wiley","issue":"31","license":[{"start":{"date-parts":[[2021,6,30]],"date-time":"2021-06-30T00:00:00Z","timestamp":1625011200000},"content-version":"am","delay-in-days":365,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#am"},{"start":{"date-parts":[[2020,6,30]],"date-time":"2020-06-30T00:00:00Z","timestamp":1593475200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/100006132","name":"Office of Science","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100006132","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100006151","name":"Basic Energy Sciences","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100006151","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000015","name":"U.S. Department of Energy","doi-asserted-by":"publisher","award":["DE\u2010AC02\u201005CH11231"],"award-info":[{"award-number":["DE\u2010AC02\u201005CH11231"]}],"id":[{"id":"10.13039\/100000015","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100006132","name":"Office of Science","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100006132","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100006151","name":"Basic Energy Sciences","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100006151","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100006132","name":"Office of Science","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100006132","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100006151","name":"Basic Energy Sciences","doi-asserted-by":"publisher","award":["DE\u2010AC02\u201006CH11357"],"award-info":[{"award-number":["DE\u2010AC02\u201006CH11357"]}],"id":[{"id":"10.13039\/100006151","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100006134","name":"Office of Energy Efficiency and Renewable Energy","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100006134","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100006233","name":"National Renewable Energy Laboratory","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100006233","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000001","name":"National Science Foundation","doi-asserted-by":"publisher","award":["TG\u2010DMR970008S"],"award-info":[{"award-number":["TG\u2010DMR970008S"]}],"id":[{"id":"10.13039\/100000001","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000015","name":"U.S. Department of Energy","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100000015","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100006132","name":"Office of Science","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100006132","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100006151","name":"Basic Energy Sciences","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100006151","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Energy Materials"],"published-print":{"date-parts":[[2020,8]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The oxygen stacking of O3\u2010type layered sodium transition metal oxides (O3\u2010NaTMO\n                    <jats:sub>2<\/jats:sub>\n                    ) changes dynamically upon topotactic Na extraction and reinsertion. While the phase transition from octahedral to prismatic Na coordination that occurs at intermediate desodiation by transition metal slab gliding is well understood, the structural evolution at high desodiation, crucial to achieve high reversible capacity, remains mostly uncharted. In this work, the phase transitions of O3\u2010type layered NaTMO\n                    <jats:sub>2<\/jats:sub>\n                    at high voltage are investigated by combining experimental and computational approaches. An OP2\u2010type phase that consists of alternating octahedral and prismatic Na layers is directly observed by in situ X\u2010ray diffraction and high\u2010resolution scanning transmission electron microscopy. The origin of this peculiar phase is explained by atomic interactions involving Jahn\u2013Teller active Fe\n                    <jats:sup>4+<\/jats:sup>\n                    and distortion tolerant Ti\n                    <jats:sup>4+<\/jats:sup>\n                    that stabilize the local Na environment. The path\u2010dependent desodiation and resodiation pathways are also rationalized in this material through the different kinetics of the prismatic and octahedral layers, presenting a comprehensive picture about the structural stability of the layered materials upon Na intercalation.\n                  <\/jats:p>","DOI":"10.1002\/aenm.202001151","type":"journal-article","created":{"date-parts":[[2020,6,30]],"date-time":"2020-06-30T12:11:22Z","timestamp":1593519082000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":98,"title":["Direct Observation of Alternating Octahedral and Prismatic Sodium Layers in O3\u2010Type Transition Metal Oxides"],"prefix":"10.1002","volume":"10","author":[{"given":"Jae Chul","family":"Kim","sequence":"first","affiliation":[{"name":"Materials Sciences Division Lawrence Berkeley National Laboratory  Berkeley CA 94720 USA"},{"name":"Department of Chemical Engineering and Materials Science Stevens Institute of Technology  Hoboken NJ 07030 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Deok\u2010Hwang","family":"Kwon","sequence":"additional","affiliation":[{"name":"Materials Sciences Division Lawrence Berkeley National Laboratory  Berkeley CA 94720 USA"},{"name":"Department of Materials Science and Engineering University of California Berkeley  Berkeley CA 94720 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Julia H.","family":"Yang","sequence":"additional","affiliation":[{"name":"Materials Sciences Division Lawrence Berkeley National Laboratory  Berkeley CA 94720 USA"},{"name":"Department of Materials Science and Engineering University of California Berkeley  Berkeley CA 94720 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hyunchul","family":"Kim","sequence":"additional","affiliation":[{"name":"Materials Sciences Division Lawrence Berkeley National Laboratory  Berkeley CA 94720 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shou\u2010Hang","family":"Bo","sequence":"additional","affiliation":[{"name":"Materials Sciences Division Lawrence Berkeley National Laboratory  Berkeley CA 94720 USA"},{"name":"University of Michigan\u2010Shanghai Jiao Tong University Joint Institute Shanghai Jiao Tong University  Shanghai 200240 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lijun","family":"Wu","sequence":"additional","affiliation":[{"name":"Condensed Matter Physics and Materials Science Department Brookhaven National Laboratory  Upton NY 11973 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haegyeom","family":"Kim","sequence":"additional","affiliation":[{"name":"Materials Sciences Division Lawrence Berkeley National Laboratory  Berkeley CA 94720 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dong\u2010Hwa","family":"Seo","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering University of California Berkeley  Berkeley CA 94720 USA"},{"name":"Department of Energy Engineering Ulsan National Institute of Science and Technology (UNIST)  Ulsan 44919 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tan","family":"Shi","sequence":"additional","affiliation":[{"name":"Materials Sciences Division Lawrence Berkeley National Laboratory  Berkeley CA 94720 USA"},{"name":"Department of Materials Science and Engineering University of California Berkeley  Berkeley CA 94720 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jingyang","family":"Wang","sequence":"additional","affiliation":[{"name":"Materials Sciences Division Lawrence Berkeley National Laboratory  Berkeley CA 94720 USA"},{"name":"Department of Materials Science and Engineering University of California Berkeley  Berkeley CA 94720 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yimei","family":"Zhu","sequence":"additional","affiliation":[{"name":"Condensed Matter Physics and Materials Science Department Brookhaven National Laboratory  Upton NY 11973 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9275-3605","authenticated-orcid":false,"given":"Gerbrand","family":"Ceder","sequence":"additional","affiliation":[{"name":"Materials Sciences Division Lawrence Berkeley National Laboratory  Berkeley CA 94720 USA"},{"name":"Department of Materials Science and Engineering University of California Berkeley  Berkeley CA 94720 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2020,6,30]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201600943"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr500192f"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/0378-4363(80)90214-4"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/c1ee01782a"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1149\/1.1480135"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr020733x"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201200026"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201700189"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201912171"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2019.227064"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5EE01365H"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat3309"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.5b00594"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic102218w"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8EE02991A"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1149\/2.0271714jes"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5TA05769H"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1080\/10448639208218770"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b00164"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1007\/978-1-4419-7200-2"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1007\/978-1-4419-6533-2"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1007\/978-1-4419-7200-2"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1038\/am.2016.53"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja5115562"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.7b01542"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.aar6018"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201404549"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b05176"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.6b02440"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0167-2738(03)00106-1"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0378-7753(99)00349-3"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2015.12.027"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar200329r"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.56.1354"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.96.094102"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.100.035132"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevMaterials.3.015402"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.elecom.2014.10.003"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201803896"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6TA09220A"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.9b10352"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.63.224304"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9EE02803J"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.119.176402"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm501563f"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1088\/0953-8984\/19\/33\/335219"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.97.094111"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.93.045132"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.commatsci.2012.10.028"}],"container-title":["Advanced Energy Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Faenm.202001151","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/aenm.202001151","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/aenm.202001151","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/am-pdf\/10.1002\/aenm.202001151","content-type":"application\/pdf","content-version":"am","intended-application":"syndication"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/aenm.202001151","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,7]],"date-time":"2025-10-07T17:42:27Z","timestamp":1759858947000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/aenm.202001151"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2020,6,30]]},"references-count":49,"journal-issue":{"issue":"31","published-print":{"date-parts":[[2020,8]]}},"alternative-id":["10.1002\/aenm.202001151"],"URL":"https:\/\/doi.org\/10.1002\/aenm.202001151","archive":["Portico"],"relation":{},"ISSN":["1614-6832","1614-6840"],"issn-type":[{"value":"1614-6832","type":"print"},{"value":"1614-6840","type":"electronic"}],"subject":[],"published":{"date-parts":[[2020,6,30]]},"assertion":[{"value":"2020-04-01","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2020-06-30","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"2001151"}}