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Disordered rock\u2010salt (DRX) cathode materials, known for their high compositional flexibility, offer a unique opportunity in this regard. However, Fe\u2010rich DRX (Fe\u2010DRX) cathodes, potentially the most cost\u2010effective among all DRXs, have seen limited research interest due to their comparatively restrained performance. This limitation stems from the inaccessibility of the Fe\n                    <jats:sup>3+<\/jats:sup>\n                    \/Fe\n                    <jats:sup>4+<\/jats:sup>\n                    redox in the DRX structure, prompting the need for redox engineering to enable Fe\u2010DRXs with readily utilizable redox mechanisms. In this work, utilizing both experiments and theoretical study, reversible Fe\n                    <jats:sup>2+<\/jats:sup>\n                    \/Fe\n                    <jats:sup>3+<\/jats:sup>\n                    redox in an Fe\n                    <jats:sup>2+<\/jats:sup>\n                    \u2010based DRX cathode is demonstrated. This design minimizes the reliance on O redox, resulting in a high capacity (\u2248290 mAh\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) and energy density (\u2248700\u00a0Wh\u00a0kg\n                    <jats:sup>\u22121<\/jats:sup>\n                    ), as opposed to an Fe\n                    <jats:sup>3+<\/jats:sup>\n                    \u2010based DRX operating on the limited Fe\n                    <jats:sup>3+<\/jats:sup>\n                    \/Fe\n                    <jats:sup>4+<\/jats:sup>\n                    redox and extensive O redox upon cycling. Overall, the study introduces a novel approach to redox engineering to develop low\u2010cost, high\u2010performing Fe\u2010rich cathode materials.\n                  <\/jats:p>","DOI":"10.1002\/aenm.202400402","type":"journal-article","created":{"date-parts":[[2024,3,18]],"date-time":"2024-03-18T07:20:35Z","timestamp":1710746435000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":25,"title":["Redox Engineering of Fe\u2010Rich Disordered Rock\u2010Salt Li\u2010Ion Cathode Materials"],"prefix":"10.1002","volume":"14","author":[{"ORCID":"https:\/\/orcid.org\/0009-0009-6224-0986","authenticated-orcid":false,"given":"Richie","family":"Fong","sequence":"first","affiliation":[{"name":"Department of Mining and Materials Engineering McGill University  Montr\u00e9al QC H3A 0C5 Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5376-2944","authenticated-orcid":false,"given":"Nauman","family":"Mubarak","sequence":"additional","affiliation":[{"name":"Department of Mining and Materials Engineering McGill University  Montr\u00e9al QC H3A 0C5 Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sang\u2010Wook","family":"Park","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Korea Advanced Institute of Science and Technology (KAIST)  291 Daehak\u2010ro Daejeon 34141 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gregory","family":"Lazaris","sequence":"additional","affiliation":[{"name":"Department of Mining and Materials Engineering McGill University  Montr\u00e9al QC H3A 0C5 Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yiwei","family":"Liu","sequence":"additional","affiliation":[{"name":"Department of Mining and Materials Engineering McGill University  Montr\u00e9al QC H3A 0C5 Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rahul","family":"Malik","sequence":"additional","affiliation":[{"name":"Office of Energy Research and Development Natural Resources Canada  Ottawa ON K1A 0E4 Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7200-7186","authenticated-orcid":false,"given":"Dong\u2010Hwa","family":"Seo","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Korea Advanced Institute of Science and Technology (KAIST)  291 Daehak\u2010ro Daejeon 34141 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5705-6513","authenticated-orcid":false,"given":"Jinhyuk","family":"Lee","sequence":"additional","affiliation":[{"name":"Department of Mining and Materials Engineering McGill University  Montr\u00e9al QC H3A 0C5 Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,3,18]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2021.11.005"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1149\/1.1837571"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat2590"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.elecom.2004.11.008"},{"key":"e_1_2_8_5_1","volume-title":"Rechargeable Batteries: Materials, Technologies and New Trends","author":"Wu X. 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