{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,18]],"date-time":"2026-09-18T22:37:47Z","timestamp":1789771067150,"version":"4.0.1"},"reference-count":40,"publisher":"Wiley","issue":"48","license":[{"start":{"date-parts":[[2025,10,23]],"date-time":"2025-10-23T00:00:00Z","timestamp":1761177600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/4.0\/"}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Energy Materials"],"published-print":{"date-parts":[[2025,12]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Manganese\u2010based disordered rock\u2010salt (Mn\u2010DRX) cathodes provide high energy density and exceptional compositional tunability, which enables the rational design and discovery of advanced DRX chemistries. However, exploration across the vast Mn\u2010DRX design space remains hindered by the slow and energy\u2010intensive nature of traditional synthesis methods. Here, the Joule\u2010heating (JH) method is demonstrated to enable rapid and energy\u2010efficient synthesis of high\u2010performance Mn\u2010DRX cathodes. Through a case study of Li\n                    <jats:sub>1.2<\/jats:sub>\n                    Mn\n                    <jats:sub>0.4<\/jats:sub>\n                    Ti\n                    <jats:sub>0.4<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    (LMTO), we show that optimizing DRX materials under rapid synthesis requires controlling both nanoscale short\u2010range ordering (SRO) and microscale features such as bulk homogeneity and impurity phases, highlighting that microscale features are as critical as SRO. Based on this understanding, we show that a JH\u2010synthesized LMTO (annealed at 1050\u00a0\u00b0C just for 10 min) achieves a near\u2010phase\u2010pure DRX structure with uniform elemental distribution and reduced SRO compared to furnace\u2010synthesized LMTO (annealed at 950\u00a0\u00b0C for 12 h), leading to improved rate capability (161 vs 137 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 1 A\/g). Additionally, using the JH system, various DRX compositions are synthesized with electrochemical performance comparable to that of furnace\u2010synthesized counterparts, demonstrating its versatility. These findings demonstrate that rapid JH synthesis offers a robust approach to producing high\u2010performance Mn\u2010DRX cathodes, paving the way for high\u2010throughput discovery across the vast DRX design space.\n                  <\/jats:p>","DOI":"10.1002\/aenm.202503496","type":"journal-article","created":{"date-parts":[[2025,10,24]],"date-time":"2025-10-24T05:25:28Z","timestamp":1761283528000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["High\u2010Throughput Synthesis of Mn\u2010Based Disordered Rock\u2010Salt Li\u2010Ion Cathodes with Improved Rate Capability via Rapid Joule\u2010Heating"],"prefix":"10.1002","volume":"15","author":[{"ORCID":"https:\/\/orcid.org\/0009-0004-7461-2541","authenticated-orcid":false,"given":"Sang\u2010Wook","family":"Park","sequence":"first","affiliation":[{"name":"Department of Materials Science and Engineering Korea Advanced Institute of Science and Technology (KAIST)  Daejeon 34141 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hojoon","family":"Kim","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Korea Advanced Institute of Science and Technology (KAIST)  Daejeon 34141 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sangwook","family":"Han","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Seoul National University  Seoul 08826 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kyoung Sun","family":"Kim","sequence":"additional","affiliation":[{"name":"Neutron Science Division Korea Atomic Energy Research Institute (KAERI)  Daejeon 34057 Republic of Korea"},{"name":"Department of Chemical and Biological Engineering Korea University  Seoul 02841 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"You\u2010Yeob","family":"Song","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Korea Advanced Institute of Science and Technology (KAIST)  Daejeon 34141 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hyun\u2010Gi","family":"Lee","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Korea Advanced Institute of Science and Technology (KAIST)  Daejeon 34141 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wonyoung","family":"Jang","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Korea Advanced Institute of Science and Technology (KAIST)  Daejeon 34141 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dae\u2010Hyung","family":"Lee","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Korea Advanced Institute of Science and Technology (KAIST)  Daejeon 34141 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Seongjae","family":"Bae","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Korea Advanced Institute of Science and Technology (KAIST)  Daejeon 34141 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dongwoo","family":"Kim","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Korea Advanced Institute of Science and Technology (KAIST)  Daejeon 34141 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jungwoo","family":"Park","sequence":"additional","affiliation":[{"name":"Energy Materials R&amp;D Laboratories N.E.X.T Hub, POSCO Holdings  100 Songdogwahak\u2010ro, Yeonsu\u2010gu Incheon 21985 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Inchul","family":"Park","sequence":"additional","affiliation":[{"name":"Energy Materials R&amp;D Laboratories N.E.X.T Hub, POSCO Holdings  100 Songdogwahak\u2010ro, Yeonsu\u2010gu Incheon 21985 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sang\u2010Cheol","family":"Nam","sequence":"additional","affiliation":[{"name":"Energy Materials R&amp;D Laboratories N.E.X.T Hub, POSCO Holdings  100 Songdogwahak\u2010ro, Yeonsu\u2010gu Incheon 21985 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hyungsub","family":"Kim","sequence":"additional","affiliation":[{"name":"Neutron Science Division Korea Atomic Energy Research Institute (KAERI)  Daejeon 34057 Republic of Korea"},{"name":"Advanced Energy Research Institute Chungbuk National 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Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7200-7186","authenticated-orcid":false,"given":"Dong\u2010Hwa","family":"Seo","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Korea Advanced Institute of Science and Technology (KAIST)  Daejeon 34141 Republic of 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