{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,5]],"date-time":"2026-08-05T00:49:10Z","timestamp":1785890950048,"version":"3.56.0"},"reference-count":54,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,3,6]],"date-time":"2026-03-06T00:00:00Z","timestamp":1772755200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/4.0\/"},{"start":{"date-parts":[[2026,3,6]],"date-time":"2026-03-06T00:00:00Z","timestamp":1772755200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100014364","name":"Samsung Science and Technology Foundation","doi-asserted-by":"publisher","award":["SRFC\u2010MA2102\u201003"],"award-info":[{"award-number":["SRFC\u2010MA2102\u201003"]}],"id":[{"id":"10.13039\/501100014364","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Energy Materials"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Research into halide solid electrolytes has intensified due to their high ionic conductivity, oxidation stability and ductility, yet their close\u2010packed anion frameworks offer limited structural tunability, hindering further enhancement of bulk Li\n                    <jats:sup>+<\/jats:sup>\n                    conduction. Here, we demonstrate a universal bulk oxygen incorporation strategy for halide solid electrolytes, using WO\n                    <jats:sub>2<\/jats:sub>\n                    Cl\n                    <jats:sub>2<\/jats:sub>\n                    to enable controlled introduction of oxygen into diverse Li\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    MCl\n                    <jats:sub>6<\/jats:sub>\n                    (M = Zr, Y, Er, and In) lattices, effectively enhancing Li\n                    <jats:sup>+<\/jats:sup>\n                    conduction. Complementary structural, spatial, and vibrational analyses, including synchrotron X\u2010ray techniques, depth\u2010resolved spectroscopy, and Raman measurements, confirm oxygen incorporation via the [WO\n                    <jats:sub>2<\/jats:sub>\n                    Cl\n                    <jats:sub>4<\/jats:sub>\n                    ]\n                    <jats:sup>2\u2212<\/jats:sup>\n                    polyhedral unit, validating the structural integrity of the modified halides. First\u2010principles calculations reveal that the anchored oxygen flattens the Li\n                    <jats:sup>+<\/jats:sup>\n                    migration energy landscape by diversifying Li sites and weakening Li\u2013Cl interactions, accounting for the observed conductivity enhancement. In addition, the alleviation of the thermodynamic driving force for hydrolysis improves air and moisture stability, and the enhancement in ionic conductivity leads to improved electrochemical performance. These oxygen\u2010anchored oxychlorides offer lattice\u2010level regulation principles that underpin conventional halide design, ensuring both practicality and broad applicability.\n                  <\/jats:p>","DOI":"10.1002\/aenm.202506744","type":"journal-article","created":{"date-parts":[[2026,3,8]],"date-time":"2026-03-08T21:13:10Z","timestamp":1773004390000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Universal Oxychlorination Strategy in Halide Solid Electrolytes for All\u2010Solid\u2010State Batteries"],"prefix":"10.1002","author":[{"given":"Jae\u2010Seung","family":"Kim","sequence":"first","affiliation":[{"name":"Department of Materials Science and Engineering Korea Advanced Institute of Science and Technology  Daejeon Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Heeju","family":"Park","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Korea Advanced Institute of Science and Technology  Daejeon Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hae\u2010Yong","family":"Kim","sequence":"additional","affiliation":[{"name":"Department of Energy and Materials Engineering Dongguk University  Seoul Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Eunryeol","family":"Lee","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering Chungbuk National University  Cheongju Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Heewon","family":"Kim","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Korea Advanced Institute of Science and Technology  Daejeon Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Soeul","family":"Lee","sequence":"additional","affiliation":[{"name":"Department of Energy and Materials 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