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In this study, we reveal a counterintuitive yet constructive role of trace water in enhancing ion transport in a gallium\u2010based pliable halide solid electrolyte. Controlled exposure of 2LiCl\u2013GaF\n                    <jats:sub>3<\/jats:sub>\n                    to trace amounts of water introduces oxygen into the structure and reorganizes the local environments around gallium and lithium. This oxygen\u2010driven structural reconfiguration forms Ga\u2013O and Li\u2013O linkages and diversifies the local environment of gallium by converting its coordination from sixfold to fourfold. It reduces the average Li\u2013anion binding strength and flattens the Li\u2010ion migration energy landscape, resulting in enhanced Li\u2010ion transport. These changes collectively increase the ionic conductivity by more than two orders of magnitude, from 10\n                    <jats:sup>\u22122<\/jats:sup>\n                    mS cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    to over 3 mS cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    , while imparting amorphous and deformable characteristics to the 2LiCl\u2010GaF\n                    <jats:sub>3<\/jats:sub>\n                    electrolyte. This study demonstrates that the interaction between trace water and complex anion frameworks can be harnessed to simultaneously tailor structural and transport properties, offering a new design strategy for high\u2010performance oxyhalide solid electrolytes.\n                  <\/jats:p>","DOI":"10.1002\/aenm.202506748","type":"journal-article","created":{"date-parts":[[2026,3,16]],"date-time":"2026-03-16T05:25:21Z","timestamp":1773638721000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Oxygen\u2010Driven Structural Reorganization by Trace Water Enabling Fast Li\u2010Ion Transport in a Pliable Solid Electrolyte"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0009-0001-1916-4609","authenticated-orcid":false,"given":"Youngkyung","family":"Kim","sequence":"first","affiliation":[{"name":"Department of Materials Science and Engineering Seoul National University (SNU)  Seoul Republic of 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