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Here, we report a self\u2010supported, noble\u2010metal\u2010free Fe\n                    <jats:sub>3<\/jats:sub>\n                    C\/Fe\n                    <jats:sub>3<\/jats:sub>\n                    N@C catalyst, composed of earth\u2010abundant Fe, C, and N, featuring defect\u2010rich Fe\n                    <jats:sub>3<\/jats:sub>\n                    C\/Fe\n                    <jats:sub>3<\/jats:sub>\n                    N Janus nanostructures confined within graphitic carbon. The catalyst achieves an NH\n                    <jats:sub>3<\/jats:sub>\n                    yield rate of 468.3 \u00b5mol h\n                    <jats:sup>\u22121<\/jats:sup>\n                    cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    with a Faradaic efficiency of 94.2% at \u22120.6 V versus RHE, placing it among the most efficient reported NORR electrocatalysts. Mechanistic studies reveal that the graphitic carbon shell facilitates NO diffusion by alleviating the steric and dynamic constraints imposed by the hydrogen\u2010bonded water network. At the Janus interface, Fe\n                    <jats:sub>3<\/jats:sub>\n                    C sites preferentially adsorb and activate NO, whereas nitrogen\u2010vacancy\u2010rich Fe\n                    <jats:sub>3<\/jats:sub>\n                    N sites promote H\n                    <jats:sub>2<\/jats:sub>\n                    O dissociation to supply reactive *H for subsequent hydrogenation. This spatial coupling of mass\u2010transfer promotion, NO activation, and interfacial *H generation enables efficient and selective NO\u2010to\u2010NH\n                    <jats:sub>3<\/jats:sub>\n                    electroreduction. These findings establish carbon\u2010confined, earth\u2010abundant carbide\/nitride Janus interfaces as a promising design principle for high\u2010performance NORR catalysts.\n                  <\/jats:p>","DOI":"10.1002\/anie.1030679","type":"journal-article","created":{"date-parts":[[2026,7,24]],"date-time":"2026-07-24T10:33:25Z","timestamp":1784889205000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Carbon\u2010Confined Fe\n                    <sub>3<\/sub>\n                    C\/Fe\n                    <sub>3<\/sub>\n                    N Janus Interfaces for Selective Nitric Oxide\u2010to\u2010Ammonia Electroreduction"],"prefix":"10.1002","volume":"65","author":[{"given":"Jialing","family":"Song","sequence":"first","affiliation":[{"name":"Department of Chemistry International Joint Laboratory of Catalytic Chemistry State Key Laboratory of Materials for Advanced Nuclear Energy Innovation Institute of Carbon Neutrality College of Sciences Shanghai University  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ziqi","family":"Wei","sequence":"additional","affiliation":[{"name":"Department of Chemistry International Joint Laboratory of Catalytic Chemistry State Key Laboratory of Materials for Advanced Nuclear Energy Innovation Institute of Carbon Neutrality College of Sciences Shanghai University  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haotian","family":"Huang","sequence":"additional","affiliation":[{"name":"Department of Chemistry International Joint Laboratory of Catalytic Chemistry State Key Laboratory of Materials for Advanced Nuclear Energy Innovation Institute of Carbon Neutrality College of Sciences Shanghai University  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lupeng","family":"Han","sequence":"additional","affiliation":[{"name":"Department of Chemistry International Joint 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