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Here, scanning electrochemical cell microscopy coupled with fast scan cyclic voltammetry (FSCV) is used to resolve Zn plating and stripping on single\u2010crystal (002), (100), and (101) surfaces. Meniscus\u2010confined measurements reveal facet\u2010dependent branch\u2010specific apparent zero\u2010current potentials and apparent exchange current densities,\n                    <jats:italic>j<\/jats:italic>\n                    <jats:sub>0<\/jats:sub>\n                    , with the kinetic ordering\n                    <jats:italic>j<\/jats:italic>\n                    <jats:sub>0<\/jats:sub>\n                    (100) &gt;\n                    <jats:italic>j<\/jats:italic>\n                    <jats:sub>0<\/jats:sub>\n                    (101) &gt;\n                    <jats:italic>j<\/jats:italic>\n                    <jats:sub>0<\/jats:sub>\n                    (002) for both plating and stripping. This ordering is reproduced across independently prepared electrodes and retained over different scan rates and aqueous electrolytes. Beyond charge transfer, Zn removal and regrowth are strongly crystallographically encoded: dissolution footprints preserve the symmetry of the parent facets, while potentiostatically deposited Zn adopts substrate\u2010dependent growth geometries. These coupled kinetic and morphological differences translate directly to battery performance. Despite its slower apparent kinetics, the close\u2010packed, low\u2010energy (002) facet exhibits the longest cycling life in Zn\/Zn symmetric cells and substantially improved capacity retention in both polyaniline\/Zn and Na\n                    <jats:sub>0.33<\/jats:sub>\n                    V\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>5<\/jats:sub>\n                    \/Zn full cells, whereas the faster (100) and (101) interfaces fail earlier. These findings establish a facet\u2010dependent kinetics\u2013stability trade\u2010off and show that durable Zn anodes require coordinated control of charge transfer, dissolution topology, and crystallographic reconstruction.\n                  <\/jats:p>","DOI":"10.1002\/anie.1058773","type":"journal-article","created":{"date-parts":[[2026,10,15]],"date-time":"2026-10-15T03:58:30Z","timestamp":1792036710000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Crystallography\u2010Dependent Plating\/Stripping Kinetics and Interfacial Morphologies in Zn Metal Anodes"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-7746-0409","authenticated-orcid":false,"given":"Ziqing","family":"Wang","sequence":"first","affiliation":[{"name":"Department of Chemistry The University of Texas at Austin  Austin Texas USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Debasree","family":"Mandal","sequence":"additional","affiliation":[{"name":"Department of Chemistry The University of Texas at Austin  Austin Texas USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Iv\u00e1n El\u00edas","family":"Mondaca\u2010Medina","sequence":"additional","affiliation":[{"name":"Department of Chemistry The University of Texas at Austin  Austin Texas USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kenta","family":"Kawashima","sequence":"additional","affiliation":[{"name":"Department of Chemistry The University of Texas at Austin  Austin Texas USA"},{"name":"Department of Chemistry University of Utah  Salt Lake City Utah USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1767-0575","authenticated-orcid":false,"given":"Rinish Reddy","family":"Vaidyula","sequence":"additional","affiliation":[{"name":"Department of Chemistry The University of Texas at Austin  Austin Texas USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1030-4801","authenticated-orcid":false,"given":"Charles Buddie","family":"Mullins","sequence":"additional","affiliation":[{"name":"Department of Chemistry The University of Texas at Austin  Austin Texas USA"},{"name":"McKetta Department of Chemical Engineering The University of Texas at Austin  Austin Texas USA"},{"name":"Allen J. Bard Center for Electrochemistry The University of Texas at Austin  Austin Texas USA"},{"name":"Texas Materials Institute The University of Texas at Austin  Austin Texas USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hang","family":"Ren","sequence":"additional","affiliation":[{"name":"Department of Chemistry The University of Texas at Austin  Austin Texas USA"},{"name":"Allen J. Bard Center for Electrochemistry The University of Texas at Austin  Austin Texas USA"},{"name":"Texas Materials Institute The University of Texas at Austin  Austin Texas USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kent J. X.","family":"Zheng","sequence":"additional","affiliation":[{"name":"McKetta Department of Chemical Engineering The University of Texas at Austin  Austin Texas USA"},{"name":"Allen J. Bard Center for Electrochemistry The University of Texas at Austin  Austin Texas USA"},{"name":"Texas Materials Institute The University of Texas at Austin  Austin Texas USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,10,14]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202522157"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c21500"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.5c03711"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202303550"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4EE02264E"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2021.134032"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.55713\/jmmm.v34i2.2009"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202518262"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c09524"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c05027"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202504965"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202207751"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202509963"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202401293"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202403995"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/sstr.202400325"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202517845"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/batt.202400727"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/batt.70326"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202304003"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202407881"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40820\u2010024\u201001337\u20100"},{"key":"e_1_2_8_24_1","volume-title":"Electrochemical Methods: Fundamentals and Applications","author":"Bard A. 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