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Herein, we successfully synthesized a series of high\u2010nuclearity MB clusters,\n                    <jats:bold>\n                      S\n                      <jats:sub>2<\/jats:sub>\n                      Mo\n                      <jats:sub>62<\/jats:sub>\n                    <\/jats:bold>\n                    ,\n                    <jats:bold>\n                      SMo\n                      <jats:sub>53<\/jats:sub>\n                      W\n                      <jats:sub>7<\/jats:sub>\n                    <\/jats:bold>\n                    ,\n                    <jats:bold>\n                      Mo\n                      <jats:sub>50<\/jats:sub>\n                      W\n                      <jats:sub>8<\/jats:sub>\n                    <\/jats:bold>\n                    , and\n                    <jats:bold>\n                      Mo\n                      <jats:sub>44<\/jats:sub>\n                      W\n                      <jats:sub>8<\/jats:sub>\n                    <\/jats:bold>\n                    , which exhibit regular lacunary variation. More importantly, such structural variation endows these MB clusters with distinct Lewis acidity and redox properties. Consequently, when employed as heterogeneous photocatalysts for the chemodivergent C\u2500C coupling reactions between 1,3\u2010diketones and alkenes, the hexa\u2010lacunary\n                    <jats:bold>\n                      Mo\n                      <jats:sub>50<\/jats:sub>\n                      W\n                      <jats:sub>8<\/jats:sub>\n                    <\/jats:bold>\n                    and\n                    <jats:bold>\n                      Mo\n                      <jats:sub>44<\/jats:sub>\n                      W\n                      <jats:sub>8<\/jats:sub>\n                    <\/jats:bold>\n                    with more Lewis acid sites can achieve a 93% 1,5\u2010diketone yield within 12\u00a0h, while parent\n                    <jats:bold>\n                      S\n                      <jats:sub>2<\/jats:sub>\n                      Mo\n                      <jats:sub>62<\/jats:sub>\n                    <\/jats:bold>\n                    with superior oxygen activation can achieve a 99% 1,4\u2010diketone yield within 3\u00a0h. Furthermore,\n                    <jats:bold>\n                      Mo\n                      <jats:sub>50<\/jats:sub>\n                      W\n                      <jats:sub>8<\/jats:sub>\n                    <\/jats:bold>\n                    enables gram\u2010scale and sunlight driven synthesis of diverse 1,5\u2010diketone, and maintains long\u2010term cycling stability over 370\u00a0h (16 cycles). This work represents the first report of high\u2010nuclearity MB clusters with regular lacunary variation, and extends their application to sunlight driven photocatalytic C\u2500C coupling reaction, highlighting the innovative research of MB clusters.\n                  <\/jats:p>","DOI":"10.1002\/anie.1160992","type":"journal-article","created":{"date-parts":[[2026,5,4]],"date-time":"2026-05-04T11:50:14Z","timestamp":1777895414000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Lacunary Evolution of Molybdenum Blue Clusters for Efficient and Sustainable Photocatalytic Chemodivergent C\u2500C Coupling Reactions"],"prefix":"10.1002","volume":"65","author":[{"given":"Yi","family":"Kuang","sequence":"first","affiliation":[{"name":"Guangdong Provincial Key Laboratory of Carbon Dioxide Resource Utilization School of Chemistry South China Normal University  Guangzhou P. R. 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