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Herein, we demonstrate that photoactivated PtO\n                    <jats:sub>2<\/jats:sub>\n                    enables regenerable and highly selective PDH over a PtO\n                    <jats:sub>2<\/jats:sub>\n                    \/Pt\n                    <jats:sub>1<\/jats:sub>\n                    \u2010In\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    catalyst under mild conditions. Under simulated sunlight without external heating, the catalyst achieves a propylene formation rate of 1322.35\u00a0\u00b5mol g\n                    <jats:sup>\u22121<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    with unity selectivity, while remaining inactive under comparable thermocatalytic conditions. In situ spectroscopic analyses combined with density functional theory calculations reveal a photoactivated dual\u2010site mechanism, in which PtO\n                    <jats:sub>2<\/jats:sub>\n                    nanoparticles function as oxidation centers for hole\u2010driven C\u2500H bond activation, whereas neighboring interfacial Pt single atoms act as electron\u2010accepting sites to promote H\n                    <jats:sub>2<\/jats:sub>\n                    evolution, enabling efficient spatial separation and utilization of photogenerated charge carriers. Catalyst deactivation arises from partial reduction of PtO\n                    <jats:sub>2<\/jats:sub>\n                    , which can be exactly regenerated via a facile oxidative annealing process in air, affording excellent reusability. These findings identify photoactivated PtO\n                    <jats:sub>2<\/jats:sub>\n                    as a distinct active phase for selective PDH and provide a design principle for solar\u2010driven alkane valorization.\n                  <\/jats:p>","DOI":"10.1002\/anie.1300481","type":"journal-article","created":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T05:05:58Z","timestamp":1790658358000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Cooperation of PtO\n                    <sub>2<\/sub>\n                    and Adjacent Pt\n                    <sub>1<\/sub>\n                    on In\n                    <sub>2<\/sub>\n                    O\n                    <sub>3<\/sub>\n                    Photocatalysts for Unity\u2010Selective Propane Dehydrogenation"],"prefix":"10.1002","author":[{"given":"Jia","family":"Zhou","sequence":"first","affiliation":[{"name":"State Key Laboratory of Chemistry for NBC Hazards Protection State Key Laboratory of Photocatalysis on Energy and Environment College of Chemistry Fuzhou University  Fuzhou P. 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