{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T14:29:10Z","timestamp":1786976950965,"version":"build-2736575974"},"reference-count":22,"publisher":"Wiley","issue":"31","license":[{"start":{"date-parts":[[2026,5,30]],"date-time":"2026-05-30T00:00:00Z","timestamp":1780099200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,5,30]],"date-time":"2026-05-30T00:00:00Z","timestamp":1780099200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22579005"],"award-info":[{"award-number":["22579005"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,7,27]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Photocatalytic carbon\u2013nitrogen (C\u2013N) coupling of biomass\u2010derived alcohols and inorganic nitrogen sources provides a sustainable route to high\u2010value amines but is often limited by inefficient C\u2013H activation and uncontrollable nitrogen conversion kinetics. Herein, we report a synergistic redox pathway integrating anaerobic alcohol dehydrogenation and imine hydrogenation, enabled by an atomically dispersed Au species coordinated with three foreign phosphorus atoms on CdS nanorods (AuP\n                    <jats:sub>3<\/jats:sub>\n                    \u2010CdS). In situ spectroscopy and theoretical calculations elucidate that Au\u2013P\n                    <jats:sub>3<\/jats:sub>\n                    sites boost charge separation and enable both alcohol dehydrogenation and imine hydrogenation with optimal reaction energies compared to the conventional Au species coordinated with three intrinsic sulfur atoms on CdS nanorods (AuS\n                    <jats:sub>3<\/jats:sub>\n                    \u2010CdS). These characteristics enable AuP\n                    <jats:sub>3<\/jats:sub>\n                    \u2010CdS to achieve a furfurylamine production rate of 41.48 mmol g\n                    <jats:sup>\u22121<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    with a selectivity of 99.1% from biomass\u2010derived furfuryl alcohol and ammonia, which is 63 times higher than that of conventional AuS\n                    <jats:sub>3<\/jats:sub>\n                    \u2010CdS, and notably surpasses other P\u2010coordinated metal\u2010loaded CdS catalysts. Moreover, AuP\n                    <jats:sub>3<\/jats:sub>\n                    \u2010CdS is also applicable to various other alcohols for diverse amine synthesis. Furthermore, this catalyst demonstrates a production rate of 14.24 mmol\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00a0h\n                    <jats:sup>\u22121<\/jats:sup>\n                    with a selectivity of 97.1% under concentrated natural sunlight (3773 mW\u00a0cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    ) in a scalable reactor, providing a promising strategy for the photosynthetic synthesis of amines from diverse biomass\u2010derived alcohols and ammonia.\n                  <\/jats:p>","DOI":"10.1002\/anie.1386399","type":"journal-article","created":{"date-parts":[[2026,5,30]],"date-time":"2026-05-30T11:43:02Z","timestamp":1780141382000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Solar\u2010Driven Carbon\u2013Nitrogen Coupling Between Biomass\u2010Derived Alcohol and Ammonia for High\u2010Value Amine Synthesis"],"prefix":"10.1002","volume":"65","author":[{"given":"Huanmin","family":"Liu","sequence":"first","affiliation":[{"name":"School of Environment and Energy Peking University Shenzhen Graduate School  Shenzhen Guangdong People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinyu","family":"Song","sequence":"additional","affiliation":[{"name":"School of Environment and Energy Peking University Shenzhen Graduate School  Shenzhen Guangdong People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6850-4884","authenticated-orcid":false,"given":"Qin","family":"Li","sequence":"additional","affiliation":[{"name":"Key Laboratory of Catalysis and Energy Materials Chemistry of Ministry of Education &amp; Hubei Key Laboratory of Catalysis and Materials Science &amp; Key Laboratory of Analytical Chemistry of the State Ethnic Affairs Commission South\u2010Central Minzu University  Wuhan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chao","family":"Wu","sequence":"additional","affiliation":[{"name":"School of Materials and Food Science Jiangmen Polytechnic  Jiangmen Guangdong People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wei","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Environment and Energy Peking University Shenzhen Graduate School  Shenzhen Guangdong People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaomin","family":"Lao","sequence":"additional","affiliation":[{"name":"School of Environment and Energy Peking University Shenzhen Graduate School  Shenzhen Guangdong People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kangle","family":"Lv","sequence":"additional","affiliation":[{"name":"Key Laboratory of Catalysis and Energy Materials Chemistry of Ministry of Education &amp; Hubei Key Laboratory of Catalysis and Materials Science &amp; Key Laboratory of Analytical Chemistry of the State Ethnic Affairs Commission South\u2010Central Minzu University  Wuhan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8034-8282","authenticated-orcid":false,"given":"Peng","family":"Zhou","sequence":"additional","affiliation":[{"name":"School of Environment and Energy Peking University Shenzhen Graduate School  Shenzhen Guangdong People's Republic of China"},{"name":"Eco\u2010Environment and Resource Efficiency Research Laboratory School of Environment and Energy Peking University Shenzhen Graduate School  Shenzhen Guangdong People's Republic of China"},{"name":"Guangdong Provincial Key Lab of Nano\u2010Micro Material Research Peking University Shenzhen Graduate School  Shenzhen Guangdong People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,5,30]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010024\u201007446\u20105"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41565\u2010025\u201001897\u20101"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202307962"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.4c04562"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010021\u201023429\u2010w"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.151954"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.biortech.2023.129638"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5c03903"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202411991"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202408527"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202320014"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202306305"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.158618"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c15434"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202400764"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201904249"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202312734"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201061223\u20100"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/s1872\u20102067(23)64542\u20105"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201047022\u2010z"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.4c00123"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2022.09.027"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.1386399","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.1386399","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.1386399","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,28]],"date-time":"2026-07-28T13:36:04Z","timestamp":1785245764000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.1386399"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,5,30]]},"references-count":22,"journal-issue":{"issue":"31","published-print":{"date-parts":[[2026,7,27]]}},"alternative-id":["10.1002\/anie.1386399"],"URL":"https:\/\/doi.org\/10.1002\/anie.1386399","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,5,30]]},"assertion":[{"value":"2026-04-22","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-05-22","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-05-30","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e1386399"}}