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Herein, we designed and synthesized a novel class of highly efficient boron cluster\u2010based organic scintillators featuring a donor\u2013acceptor architecture, constructed by covalently integrating a carbazole donor into an iodophenyl carborane cluster acceptor. These materials exhibit high absolute quantum yields up to 95.8% and an ultralow x\u2010ray detection limit of 76 nGy s\n                    <jats:sup>\u22121<\/jats:sup>\n                    , representing exceptional scintillation performance compared to the commercial inorganic BGO (Bi\n                    <jats:sub>4<\/jats:sub>\n                    Ge\n                    <jats:sub>3<\/jats:sub>\n                    O\n                    <jats:sub>12<\/jats:sub>\n                    ) scintillator (105 nGy s\n                    <jats:sup>\u22121<\/jats:sup>\n                    ). Mechanistic studies reveal that the bright radioluminescence originates from intramolecular charge transfer from the carbazole moiety to the carborane core, which leads to thermally activated delayed fluorescence (TADF) emission and enables theoretically 100% exciton utilization. This work establishes that metal\u2010free boron clusters can serve as versatile building blocks for constructing high\u2010performance organic scintillators, opening a new avenue for next\u2010generation x\u2010ray scintillators.\n                  <\/jats:p>","DOI":"10.1002\/anie.1428276","type":"journal-article","created":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T15:49:36Z","timestamp":1785426576000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Boron Cluster\u2010Based X\u2010Ray Scintillators for Highly Efficient Radioluminescence"],"prefix":"10.1002","volume":"65","author":[{"given":"Mengmeng","family":"Wang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Coordination Chemistry Jiangsu Key Laboratory of Advanced Organic Materials School of Chemistry Nanjing University  Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yitong","family":"Liu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Organic Electronics and Information Displays &amp; Institute of Advanced Materials (IAM) Nanjing University of Posts &amp; Telecommunications  Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mengzhu","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Organic Electronics and Information Displays &amp; Institute of Advanced Materials (IAM) Nanjing University of Posts &amp; Telecommunications  Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ningning","family":"Zhou","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Coordination Chemistry Jiangsu Key Laboratory of Advanced Organic Materials School of Chemistry Nanjing University  Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5080-2533","authenticated-orcid":false,"given":"Ye","family":"Tao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Organic Electronics and Information Displays &amp; 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