{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,7]],"date-time":"2026-07-07T15:14:11Z","timestamp":1783437251748,"version":"3.54.6"},"reference-count":45,"publisher":"Wiley","issue":"27","license":[{"start":{"date-parts":[[2026,5,18]],"date-time":"2026-05-18T00:00:00Z","timestamp":1779062400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,5,18]],"date-time":"2026-05-18T00:00:00Z","timestamp":1779062400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100004359","name":"Vetenskapsr\u00e5det","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100004359","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,7,1]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The electrocatalytic reduction of CO\n                    <jats:sub>2<\/jats:sub>\n                    to methanol offers a compelling pathway for sustainable fuel synthesis, wherein cations in the electric double layer (EDL) exert a substantial influence on catalytic performance. Although cation modulation of CO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010to\u2010CO conversion has been extensively documented, its influence on downstream reduction pathways toward CH\n                    <jats:sub>3<\/jats:sub>\n                    OH has received comparatively little attention. Using multiscale simulation, we establish that methanol synthesis over immobilized cobalt phthalocyanine (CoPc) is kinetically governed by the final proton transfer (*CH\n                    <jats:sub>2<\/jats:sub>\n                    OH + H\n                    <jats:sub>2<\/jats:sub>\n                    O \u2192 * + CH\n                    <jats:sub>3<\/jats:sub>\n                    OH + OH\n                    <jats:sup>\u2212<\/jats:sup>\n                    ). The EDL environment substantially accelerates this rate\u2010determining step (RDS). Moreover, the activity exhibits a clear dependence on cation radius, following the trend Li\n                    <jats:sup>+<\/jats:sup>\n                    &gt; Na\n                    <jats:sup>+<\/jats:sup>\n                    &gt; K\n                    <jats:sup>+<\/jats:sup>\n                    &gt; Cs\n                    <jats:sup>+<\/jats:sup>\n                    , with smaller cations systematically lowering the proton transfer barrier. This trend stems from the enhanced accessibility of smaller cations to the transition state, where Li\n                    <jats:sup>+<\/jats:sup>\n                    achieves tighter coordination than Cs\n                    <jats:sup>+<\/jats:sup>\n                    , conferring greater electrostatic stabilization and a correspondingly reduced barrier. Conversely, smaller cations attenuate the hydrogen\u2010bond network surrounding OH\n                    <jats:sup>\u2212<\/jats:sup>\n                    , potentially impeding OH\n                    <jats:sup>\u2212<\/jats:sup>\n                    transfer from the catalyst surface to the bulk electrolyte. These multifaceted cation effects underscore the complex interplay between kinetic promotion and mass transfer limitations in electrocatalytic systems.\n                  <\/jats:p>","DOI":"10.1002\/anie.1450878","type":"journal-article","created":{"date-parts":[[2026,5,18]],"date-time":"2026-05-18T11:58:41Z","timestamp":1779105521000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Inversed Cation Size Effects on Methanol Formations From CO\n                    <sub>2<\/sub>\n                    Electroreduction by Immobilized Cobalt Phthalocyanine"],"prefix":"10.1002","volume":"65","author":[{"given":"Ke","family":"Ye","sequence":"first","affiliation":[{"name":"Division of Theoretical Chemistry and Biology KTH Royal Institute of Technology  Stockholm Sweden"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Min","family":"Hu","sequence":"additional","affiliation":[{"name":"School of Arts and Sciences Fuyao University of Science and Technology  Fuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0125-9666","authenticated-orcid":false,"given":"Guozhen","family":"Zhang","sequence":"additional","affiliation":[{"name":"Hefei National Research Center for Physical Sciences At the Microscale School of Chemistry and Materials Science University of Science and Technology of China  Hefei China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1553-4027","authenticated-orcid":false,"given":"M\u00e5rten S. 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