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Herein, we develop an atomic\u2010level engineering strategy to construct RuO\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    cluster\u2010modified Cu\u2010based nanowire array electrodes with abundant interfacial structures, which act as efficient tandem catalysts for sustained nitrite\u2013ethanol paired electrolysis at ampere\u2010level current densities. In situ spectroscopic analysis combined with theoretical calculations reveals that the atomically RuO\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    cluster serves as highly active water\u2010activation sites, generating abundant active hydrogen\/oxygen species that subsequently react with adsorbed nitrogen and carbon\u2010containing intermediates, thereby enabling exceptionally favorable co\u2010electrolysis kinetics. Impressively, a membrane electrode assembly flow electrolyzer constructed with RuO\n                    <jats:sub>x<\/jats:sub>\n                    @R\u2010Cu\/CF as both electrodes achieves &gt;90% Faradaic efficiencies for NH\n                    <jats:sub>3<\/jats:sub>\n                    and acetate over a wide current density window of 0.2\u20131.0 A cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , along with high yields of 5.86\u00a0mmol h\n                    <jats:sup>\u22121<\/jats:sup>\n                    cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    (NH\n                    <jats:sub>3<\/jats:sub>\n                    ) and 8.65\u00a0mmol h\n                    <jats:sup>\u22121<\/jats:sup>\n                    cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    (acetate) at 1.0 A cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , and outstanding operational stability, significantly surpassing previously reported co\u2010electrolysis systems.\n                  <\/jats:p>","DOI":"10.1002\/anie.1451856","type":"journal-article","created":{"date-parts":[[2026,6,7]],"date-time":"2026-06-07T16:48:15Z","timestamp":1780850895000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":14,"title":["Atomically Engineered RuO\n                    <i>\n                      <sub>x<\/sub>\n                    <\/i>\n                    \u2010Cu Interfaces Enabling Tandem Catalysis for Ampere\u2010Level Nitrite\u2013Ethanol Co\u2010Electrolysis"],"prefix":"10.1002","volume":"65","author":[{"given":"Jinxuan","family":"Wu","sequence":"first","affiliation":[{"name":"School of Chemistry and Chemical Engineering State Key Laboratory of Bio\u2010based Fiber Materials Zhejiang Sci\u2010Tech University  Hangzhou Zhejiang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jinyang","family":"Zhang","sequence":"additional","affiliation":[{"name":"Guizhou Provincial Key Laboratory of Computational Nano\u2010Material Science Guizhou Education University  Guiyang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huiying","family":"Zhou","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering State Key Laboratory of Bio\u2010based Fiber Materials Zhejiang Sci\u2010Tech University  Hangzhou Zhejiang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kun","family":"Chen","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering State Key Laboratory of Bio\u2010based Fiber Materials Zhejiang Sci\u2010Tech University  Hangzhou Zhejiang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4308-3515","authenticated-orcid":false,"given":"Wentao","family":"Wang","sequence":"additional","affiliation":[{"name":"Guizhou Provincial Key Laboratory of Computational Nano\u2010Material Science Guizhou Education University  Guiyang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lin","family":"Luo","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering State Key Laboratory of Bio\u2010based Fiber Materials Zhejiang Sci\u2010Tech University  Hangzhou Zhejiang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Han","family":"Cheng","sequence":"additional","affiliation":[{"name":"Key Laboratory of Precision and Intelligent Chemistry CAS Center for Excellence in Nanoscience and CAS Key Laboratory of Mechanical Behavior and Design of Materials Collaborative Innovation Center of Chemistry for Energy Mate\u2010Rials (iChEM) University of Science and Technology of China  Hefei Anhui P. 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