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However, designing heterogenous catalysts with highly efficient, uniformed, stable active sites for this solid\u2010liquid\u2010gas three\u2010phase systems remained a significant challenge. Herein, we proposed a solvent\u2010assist hydrothermal method to synthesis 6\u20137\u00a0nm uniformed Ag nanoparticles in ZSM\u20105 (Ag\n                    <jats:sub>NP<\/jats:sub>\n                    \u2010ZSM5). Ag\n                    <jats:sub>NP<\/jats:sub>\n                    \u2010ZSM5 exhibited a yield of 90% and a TOF of 306\u00a0h\n                    <jats:sup>\u22121<\/jats:sup>\n                    in 4\u00a0h alkynes carboxylation reaction. The excellent CO\n                    <jats:sub>2<\/jats:sub>\n                    adsorption capacity of ZSM\u20105, together with the metal\u2010support interaction (MSI) between Ag nanoparticles and the ZSM\u20105 support, jointly enhanced the intrinsic activity of the alkyne carboxylation reaction. This work not only proposed an innovative strategy for synthesizing uniform nanoparticles within zeolites, but also provided a new approach to facilitate the industrial application of terminal alkyne carboxylation.\n                  <\/jats:p>","DOI":"10.1002\/anie.1541233","type":"journal-article","created":{"date-parts":[[2026,6,9]],"date-time":"2026-06-09T01:11:59Z","timestamp":1780967519000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Promoting CO\n                    <sub>2<\/sub>\n                    Conversion With Terminal Alkynes Over ZSM\u20105 Zeolite\u2010Confined Uniform Ag Nanoparticles"],"prefix":"10.1002","volume":"65","author":[{"given":"Qingyun","family":"Qu","sequence":"first","affiliation":[{"name":"Department of Chemistry Tsinghua University  Beijing 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