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Here, we report a charge\/discharge\u2010regulated transformation of lanthanum oxide nanocrystals on ruthenium nanoparticles (La\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    \u2500Ru) as a cathode catalyst. During discharge, high\u2010energy La\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    nanocrystals are electrochemically formed, whereas in the subsequent charge process they undergo catalytic decomposition, enabling autonomous regeneration of active catalytic sites throughout cycling. Integrated experimental characterization and first\u2010principles calculations reveal that the supported Ru not only dictates the reversible La\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    formation\u2010decomposition, but also modulates the O 2p electronic states of La\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    near the Fermi level. This La\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    \u2500Ru heterojunction electronic restructuring establishes a direct electron\u2010transfer channel from the heterojunction catalyst to discharged products, which accelerates lithium\u2010oxygen interfacial reaction kinetics and enhances discharge capacity. Consequently, La\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    \u2500Ru\u2010based LOBs exhibit low charge overpotential, improved reversibility, and high discharge capacity, achieving 5000\u00a0mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    for 46 cycles and markedly outperforming either solid\u2010phase or liquid\u2010phase systems. Leveraging the reversible nature of this heterojunction catalyst resolves the long\u2010standing trade\u2010off between limited capacity and cycling stability, offering a paradigm for designing adaptive catalysts that advance LOBs toward practical high\u2010capacity, durable operation.\n                  <\/jats:p>","DOI":"10.1002\/anie.1656625","type":"journal-article","created":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T15:31:17Z","timestamp":1790695877000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Dynamically Constructing Lanthanum Oxide on Ruthenium to Enhance Lithium\u2010Oxygen Interfacial Reactions"],"prefix":"10.1002","author":[{"given":"Tian","family":"Tang","sequence":"first","affiliation":[{"name":"Energy Materials Research Center Shanghai Institute of Ceramics Chinese Academy of Sciences  Shanghai P. R. 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China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bin","family":"Liu","sequence":"additional","affiliation":[{"name":"Institute of Industrial Nanomaterials Kumamoto University  Kumamoto Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fan","family":"Bai","sequence":"additional","affiliation":[{"name":"Energy Materials Research Center Shanghai Institute of Ceramics Chinese Academy of Sciences  Shanghai P. R. China"},{"name":"Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences  Beijing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6541-6686","authenticated-orcid":false,"given":"Zhuang","family":"Sun","sequence":"additional","affiliation":[{"name":"Energy Materials Research Center Shanghai Institute of Ceramics Chinese Academy of Sciences  Shanghai P. R. 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