{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,8]],"date-time":"2026-10-08T21:16:50Z","timestamp":1791494210618,"version":"4.3.4"},"reference-count":27,"publisher":"Wiley","issue":"28","license":[{"start":{"date-parts":[[2026,5,17]],"date-time":"2026-05-17T00:00:00Z","timestamp":1778976000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,5,17]],"date-time":"2026-05-17T00:00:00Z","timestamp":1778976000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22125503"],"award-info":[{"award-number":["22125503"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52394201"],"award-info":[{"award-number":["52394201"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22321001"],"award-info":[{"award-number":["22321001"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22405260"],"award-info":[{"award-number":["22405260"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002858","name":"China Postdoctoral Science Foundation","doi-asserted-by":"publisher","award":["BX20240358"],"award-info":[{"award-number":["BX20240358"]}],"id":[{"id":"10.13039\/501100002858","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002858","name":"China Postdoctoral Science Foundation","doi-asserted-by":"publisher","award":["2025M771119"],"award-info":[{"award-number":["2025M771119"]}],"id":[{"id":"10.13039\/501100002858","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","award":["WK9990000128"],"award-info":[{"award-number":["WK9990000128"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","award":["WK9990250172"],"award-info":[{"award-number":["WK9990250172"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,7,6]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The efficient recycling of polyethylene terephthalate (PET) is often hindered by challenges such as low\u2010value products, limited processing capacity, prolonged reaction times, and incomplete carbon conversion. Here, we develop a large\u2010scale, ultrafast Joule\u2010assisted reformation strategy that achieves nearly 100% valorization of physical mixtures containing 10\u00a0g of PET waste and metal oxides within seconds. This process converts more than 30% of the carbon into single\u2010metal\u2010atom oxide clusters supported on reduced graphene oxide (M\n                    <jats:sub>1<\/jats:sub>\n                    O\n                    <jats:sub>x<\/jats:sub>\n                    \/rGO) nanosheets, while transforming the remaining carbon into high\u2010value syngas and aromatic compounds. When applied to a physical mixture of PET waste and commercial ZnO, the gaseous products consist mainly of syngas (88.91\u00a0mmol CO and 41.85\u00a0mmol H\n                    <jats:sub>2<\/jats:sub>\n                    ), the aromatic fraction contains 22.84\u00a0mmol benzene, and the solid product is Zn\n                    <jats:sub>1<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    \/rGO nanosheets. Synchrotron\u2010radiation X\u2010ray absorption fine structure and X\u2010ray emission spectroscopy analyses confirm a four\u2010coordinate oxygen environment around the Zn center in the as\u2010synthesized Zn\n                    <jats:sub>1<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    \/rGO nanosheets. The PET reformation pathway was monitored using quasi\u2010in\u00a0situ Fourier transform infrared spectroscopy and quasi\u2010in\u00a0situ gas chromatography\/mass spectrometry, and ab initio molecular dynamics simulations revealed a fragmentation\u2013annulation mechanism. The resulting Zn\n                    <jats:sub>1<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    \/rGO nanosheets exhibit excellent electrocatalytic performance for syngas production via CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction at an industrial\u2010level current density of 400\u00a0mA\u00a0cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . This work establishes a new paradigm for the near\u2010complete valorization of PET waste into high\u2010value products.\n                  <\/jats:p>","DOI":"10.1002\/anie.1688371","type":"journal-article","created":{"date-parts":[[2026,5,18]],"date-time":"2026-05-18T03:21:31Z","timestamp":1779074491000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Nearly 100% Valorization in Seconds: Transforming PET\u2010Metal Oxide Mixtures Into M\n                    <sub>1<\/sub>\n                    O\n                    <sub>x<\/sub>\n                    Clusters on rGO and Premium Syngas\/Aromatics Products"],"prefix":"10.1002","volume":"65","author":[{"given":"Bangwang","family":"Li","sequence":"first","affiliation":[{"name":"Hefei National Research Center for Physical Sciences at the Microscale University of Science and Technology of China Hefei China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Youbin","family":"Zheng","sequence":"additional","affiliation":[{"name":"Hefei National Research Center for Physical Sciences at the Microscale University of Science and Technology of China Hefei China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zihan","family":"Qin","sequence":"additional","affiliation":[{"name":"Hefei National Research Center for Physical Sciences at the Microscale University of Science and Technology of China Hefei China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ziyu","family":"Wang","sequence":"additional","affiliation":[{"name":"Shanghai Synchrotron Radiation Facility Shanghai Advanced Research Institute Shanghai Institute of Applied Physics Chinese Academy of Sciences  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0007-1383-832X","authenticated-orcid":false,"given":"Kai","family":"Zheng","sequence":"additional","affiliation":[{"name":"Hefei National Research Center for Physical Sciences at the Microscale University of Science and Technology of China Hefei China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Siying","family":"Liu","sequence":"additional","affiliation":[{"name":"Hefei National Research Center for Physical Sciences at the Microscale University of Science and Technology of China Hefei China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiangning","family":"Wang","sequence":"additional","affiliation":[{"name":"Hefei National Research Center for Physical Sciences at the Microscale University of Science and Technology of China Hefei China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mingyu","family":"Wu","sequence":"additional","affiliation":[{"name":"Hefei National Research Center for Physical Sciences at the Microscale University of Science and Technology of China Hefei China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Juncheng","family":"Zhu","sequence":"additional","affiliation":[{"name":"Hefei National Research Center for Physical Sciences at the Microscale University of Science and Technology of China Hefei China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6297-4589","authenticated-orcid":false,"given":"Wensheng","family":"Yan","sequence":"additional","affiliation":[{"name":"National Synchrotron Radiation Laboratory University of Science and Technology of China  Hefei China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenxiu","family":"Liu","sequence":"additional","affiliation":[{"name":"Instruments Center for Physical Science University of Science and Technology of China  Hefei China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fanfei","family":"Sun","sequence":"additional","affiliation":[{"name":"Shanghai Synchrotron Radiation Facility Shanghai Advanced Research Institute Shanghai Institute of Applied Physics Chinese Academy of Sciences  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ming","family":"Zuo","sequence":"additional","affiliation":[{"name":"Instruments Center for Physical Science University of Science and Technology of China  Hefei China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4420-5708","authenticated-orcid":false,"given":"Yongfu","family":"Sun","sequence":"additional","affiliation":[{"name":"Hefei National Research Center for Physical Sciences at the Microscale University of Science and Technology of China Hefei China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yi","family":"Xie","sequence":"additional","affiliation":[{"name":"Hefei National Research Center for Physical Sciences at the Microscale University of Science and Technology of China Hefei China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,5,17]]},"reference":[{"key":"e_1_2_8_2_1","article-title":"Anchoring and Competition: Weakly Solvated Structure of Glymes Enhances Stability in Lithium Metal Batteries Operating Under Extreme Conditions","volume":"64","author":"Yu Y. K.","year":"2025","journal-title":"Angewandte Chemie International Edition"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b06872"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201052515\u2010y"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010023\u201005845\u20108"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010020\u20101938\u20100"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201063648\u2010z"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202112576"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202011063"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202100956"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuproc.2007.12.011"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.0c06328"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202306763"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.2c00379"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201061051\u20102"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41893\u2010024\u201001480\u2010x"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202102053"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202303525"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1038\/s44160\u2010024\u201000545\u20101"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1206445"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.energyfuels.9b02915"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40843\u2010025\u20103392\u20108"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202314209"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.8b02525"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201808135"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202506608"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2025.101926"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c04031"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.1688371","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.1688371","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.1688371","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,2]],"date-time":"2026-09-02T11:30:04Z","timestamp":1788348604000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.1688371"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,5,17]]},"references-count":27,"journal-issue":{"issue":"28","published-print":{"date-parts":[[2026,7,6]]}},"alternative-id":["10.1002\/anie.1688371"],"URL":"https:\/\/doi.org\/10.1002\/anie.1688371","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,5,17]]},"assertion":[{"value":"2026-03-09","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-05-05","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-05-17","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e1688371"}}