{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,11,10]],"date-time":"2026-11-10T11:21:27Z","timestamp":1794309687500,"version":"4.9.0"},"reference-count":65,"publisher":"Wiley","issue":"46","license":[{"start":{"date-parts":[[2026,9,28]],"date-time":"2026-09-28T00:00:00Z","timestamp":1790553600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,28]],"date-time":"2026-09-28T00:00:00Z","timestamp":1790553600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22305009"],"award-info":[{"award-number":["22305009"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100006469","name":"Fundo para o Desenvolvimento das Ci\u00eancias e da Tecnologia","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100006469","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,11,9]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Semiconducting oxides emerge as promising photoelectrodes for photoelectrochemical water splitting. However, the kinetic dilemma between ultrafast charge transport and sluggish surface reaction leads to their suboptimal activities. Here, we demonstrate a boron doping strategy that simultaneously enhances charge carrier transport and oxygen evolution reaction (OER) kinetics of bismuth vanadate (BVO) photoanodes. The cocatalyst\u2010free BVO photoanode, upon boron incorporation, shows a photocurrent density of 5.20\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    and an applied bias photon\u2010to\u2010current efficiency (ABPE) of 1.69% at 1.23 and 0.6\n                    <jats:italic>V<\/jats:italic>\n                    <jats:sub>RHE<\/jats:sub>\n                    , respectively. Spectroscopic characterizations and theoretical simulations collectively unravel the improved charge carrier transport and extraction kinetics with concurrently mediated small polaron hopping and trap states. Furthermore, the B\u2010BVO photoanode with potential formation of self\u2010assembled [B(OH)\n                    <jats:sub>4<\/jats:sub>\n                    ]\n                    <jats:sup>\u2212<\/jats:sup>\n                    molecular configurations on its surface significantly accelerates the OER and achieves a cathodically shifted onset potential of 225\u00a0mV. Such modulations in BVO properties, particularly with mediated small polaron hopping and surface configurations, ameliorate the kinetic mismatch between charge transport and surface reaction, providing key insights for improving the intrinsic performance of most semiconducting oxides.\n                  <\/jats:p>","DOI":"10.1002\/anie.1718450","type":"journal-article","created":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T03:48:38Z","timestamp":1790653718000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Reconciling Kinetic Dilemma in Photoelectrochemical Water Splitting via Mediating Small Polaron Hopping and Surface Water Oxidation"],"prefix":"10.1002","volume":"65","author":[{"given":"Zhanghong","family":"Zhou","sequence":"first","affiliation":[{"name":"Sino\u2010Luso Joint Laboratory for Optoelectronics Macao Institute of Materials Science and Engineering (MIMSE) Macau University of Science and Technology  Taipa China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3217-928X","authenticated-orcid":false,"given":"Donghui","family":"Li","sequence":"additional","affiliation":[{"name":"Sino\u2010Luso Joint Laboratory for Optoelectronics Macao Institute of Materials Science and Engineering (MIMSE) Macau University of Science and Technology  Taipa China"},{"name":"State Key Laboratory of Catalysis Chinese Academy of Sciences Dalian Institute of Chemical Physics  Dalian China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Songying","family":"Qu","sequence":"additional","affiliation":[{"name":"Sino\u2010Luso Joint Laboratory for Optoelectronics Macao Institute of Materials Science and Engineering (MIMSE) Macau University of Science and Technology  Taipa China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0623-2238","authenticated-orcid":false,"given":"Dian","family":"Song","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Bioinspired Interfacial Materials Science Institute of Functional Nano &amp; Soft Materials (FUNSOM) Soochow University  Suzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5248-2756","authenticated-orcid":false,"given":"Youyong","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Bioinspired Interfacial Materials Science Institute of Functional Nano &amp; Soft Materials (FUNSOM) Soochow University  Suzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0836-3239","authenticated-orcid":false,"given":"Hao","family":"Wu","sequence":"additional","affiliation":[{"name":"Sino\u2010Luso Joint Laboratory for Optoelectronics Macao Institute of Materials Science and Engineering (MIMSE) Macau University of Science and Technology  Taipa China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,9,28]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2026.179079"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5c09177"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201703491"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-021-27299-0"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929\u2010021\u201000724\u20109"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202402435"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202403336"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202416340"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41578\u2010021\u201000343\u20107"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c09219"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.8b01445"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010022\u201033905\u20106"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.3c00465"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202512757"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202001600"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.4c00382"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010018\u201006838\u20102"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c11706"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jmst.2024.08.014"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202522726"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202403835"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-53426-8"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010026\u201069039\u20102"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1246913"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202300347"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.2c04313"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201911303"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.6b09560"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202516885"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3TA01418E"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7SC00363C"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010019\u201011586\u2010y"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2023.123269"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2020.119477"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.7b04020"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201063670\u20101"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2024.124679"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2021.120983"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5c09061"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202307862"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201902101"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.8b00938"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.4c05982"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.7690318"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6EE00036C"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.88044"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.energyfuels.4c04528"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.9b00153"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202401122"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41567\u2010025\u201002954\u20101"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.1558534"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8TA07437B"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms9769"},{"key":"e_1_2_8_55_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201912475"},{"key":"e_1_2_8_56_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c07501"},{"key":"e_1_2_8_57_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.9b03566"},{"key":"e_1_2_8_58_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202110284"},{"key":"e_1_2_8_59_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202010908"},{"key":"e_1_2_8_60_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2026.178703"},{"key":"e_1_2_8_61_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202401420"},{"key":"e_1_2_8_62_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201058837\u20109"},{"key":"e_1_2_8_63_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8TA06269B"},{"key":"e_1_2_8_64_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.adp7833"},{"key":"e_1_2_8_65_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202504162"},{"key":"e_1_2_8_66_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.6c00836"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.1718450","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.1718450","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.1718450","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,11,10]],"date-time":"2026-11-10T10:21:54Z","timestamp":1794306114000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.1718450"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,9,28]]},"references-count":65,"journal-issue":{"issue":"46","published-print":{"date-parts":[[2026,11,9]]}},"alternative-id":["10.1002\/anie.1718450"],"URL":"https:\/\/doi.org\/10.1002\/anie.1718450","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,9,28]]},"assertion":[{"value":"2026-07-15","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-09-21","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-09-28","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e1718450"}}