{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,10]],"date-time":"2026-10-10T16:48:37Z","timestamp":1791650917852,"version":"4.3.4"},"reference-count":61,"publisher":"Wiley","issue":"42","license":[{"start":{"date-parts":[[2026,8,20]],"date-time":"2026-08-20T00:00:00Z","timestamp":1787184000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,8,20]],"date-time":"2026-08-20T00:00:00Z","timestamp":1787184000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,10,12]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Achieving high product selectivity in electrocatalytic carbon dioxide reduction (CO\n                    <jats:sub>2<\/jats:sub>\n                    RR) remains a critical challenge due to competition between multiple proton\u2010coupled electron\u2010transfer pathways on catalyst surfaces. Meanwhile, chirality\u2010induced spin selectivity (CISS), which enables spin\u2010polarized electron transport through chiral interfaces, has recently emerged as a promising strategy to modulate interfacial electrochemical reactions. Although the CISS effect has been shown to enhance selectivity and efficiency in the spin\u2010sensitive oxygen evolution reaction (OER), its role in regulating CO\n                    <jats:sub>2<\/jats:sub>\n                    RR pathways and in stabilizing intermediates remains largely unexplored. Here, chiral molecules (R\u2010 and S\u20101,1\u2032\u2010bi\u20102\u2010naphthyl\u20102,2\u2032\u2010diyl hydrogen phosphate, BNP) were integrated with SnO\n                    <jats:sub>2<\/jats:sub>\n                    to construct chiral\u2010modified catalysts (R\u2010BNP\/SnO\n                    <jats:sub>2<\/jats:sub>\n                    and S\u2010BNP\/SnO\n                    <jats:sub>2<\/jats:sub>\n                    ). Compared with bare SnO\n                    <jats:sub>2<\/jats:sub>\n                    and racemic BNP\u2010modified SnO\n                    <jats:sub>2<\/jats:sub>\n                    (Rac\u2010BNP\/SnO\n                    <jats:sub>2<\/jats:sub>\n                    ), the chiral catalysts exhibited a pronounced shift in product selectivity from CO toward formate production. Importantly, in\u2010situ attenuated total reflectance surface\u2010enhanced infrared absorption spectroscopy (ATR\u2010SEIRAS) reveals that the chiral interface selectively stabilizes the O\u2010bound *OCHO intermediate associated with the formate pathway and modulates interfacial water structure and hydrogen\u2010bonding dynamics. These findings demonstrate that spin\u2010polarized interfacial electron transfer can regulate CO\n                    <jats:sub>2<\/jats:sub>\n                    RR pathway selectivity by modulating the stabilization of key intermediates. More broadly, this work establishes chiral spin\u2010selective interfaces as a new strategy for regulating competitive electrocatalytic reaction pathways.\n                  <\/jats:p>","DOI":"10.1002\/anie.1729522","type":"journal-article","created":{"date-parts":[[2026,8,20]],"date-time":"2026-08-20T12:12:01Z","timestamp":1787227921000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Spin\u2010Polarized Interfaces Redirect CO\n                    <sub>2<\/sub>\n                    Reduction From CO to Formate"],"prefix":"10.1002","volume":"65","author":[{"ORCID":"https:\/\/orcid.org\/0009-0003-7671-1685","authenticated-orcid":false,"given":"Fan","family":"He","sequence":"first","affiliation":[{"name":"Department of Chemistry and Biochemistry San Diego State University  San Diego USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7991-4849","authenticated-orcid":false,"given":"Xingxu","family":"Yan","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering University of California  Irvine USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaoqing","family":"Pan","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering University of California  Irvine USA"},{"name":"Department of Physics and Astronomy University of California, Irvine  Irvine USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6361-0541","authenticated-orcid":false,"given":"Yong","family":"Yan","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry San Diego State University  San Diego USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5506-0049","authenticated-orcid":false,"given":"Jing","family":"Gu","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry San Diego State University  San Diego USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,8,20]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929\u2010021\u201000683\u20101"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.7848056"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aax4608"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c05444"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c00880"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929\u2010024\u201001147\u2010y"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matt.2024.09.024"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41578\u2010025\u201000875\u20102"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201045704\u20102"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010023\u201042539\u20101"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010021\u201026724\u20108"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c05984"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010024\u201001633\u20104"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.8b03547"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.abi9828"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2017.09.014"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c04841"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1199339"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41570\u2010019\u20100087\u20101"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b12971"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aar4265"},{"key":"e_1_2_8_23_1","first-page":"28214","article-title":"Chiral Nanostructured Ag Films for Multicarbon Products From CO2 Electroreduction","volume":"146","author":"Zhang W.","year":"2024","journal-title":"Journal of the American Chemical Society"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.ady4885"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aao7172"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3CS00316G"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.3c00661"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2EE03853F"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms2215"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202201063"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.adw5850"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12551\u2010025\u201001278\u2010x"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsphotonics.3c00174"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b02825"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.9b11817"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1155\/2017\/2105938"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.4c00132"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr040079g"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jct.2019.105905"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1039\/B609577A"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp909178x"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.8b09515"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tsf.2005.04.014"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.17576\/jsm\u20102018\u20104708\u201033"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201805944"},{"key":"e_1_2_8_46_1","first-page":"2519","article-title":"Dissociative Ligand Exchange at Identical Molecular and Carbon Nanoparticle Binding Sites","volume":"19","author":"Kaminsky C.","year":"2007","journal-title":"Chemistry of Materials"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.5c18273"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010023\u201040367\u2010x"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c04615"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1093\/nsr\/nwaf295"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.0c02578"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201047498\u20109"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1039\/D6CC01127F"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010026\u201002062\u20101"},{"key":"e_1_2_8_55_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.progsurf.2005.09.002"},{"key":"e_1_2_8_56_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c00858"},{"key":"e_1_2_8_57_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.3091087"},{"key":"e_1_2_8_58_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.3c05880"},{"key":"e_1_2_8_59_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2026.03.040"},{"key":"e_1_2_8_60_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00113a028"},{"key":"e_1_2_8_61_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010019\u201008805\u2010x"},{"key":"e_1_2_8_62_1","doi-asserted-by":"publisher","DOI":"10.1021\/prechem.3c00059"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.1729522","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.1729522","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.1729522","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,10]],"date-time":"2026-10-10T15:48:33Z","timestamp":1791647313000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.1729522"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,8,20]]},"references-count":61,"journal-issue":{"issue":"42","published-print":{"date-parts":[[2026,10,12]]}},"alternative-id":["10.1002\/anie.1729522"],"URL":"https:\/\/doi.org\/10.1002\/anie.1729522","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,8,20]]},"assertion":[{"value":"2026-06-04","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-08-13","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-08-20","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e1729522"}}