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Here, a dual thermal\u2010stabilization strategy is identified and rationalized as the optimal choice to tailor above issues. A fluorinated graphene (FG)\u2010interlayer is introduced to effectively enhance heat dissipation and deflect Li dendrite propagation inside the ASSLMBs, while an oxygen\u2010vacancy\u2010rich copper oxide (CuO\n                    <jats:sub>1\u2212x<\/jats:sub>\n                    ) additive is applied to efficiently capture reactive oxygen species released from charged cathodes and thus mitigate the electrolyte oxidation. As a demonstration model, the as\u2010modified Li\n                    <jats:sub>6<\/jats:sub>\n                    PS\n                    <jats:sub>5<\/jats:sub>\n                    Cl (LPSC)\u2010based full cells achieve stable cycling over 2000 cycles at 1 C with 96% capacity retention, and well retain the room\u2010temperature capacity even at 90\u00b0C. Accelerated rate calorimetry (ARC) tests on pouch cells further demonstrate enhanced thermal stability. This dual\u2010thermal\u2010stabilization paradigm can be extended to sulfide\/chlorinated oxide bilayer electrolyte systems.\n                  <\/jats:p>","DOI":"10.1002\/anie.1775824","type":"journal-article","created":{"date-parts":[[2026,7,22]],"date-time":"2026-07-22T06:27:26Z","timestamp":1784701646000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Dual Thermal Stabilization Toward Highly Safe and Durable All\u2010Solid\u2010State Lithium Metal Batteries Based on Sulfide Electrolytes"],"prefix":"10.1002","volume":"65","author":[{"given":"Bingyue","family":"Ling","sequence":"first","affiliation":[{"name":"Tsinghua Shenzhen International Graduate School Tsinghua University  Shenzhen China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kun","family":"Li","sequence":"additional","affiliation":[{"name":"Tsinghua Shenzhen International Graduate School Tsinghua University  Shenzhen 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of Interdisciplinary Science For Advanced Materials and Large\u2010Scale Scientific Facilities School of Physical Sciences Great Bay University  Dongguan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1074-4006","authenticated-orcid":false,"given":"Xu","family":"Yang","sequence":"additional","affiliation":[{"name":"Centre For Clean Energy Technology Faculty of Science University of Technology Sydney  Sydney New South Wales Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4295-8578","authenticated-orcid":false,"given":"Guoxiu","family":"Wang","sequence":"additional","affiliation":[{"name":"Centre For Clean Energy Technology Faculty of Science University of Technology Sydney  Sydney New South Wales 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