{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T16:59:38Z","timestamp":1790701178397,"version":"4.1.0"},"reference-count":60,"publisher":"Wiley","issue":"37","license":[{"start":{"date-parts":[[2026,7,9]],"date-time":"2026-07-09T00:00:00Z","timestamp":1783555200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,7,9]],"date-time":"2026-07-09T00:00:00Z","timestamp":1783555200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,9,7]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Aqueous Zn\u2010WO\n                    <jats:sub>3<\/jats:sub>\n                    electrochromic devices (ZWEDs) represent a promising frontier in energy\u2010efficient electrochromic systems. However, their practical application is hindered by the short device lifespans due to the poor electrode\/electrolyte interfacial stability which originates from high water activity. Herein, we develop a eutectic\u2010polymer dual\u2010network electrolyte to regulate water activity and stabilize the electrode\/electrolyte interface. Combined in situ\/ex situ spectroscopic analysis and simulations reveal that this eutectic\u2010polymer dual\u2010network stabilize the electrode structure via two complementary effects: (i) reconstruction of the hydrogen\u2010bond network confines free water molecules, suppressing water activity and parasitic reactions; and (ii) preferential adsorption of acetamide molecules over water on the electrode surfaces forms a stable molecular interfacial layer that regulates Zn\n                    <jats:sup>2+<\/jats:sup>\n                    electrochemical behavior and further mitigates water\u2010induced side reactions. Benefiting from the synergy between hydrogen\u2010bond reconstruction and interfacial adsorption, the interfacial stabilities of both Zn anode and WO\n                    <jats:sub>3<\/jats:sub>\n                    cathode are significantly enhanced. Consequently, the Zn\u2010WO\n                    <jats:sub>3<\/jats:sub>\n                    device achieves outstanding cyclic stability in both ion storage and optical modulation over 1000 cycles, with an operational temperature range expanded to \u221230\u00b0C\u223c80\u00b0C. This strategy offers a promising pathway to enhance the interfacial stability in ZWEDs across a wide temperature range.\n                  <\/jats:p>","DOI":"10.1002\/anie.1941770","type":"journal-article","created":{"date-parts":[[2026,7,9]],"date-time":"2026-07-09T11:39:03Z","timestamp":1783597143000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Manipulating Interfacial Water Molecules via Eutectic\u2010Polymer Dual\u2010Network for Stable Electrochromic Devices"],"prefix":"10.1002","volume":"65","author":[{"given":"Jiandong","family":"Wan","sequence":"first","affiliation":[{"name":"College of Materials Science and Engineering Hunan University  Changsha China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xin","family":"Tan","sequence":"additional","affiliation":[{"name":"College of Materials Science and Engineering Hunan University  Changsha 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