{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,16]],"date-time":"2026-04-16T01:57:14Z","timestamp":1776304634375,"version":"3.50.1"},"reference-count":173,"publisher":"Wiley","issue":"32","license":[{"start":{"date-parts":[[2004,7,7]],"date-time":"2004-07-07T00:00:00Z","timestamp":1089158400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2004,8,13]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Oxygenation of C\uf8ffH and C\uf8feC bonds of hydrocarbons with H<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub> and O<jats:sub>2<\/jats:sub> is an important industrial method to convert mineral oil into useful chemicals. Despite their enormous economic impact, these reactions are still not fully understood. In the early 1970s, the potential of Rh and Ir complexes for olefin oxygenation was investigated intensively. Simple inorganic salts of these metals proved to be rather useless for industrial application when compared with the traditional Wacker system. However, the appropriate choice of ligands allows the stepwise oxidation of olefins at Rh and Ir. These systems are therefore useful to study mechanistic details of substrate binding and C\uf8ffO bond formation at the catalytic metal center. Insight from these model studies helps in understanding the catalytic reactions at these (and possibly other) metal centers. Further insight into the differences between the Rh system and traditional Wacker\u2010type oxidation at Pd may lead to useful applications.<\/jats:p>","DOI":"10.1002\/anie.200300629","type":"journal-article","created":{"date-parts":[[2004,7,7]],"date-time":"2004-07-07T12:06:24Z","timestamp":1089201984000},"page":"4142-4157","source":"Crossref","is-referenced-by-count":127,"title":["Functional Models for Rhodium\u2010Mediated Olefin\u2010Oxygenation Catalysis"],"prefix":"10.1002","volume":"43","author":[{"given":"Bas","family":"de Bruin","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Peter H. M.","family":"Budzelaar","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Anton W.","family":"Gal","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2004,8,9]]},"reference":[{"key":"e_1_2_6_1_2","doi-asserted-by":"publisher","DOI":"10.1039\/b303160h"},{"key":"e_1_2_6_2_2","doi-asserted-by":"crossref","DOI":"10.1039\/9781847550132","volume-title":"Application of Hydrogen Peroxide and Derivatives","author":"Jones C. W.","year":"1999"},{"key":"e_1_2_6_3_2","volume-title":"Catalytic Oxidations with Hydrogen Peroxide","year":"1992"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/ie020919m"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1007\/978-1-4615-3000-8"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr00082a005"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1016\/0010-8545(92)80024-L"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1016\/0920-5861(94)80186-X"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0020-1693(00)92378-8"},{"key":"e_1_2_6_10_2","volume-title":"Metal Ion Activation of Dioxygen","author":"Spiro T. G.","year":"1980"},{"key":"e_1_2_6_11_2","volume-title":"Metal Catalyzed Oxidations of Organic Compounds","author":"Sheldon R. A.","year":"1981"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1016\/S1381-1169(98)80128-3"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3757(19980504)110:9<1256::AID-ANGE1256>3.0.CO;2-V"},{"key":"e_1_2_6_13_3","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3773(19980518)37:9<1198::AID-ANIE1198>3.0.CO;2-Y"},{"key":"e_1_2_6_14_2","volume-title":"Organometallic Reactions","author":"Becker E. I.","year":"1972"},{"key":"e_1_2_6_15_2","volume-title":"Comprehensive Coordination Chemistry","author":"Mimoun H.","year":"1987"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr00093a001"},{"key":"e_1_2_6_17_2","volume":"79","author":"Moulijn J. A.","year":"1993","journal-title":"Stud. Surf. Sci. Catal."},{"key":"e_1_2_6_18_2","first-page":"384","volume":"14","author":"Li Z.","year":"2002","journal-title":"Prog. Chem."},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1023\/A:1013897703249"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.2174\/1385272033372851"},{"key":"e_1_2_6_21_2","first-page":"95","volume-title":"The Chemical Physics of Solid Surfaces and Heterogeneous Catalysis","author":"Barteau M. A.","year":"1982"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0360-0564(08)60095-4"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1080\/03602458108068072"},{"key":"e_1_2_6_24_2","doi-asserted-by":"publisher","DOI":"10.1023\/A:1021499225395"},{"key":"e_1_2_6_25_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0926-860X(01)00799-2"},{"key":"e_1_2_6_26_2","doi-asserted-by":"publisher","DOI":"10.1023\/A:1021471718608"},{"key":"e_1_2_6_27_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0926-860X(02)00062-5"},{"key":"e_1_2_6_28_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0926-860X(02)00451-9"},{"key":"e_1_2_6_29_2","first-page":"602","author":"Landau R.","year":"1979","journal-title":"CHEMTECH"},{"key":"e_1_2_6_30_2","doi-asserted-by":"publisher","DOI":"10.1016\/0304-5102(80)85010-3"},{"key":"e_1_2_6_31_2","unstructured":"M.Taramasso G.Perego B. Notari(Enichem) US Pat. 4\u2009410\u2009501 1983["},{"key":"e_1_2_6_31_3","first-page":"206\u2009272","volume":"95","year":"1981","journal-title":"Chem. Abstr."},{"key":"e_1_2_6_32_2","doi-asserted-by":"publisher","DOI":"10.1016\/0920-5861(93)85029-Y"},{"key":"e_1_2_6_33_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0167-2991(09)60618-2"},{"key":"e_1_2_6_34_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19971090506"},{"key":"e_1_2_6_34_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199704771"},{"key":"e_1_2_6_35_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00538a077"},{"key":"e_1_2_6_36_2","doi-asserted-by":"publisher","DOI":"10.1016\/B978-0-08-052349-1.00196-7"},{"key":"e_1_2_6_37_2","first-page":"103","volume-title":"Catalytic Asymmetric Synthesis","author":"Johnson R. A.","year":"1993"},{"key":"e_1_2_6_38_2","first-page":"1","volume":"48","author":"Katsuki T.","year":"1996","journal-title":"Org. React."},{"key":"e_1_2_6_39_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00269a029"},{"key":"e_1_2_6_40_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(00)74486-8"},{"key":"e_1_2_6_41_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00163a052"},{"key":"e_1_2_6_42_2","first-page":"159","volume-title":"Catalytic Asymmetric Synthesis","author":"Jacobsen E. N.","year":"1993"},{"key":"e_1_2_6_43_2","doi-asserted-by":"publisher","DOI":"10.1016\/S1381-1169(96)00106-9"},{"key":"e_1_2_6_44_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.19960020812"},{"key":"e_1_2_6_45_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00306a029"},{"key":"e_1_2_6_46_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.19960020111"},{"key":"e_1_2_6_47_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19941062225"},{"key":"e_1_2_6_47_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199423121"},{"key":"e_1_2_6_48_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3757(19991018)111:20<3211::AID-ANGE3211>3.0.CO;2-X"},{"key":"e_1_2_6_48_3","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3773(19991018)38:20<3026::AID-ANIE3026>3.0.CO;2-P"},{"key":"e_1_2_6_49_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja000802u"},{"key":"e_1_2_6_50_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr60324a003"},{"key":"e_1_2_6_51_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr00032a009"},{"key":"e_1_2_6_52_2","first-page":"97","volume":"55","author":"Jira R.","year":"1976","journal-title":"Hydrocarbon Process."},{"key":"e_1_2_6_53_2","first-page":"1196","volume-title":"Advanced Organic Chemistry: Reactions, Mechanisms, and Structure","author":"March J.","year":"1992"},{"key":"e_1_2_6_54_2","unstructured":"R. Rappo A. Becker Isr. Res. Counc. Bull. A1956 5 300."},{"key":"e_1_2_6_55_2","first-page":"3644","volume":"41","author":"Lee D. G.","year":"1976","journal-title":"J. Org. Chem."},{"key":"e_1_2_6_56_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo00884a045"},{"key":"e_1_2_6_57_2","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.43.1153"},{"key":"e_1_2_6_58_2","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.43.3898"},{"key":"e_1_2_6_59_2","doi-asserted-by":"publisher","DOI":"10.1016\/S1381-1169(00)00065-0"},{"key":"e_1_2_6_60_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0006649"},{"key":"e_1_2_6_61_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic000204g"},{"key":"e_1_2_6_62_2","doi-asserted-by":"publisher","DOI":"10.1002\/1099-0682(200107)2001:7<1819::AID-EJIC1819>3.0.CO;2-K"},{"key":"e_1_2_6_63_2","unstructured":"\u00a0"},{"key":"e_1_2_6_64_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo00108a033"},{"key":"e_1_2_6_65_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00150a034"},{"key":"e_1_2_6_66_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1099-0682(199912)1999:12<2135::AID-EJIC2135>3.0.CO;2-X"},{"key":"e_1_2_6_67_2","unstructured":"For a selection of experimental evidence for early transition\u2010metal\u2010catalyzed olefin epoxidation through step b2 in Scheme 2 see:"},{"key":"e_1_2_6_68_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00141a016"},{"key":"e_1_2_6_69_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo951774e"},{"key":"e_1_2_6_70_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic971073v"},{"key":"e_1_2_6_71_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3765(19991203)5:12<3603::AID-CHEM3603>3.0.CO;2-W"},{"key":"e_1_2_6_72_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19961082330"},{"key":"e_1_2_6_72_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199628171"},{"key":"e_1_2_6_73_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja9625992"},{"key":"e_1_2_6_74_2","doi-asserted-by":"publisher","DOI":"10.1021\/om960783q"},{"key":"e_1_2_6_75_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19971091615"},{"key":"e_1_2_6_75_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199717231"},{"key":"e_1_2_6_76_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19971091614"},{"key":"e_1_2_6_76_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199717201"},{"key":"e_1_2_6_77_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19971091906"},{"key":"e_1_2_6_77_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199720601"},{"key":"e_1_2_6_78_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200390118"},{"key":"e_1_2_6_79_2","first-page":"357","volume-title":"Comprehensive Organometallic Chemistry","author":"Maitlis P. M.","year":"1982"},{"key":"e_1_2_6_80_2","doi-asserted-by":"publisher","DOI":"10.1007\/978-94-009-5267-6"},{"key":"e_1_2_6_81_2","volume":"11","author":"Gore E. S.","year":"1991","journal-title":"Stud. Inorg. Chem."},{"key":"e_1_2_6_82_2","volume-title":"Metal Ion Activation of Dioxygen","author":"Groves J. T.","year":"1980"},{"key":"e_1_2_6_83_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00010a066"},{"key":"e_1_2_6_84_2","doi-asserted-by":"publisher","DOI":"10.1016\/0304-5102(92)80261-E"},{"key":"e_1_2_6_85_2","doi-asserted-by":"publisher","DOI":"10.1039\/C39950001301"},{"key":"e_1_2_6_86_2","doi-asserted-by":"publisher","DOI":"10.1139\/v72-270"},{"key":"e_1_2_6_87_2","doi-asserted-by":"publisher","DOI":"10.1351\/pac198153122389"},{"key":"e_1_2_6_88_2","doi-asserted-by":"publisher","DOI":"10.1351\/pac198254101853"},{"key":"e_1_2_6_89_2","doi-asserted-by":"publisher","DOI":"10.1016\/0304-5102(84)80070-X"},{"key":"e_1_2_6_90_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(01)85228-X"},{"key":"e_1_2_6_91_2","doi-asserted-by":"publisher","DOI":"10.1039\/dt9770000883"},{"key":"e_1_2_6_92_2","doi-asserted-by":"publisher","DOI":"10.1039\/dt9850001591"},{"key":"e_1_2_6_93_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00296a011"},{"key":"e_1_2_6_94_2","doi-asserted-by":"publisher","DOI":"10.1039\/c39820000406"},{"key":"e_1_2_6_95_2","doi-asserted-by":"publisher","DOI":"10.1016\/0304-5102(85)85073-2"},{"key":"e_1_2_6_96_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(85)87071-6"},{"key":"e_1_2_6_97_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(01)84968-6"},{"key":"e_1_2_6_98_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo00983a019"},{"key":"e_1_2_6_99_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(00)82624-8"},{"key":"e_1_2_6_100_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic50003a061"},{"key":"e_1_2_6_101_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(00)98840-5"},{"key":"e_1_2_6_102_2","doi-asserted-by":"publisher","DOI":"10.1016\/0304-5102(86)85138-0"},{"key":"e_1_2_6_103_2","doi-asserted-by":"publisher","DOI":"10.1016\/0304-5102(86)85009-X"},{"key":"e_1_2_6_104_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00485a031"},{"key":"e_1_2_6_105_2","doi-asserted-by":"publisher","DOI":"10.1039\/c39840001313"},{"key":"e_1_2_6_106_2","unstructured":"The peroxide and metalladioxolane species in partAof Scheme 5 and partsA\u2032 A\u2032\u2032of Scheme 24 are depicted in an unprotonated state for simplicity. Mechanistic proposals in the literature contain both protonated and unprotonated variations. Our schemes are not intended to express any preference for the unprotonated variation."},{"key":"e_1_2_6_107_2","doi-asserted-by":"publisher","DOI":"10.1016\/0304-5102(81)85001-8"},{"key":"e_1_2_6_108_2","doi-asserted-by":"publisher","DOI":"10.1039\/c39790000274"},{"key":"e_1_2_6_109_2","doi-asserted-by":"publisher","DOI":"10.1039\/c39830000586"},{"key":"e_1_2_6_110_2","doi-asserted-by":"publisher","DOI":"10.1039\/c39780000559"},{"key":"e_1_2_6_111_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0898-8838(08)60133-6"},{"key":"e_1_2_6_112_2","doi-asserted-by":"publisher","DOI":"10.1039\/dt9920003371"},{"key":"e_1_2_6_113_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic951154w"},{"key":"e_1_2_6_114_2","doi-asserted-by":"publisher","DOI":"10.1039\/C39940000575"},{"key":"e_1_2_6_115_2","doi-asserted-by":"publisher","DOI":"10.1039\/j19680001450"},{"key":"e_1_2_6_116_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(85)88011-6"},{"key":"e_1_2_6_117_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(87)85101-X"},{"key":"e_1_2_6_118_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0020-1693(00)86102-2"},{"key":"e_1_2_6_119_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00161a076"},{"key":"e_1_2_6_120_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19971091907"},{"key":"e_1_2_6_120_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199720641"},{"key":"e_1_2_6_121_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3765(19991001)5:10<2921::AID-CHEM2921>3.0.CO;2-1"},{"key":"e_1_2_6_122_2","doi-asserted-by":"publisher","DOI":"10.1039\/b002079f"},{"key":"e_1_2_6_123_2","unstructured":"R. J. N. A. M. Kicken PhD Thesis University of Nijmegen 2001."},{"key":"e_1_2_6_124_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00086a050"},{"key":"e_1_2_6_125_2","doi-asserted-by":"publisher","DOI":"10.1002\/1099-0682(20022)2002:2<457::AID-EJIC457>3.0.CO;2-P"},{"key":"e_1_2_6_126_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3765(20000117)6:2<298::AID-CHEM298>3.0.CO;2-Z"},{"key":"e_1_2_6_127_2","unstructured":"M. Krom PhD Thesis University of Nijmegen 2003."},{"key":"e_1_2_6_128_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3765(20010119)7:2<416::AID-CHEM416>3.0.CO;2-Q"},{"key":"e_1_2_6_129_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200300546"},{"key":"e_1_2_6_130_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3757(19990115)111:1\/2<118::AID-ANGE118>3.0.CO;2-V"},{"key":"e_1_2_6_130_3","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3773(19990115)38:1\/2<219::AID-ANIE219>3.0.CO;2-I"},{"key":"e_1_2_6_131_2","unstructured":"B. de Bruin T. P. J. Peters unpublished results."},{"key":"e_1_2_6_132_2","doi-asserted-by":"publisher","DOI":"10.1002\/1099-0682(200210)2002:10<2671::AID-EJIC2671>3.0.CO;2-8"},{"key":"e_1_2_6_133_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20010601)113:11<2164::AID-ANGE2164>3.0.CO;2-#"},{"key":"e_1_2_6_133_3","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20010601)40:11<2106::AID-ANIE2106>3.0.CO;2-O"},{"key":"e_1_2_6_134_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200390139"},{"key":"e_1_2_6_135_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20020215)114:4<595::AID-ANGE595>3.0.CO;2-R"},{"key":"e_1_2_6_135_3","first-page":"576","volume":"41","year":"2002","journal-title":"Angew. Chem. Int. Ed."},{"key":"e_1_2_6_136_2","first-page":"1773","author":"Vigalok A.","year":"1996","journal-title":"Chem. Commun."},{"key":"e_1_2_6_137_2","doi-asserted-by":"publisher","DOI":"10.1039\/c29700001694"},{"key":"e_1_2_6_138_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0020-1693(00)94812-6"},{"key":"e_1_2_6_139_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20020617)114:12<2239::AID-ANGE2239>3.0.CO;2-H"},{"key":"e_1_2_6_139_3","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20020617)41:12<2138::AID-ANIE2138>3.0.CO;2-T"},{"key":"e_1_2_6_140_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic50144a032"},{"key":"e_1_2_6_141_2","doi-asserted-by":"publisher","DOI":"10.1021\/om030192h"},{"key":"e_1_2_6_142_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00858a009"},{"key":"e_1_2_6_143_2","unstructured":"This is an important difference to the typical \u201cWacker\u201d metals PdIIand PtII which have a more labile coordination environment and a higher affinity for olefins so that mechanisms involving entry of the olefin at the MIIoxidation stateafterformation of the M\uf8ffO bond are more likely. For an example see reference [152]."},{"key":"e_1_2_6_144_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja9636653"},{"key":"e_1_2_6_145_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar00102a004"},{"key":"e_1_2_6_146_2","unstructured":"Although a \u201cunified\u201d mechanism of Rh\u2010only and Rh\/Cu catalysis is certainly attractive we realize that the products may also be formed through different mechanisms which happen to arrive at the same products. Ketones are the almost inevitable products of olefin oxidation and can be formed through a variety of routes."},{"key":"e_1_2_6_147_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00173a047"},{"key":"e_1_2_6_148_2","doi-asserted-by":"publisher","DOI":"10.1021\/om00032a062"},{"key":"e_1_2_6_149_2","doi-asserted-by":"publisher","DOI":"10.1016\/S1381-1169(96)00193-8"},{"key":"e_1_2_6_150_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00829a014"},{"key":"e_1_2_6_151_2","doi-asserted-by":"publisher","DOI":"10.1039\/dt9780000279"},{"key":"e_1_2_6_152_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00219a080"},{"key":"e_1_2_6_153_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00164a067"},{"key":"e_1_2_6_154_2","doi-asserted-by":"publisher","DOI":"10.1021\/om00055a061"},{"key":"e_1_2_6_155_2","doi-asserted-by":"publisher","DOI":"10.1039\/c39720000910"},{"key":"e_1_2_6_156_2","first-page":"65","volume":"115","author":"Pandolfo L.","year":"1985","journal-title":"Gazz. Chim. Ital."},{"key":"e_1_2_6_157_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19860980914"},{"key":"e_1_2_6_157_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198608171"},{"key":"e_1_2_6_158_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja036496c"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fanie.200300629","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.200300629","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,10,10]],"date-time":"2023-10-10T20:01:16Z","timestamp":1696968076000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.200300629"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2004,8,9]]},"references-count":173,"journal-issue":{"issue":"32","published-print":{"date-parts":[[2004,8,13]]}},"alternative-id":["10.1002\/anie.200300629"],"URL":"https:\/\/doi.org\/10.1002\/anie.200300629","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2004,8,9]]}}}