{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T19:26:49Z","timestamp":1760297209020},"reference-count":52,"publisher":"Wiley","issue":"25","license":[{"start":{"date-parts":[[2004,6,16]],"date-time":"2004-06-16T00:00:00Z","timestamp":1087344000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2004,6,21]]},"DOI":"10.1002\/anie.200454022","type":"journal-article","created":{"date-parts":[[2004,6,16]],"date-time":"2004-06-16T10:05:00Z","timestamp":1087380300000},"page":"3321-3325","source":"Crossref","is-referenced-by-count":62,"title":["Isolation of [1]Ruthenocenophanes: Synthesis of Polyruthenocenylstannanes by Ring\u2010Opening Polymerization"],"prefix":"10.1002","volume":"43","author":[{"given":"Ulf","family":"Vogel","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Alan J.","family":"Lough","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ian","family":"Manners","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2004,6,16]]},"reference":[{"key":"e_1_2_3_1_2","unstructured":"\u00a0"},{"key":"e_1_2_3_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19951071707"},{"key":"e_1_2_3_2_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199518371"},{"key":"e_1_2_3_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(03)00402-9"},{"key":"e_1_2_3_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00041a053"},{"key":"e_1_2_3_5_2","unstructured":"\u00a0"},{"key":"e_1_2_3_6_2","doi-asserted-by":"publisher","DOI":"10.1039\/a810043h"},{"key":"e_1_2_3_7_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1066321"},{"key":"e_1_2_3_8_2","unstructured":"\u00a0"},{"key":"e_1_2_3_9_2","doi-asserted-by":"publisher","DOI":"10.1039\/a827263z"},{"key":"e_1_2_3_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/om0201112"},{"key":"e_1_2_3_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja000311"},{"key":"e_1_2_3_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja029297m"},{"key":"e_1_2_3_13_2","unstructured":"\u00a0"},{"key":"e_1_2_3_14_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(00)90295-X"},{"key":"e_1_2_3_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3765(19981102)4:11<2117::AID-CHEM2117>3.0.CO;2-E"},{"key":"e_1_2_3_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/om9805234"},{"key":"e_1_2_3_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja020206v"},{"key":"e_1_2_3_18_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(99)00078-9"},{"key":"e_1_2_3_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja972043u"},{"key":"e_1_2_3_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19971092114"},{"key":"e_1_2_3_20_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199723381"},{"key":"e_1_2_3_21_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(01)00923-8"},{"key":"e_1_2_3_22_2","unstructured":"\u00a0"},{"key":"e_1_2_3_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00335a011"},{"key":"e_1_2_3_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/om000483f"},{"key":"e_1_2_3_25_2","unstructured":"\u00a0"},{"key":"e_1_2_3_26_2","doi-asserted-by":"publisher","DOI":"10.1021\/om00118a001"},{"key":"e_1_2_3_27_2","doi-asserted-by":"publisher","DOI":"10.1021\/om00012a016"},{"key":"e_1_2_3_28_2","unstructured":"\u00a0"},{"key":"e_1_2_3_29_2","doi-asserted-by":"publisher","DOI":"10.1039\/cc9960002153"},{"key":"e_1_2_3_30_2","doi-asserted-by":"publisher","DOI":"10.1002\/1099-0682(200211)2002:11<3039::AID-EJIC3039>3.0.CO;2-0"},{"key":"e_1_2_3_31_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19941060909"},{"key":"e_1_2_3_31_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199409891"},{"key":"e_1_2_3_32_2","unstructured":"For3the difference in the tilt angle \u03b1 between the planes of the Cp ligands for the Ru and Fe species is 8\u00b0. (3(M=Ru):\u03b1=29.6(5)\u00b0 3(M=Fe):\u03b1=21.6(5)\u00b0); see references [9] and [17]."},{"key":"e_1_2_3_33_2","unstructured":"U. Vogel J. M. Nelson I. Manners unpublished results."},{"key":"e_1_2_3_34_2","doi-asserted-by":"publisher","DOI":"10.1515\/znb-1995-1117"},{"key":"e_1_2_3_35_2","unstructured":"Crystallographic data for C28H34RuZr (5): monoclinicC2\/c a=19.0368(4) b=9.5493(4) c=15.1497(4) \u00c5 \u03b2=124.306(2)\u00b0 V=2274.9(1) \u00c53 Z=4 \u03bc=1.135 mm\u22121 \u03c1calcd=1.643 Mg\u2009m\u22123 150(1) K Nonius Kappa\u2010CCD diffractometer using graphite\u2010monochromated MoK\u03b1radiation (\u03bb=0.71073 \u00c5) pale yellow crystal (0.30\u00d70.22\u00d70.16 mm3). Of 9615 reflections collected (5.1\u22642\u03b8\u226455.0\u00b0) 2617 were independent (Rint=0.0296) and 2279 were observed withFo\u22654\u03c3(Fo). Solution and refinement with SHELXTL\u2010PC v6.12 non\u2010hydrogen atoms were refined with anisotropic parameters hydrogen atoms were refined on calculated positions using a riding model R1=0.0256 wR2=0.0628 (R1=\u2211(Fo\u2212Fc)\/\u2211Foobserved data wR2={\u2211[w(F${{2\\hfill \\atop {\\rm o}\\hfill}}$\u2212F${{2\\hfill \\atop {\\rm c}\\hfill}}$)2]\/\u2211[w(F${{2\\hfill \\atop {\\rm o}\\hfill}}$)2]}1\/2for all data) GOF=1.102 \u0394\u03c1max=0.896 e\u2009\u00c5\u22123. Crystallographic data for C28H30RuSn (6): monoclinicP21\/c a=17.8377(4) b=12.4501(3) c=31.9136(7) \u00c5 \u03b2=93.826(1)\u00b0 V=7071.6(3) \u00c53 Z=12 \u03bc=1.712 mm\u22121 \u03c1calcd=1.652 Mg\u2009m\u22123 150(1) K Nonius Kappa\u2010CCD diffractometer using graphite\u2010monochromated MoK\u03b1radiation (\u03bb=0.71073 \u00c5) pale yellow crystal (0.26\u00d70.26\u00d70.03 mm3). Of 36\u2009931 reflections collected (5.1\u22642\u03b8\u226455.0\u00b0) 16\u2009057 were independentRint=0.0657 and 10\u2009129 were observed withFo\u22654\u03c3(Fo). Solution and refinement as for5 R1=0.0557 wR2=0.1296 (R1=\u2211(Fo\u2212Fc)\/\u2211Foobserved data wR2={\u2211[w(F${{2\\hfill \\atop {\\rm o}\\hfill}}$\u2212F${{2\\hfill \\atop {\\rm c}\\hfill}}$)2]\/\u2211[w(F${{2\\hfill \\atop {\\rm o}\\hfill}}$)2]}1\/2for all data) GOF=1.015 \u0394\u03c1max=1.47 e\u2009\u00c5\u22123. CCDC\u2010231\u2009377 (6) and \u2010231\u2009378 (5) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk\/conts\/retrieving.html (or from the Cambridge Crystallographic Data Centre 12 Union Road Cambridge CB2\u20091EZ UK; fax: (+44)\u20091223\u2010336\u2010033; or deposit@ccdc.cam.ac.uk)."},{"key":"e_1_2_3_36_2","doi-asserted-by":"publisher","DOI":"10.1021\/om00081a036"},{"key":"e_1_2_3_37_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00341a081"},{"key":"e_1_2_3_38_2","unstructured":"Although the1H NMR spectrum of the crude reaction mixture showed the formation of6in approximately 40\u2009% yield the purification of the compound was difficult owing to the similar solubilities of6and the by\u2010products."},{"key":"e_1_2_3_39_2","unstructured":"\u00a0"},{"key":"e_1_2_3_40_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00068a096"},{"key":"e_1_2_3_41_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.19970030413"},{"key":"e_1_2_3_42_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00744a011"},{"key":"e_1_2_3_43_2","unstructured":"\u00a0"},{"key":"e_1_2_3_44_2","doi-asserted-by":"publisher","DOI":"10.1021\/om00005a051"},{"key":"e_1_2_3_45_2","doi-asserted-by":"publisher","DOI":"10.1021\/om980087l"},{"key":"e_1_2_3_46_2","unstructured":"The average bond length of 119 Ru\uf8ffSn bonds found in a CSD database search was 266(6) pm."},{"key":"e_1_2_3_47_2","doi-asserted-by":"publisher","DOI":"10.1039\/b004585n"},{"key":"e_1_2_3_48_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(86)80133-4"},{"key":"e_1_2_3_49_2","doi-asserted-by":"publisher","DOI":"10.1021\/om9901224"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fanie.200454022","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.200454022","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,10,11]],"date-time":"2023-10-11T00:40:39Z","timestamp":1696984839000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.200454022"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2004,6,16]]},"references-count":52,"journal-issue":{"issue":"25","published-print":{"date-parts":[[2004,6,21]]}},"alternative-id":["10.1002\/anie.200454022"],"URL":"https:\/\/doi.org\/10.1002\/anie.200454022","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2004,6,16]]}}}