{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,18]],"date-time":"2026-08-18T15:51:11Z","timestamp":1787068271422,"version":"build-2736575974"},"reference-count":41,"publisher":"Wiley","issue":"7","license":[{"start":{"date-parts":[[2005,1,3]],"date-time":"2005-01-03T00:00:00Z","timestamp":1104710400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2005,2,4]]},"DOI":"10.1002\/anie.200462205","type":"journal-article","created":{"date-parts":[[2005,1,3]],"date-time":"2005-01-03T10:19:10Z","timestamp":1104747550000},"page":"1088-1092","source":"Crossref","is-referenced-by-count":55,"title":["A Rock\u2010Salt\u2010Like Lattice Structure Consisting of Monocationic and Monoanionic Au\n                    <sup>I<\/sup>\n                    Ag\n                    <sup>I<\/sup>\n                    Cu\n                    <sup>II<\/sup>\n                    Supramolecular Cages of\n                    <scp>D<\/scp>\n                    \u2010Penicillaminate"],"prefix":"10.1002","volume":"44","author":[{"given":"Atsushi","family":"Toyota","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tadashi","family":"Yamaguchi","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Asako","family":"Igashira\u2010Kamiyama","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tatsuya","family":"Kawamoto","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Takumi","family":"Konno","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2005,1,3]]},"reference":[{"key":"e_1_2_3_1_2","unstructured":"\u00a0"},{"key":"e_1_2_3_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr9601324"},{"key":"e_1_2_3_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr990110s"},{"key":"e_1_2_3_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20010601)113:11<2076::AID-ANGE2076>3.0.CO;2-S"},{"key":"e_1_2_3_4_3","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20010601)40:11<2022::AID-ANIE2022>3.0.CO;2-D"},{"key":"e_1_2_3_5_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(01)00301-0"},{"key":"e_1_2_3_6_2","doi-asserted-by":"publisher","DOI":"10.1039\/b305705b"},{"key":"e_1_2_3_7_2","unstructured":"\u00a0"},{"key":"e_1_2_3_8_2","doi-asserted-by":"publisher","DOI":"10.1246\/cl.2000.852"},{"key":"e_1_2_3_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20010504)113:9<1815::AID-ANGE18150>3.0.CO;2-N"},{"key":"e_1_2_3_9_3","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20010504)40:9<1765::AID-ANIE17650>3.0.CO;2-K"},{"key":"e_1_2_3_10_2","doi-asserted-by":"publisher","DOI":"10.1246\/cl.2002.304"},{"key":"e_1_2_3_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200290024"},{"key":"e_1_2_3_11_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200290025"},{"key":"e_1_2_3_12_2","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.77.627"},{"key":"e_1_2_3_13_2","unstructured":"\u00a0"},{"key":"e_1_2_3_14_2","doi-asserted-by":"publisher","DOI":"10.1039\/DT9940003183"},{"key":"e_1_2_3_15_2","doi-asserted-by":"publisher","DOI":"10.1107\/S0108270197009724"},{"key":"e_1_2_3_16_2","unstructured":"\u00a0"},{"key":"e_1_2_3_17_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3765(20000218)6:4<636::AID-CHEM636>3.0.CO;2-A"},{"key":"e_1_2_3_18_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0020-1693(02)00864-2"},{"key":"e_1_2_3_19_2","doi-asserted-by":"publisher","DOI":"10.1002\/1099-0682(200203)2002:3<750::AID-EJIC750>3.0.CO;2-2"},{"key":"e_1_2_3_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic030200m"},{"key":"e_1_2_3_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic0499244"},{"key":"e_1_2_3_22_2","unstructured":"A white crystalline sample of1was prepared in 84\u2009% yield from AuIandD\u2010H2pen according to a modified literature method[3b]using chloro(thiodiethanol)gold(I) instead of chloro(tetrahydrothiophene)gold(I). Elemental analysis (%) calcd for NH4[Au(D\u2010Hpen)2]\u22c511\/3\u2009H2O (C10H31.3AuN3O7.67S2): C 20.80 H 5.47 N 7.28; found: C 20.84 H 5.14 N 7.23;1H NMR (270 MHz D2O\/1\u2009MNa2CO3):\u03b4=1.30 and 1.61 (CH3) 3.47 ppm (CH);13C NMR (68 MHz D2O\/1\u2009MNa2CO3):\u03b4=31.06 and 37.99 (CH3) 51.02 (SC) 70.71 (CH) 177.22 ppm (COO)."},{"key":"e_1_2_3_23_2","unstructured":"A solution of AgNO3(0.23 g 1.36 mmol) in water (24 mL) was added to a stirred solution of1(0.80 g 1.39 mmol) in water (12 mL) which gave a white precipitate immediately. After stirring at RT for 90 min followed by cooling in an ice bath for 30 min the resulting white powder of2was collected by filtration and washed with water and methanol. Yield: 0.83 g (95\u2009%); elemental analysis (%) calcd for [Au2Ag2(D\u2010Hpen)4]\u22c54\u2009H2O (C20H48Ag2Au2N4O12S4): C 18.85 H 3.80 N 4.40; found: C 18.75 H 3.62 N 4.50;1H NMR (270 MHz D2O\/1\u2009MNa2CO3):\u03b4=1.40 and 1.64 (CH3) 3.36 ppm (CH);13C NMR (68 MHz D2O\/1\u2009MNa2CO3):\u03b4=31.22 and 38.11 (CH3) 54.33 (SC) 71.00 (CH) 180.52 ppm (COO). Excitation of a solid sample of2at 308 nm at RT and 77 K gave a strong emission band at 709 and 672 nm respectively."},{"key":"e_1_2_3_24_2","unstructured":"Crystal structure analysis for3: Bruker SMART\u20101000 CCD\u2010based diffractometer T=213 K MoK\u03b1radiation (\u03bb=0.71069 \u00c5). The structure was solved by the Patterson method with DIRDIF92 (PATTY) and refined by full\u2010matrix least\u2010squares techniques onF2using SHELXL\u201093. Hydrogen atoms were not included in the calculations. C120H265Ag17Au12Cl5Cu12N24O72.5S24 Mr=9111.12 crystal size 0.2\u00d70.2\u00d70.1 mm3 cubic space groupP213 a=32.749(2) \u00c5 V=35\u2009124(3) \u00c53 Z=4 \u03c1calcd=1.723 g\u2009cm\u22123 \u03bc=6.851 mm\u22121 \u03c9\u22122\u2009\u03b8scan mode 2\u2009\u03b8max=50.0 221\u2009649 reflections collected 20\u2009699 independent reflections 15\u2009791 observed reflections (I>2\u2009\u03c3(I)) 880 parameters semiempirical absorption corrections with SADABS max.\/min. transmission 0.478\/0.345 R1 (I>2\u2009\u03c3(I))=0.055 wR2 (all data)=0.174 Flack parameter 0.010(6) residual electron density 3.34\/\u22121.55 e\u2009\u00c5\u22123(the peaks larger than 1.5 e\u2009\u00c5\u22123were found in the vicinity of heavy atoms). The disordered Ag and O atoms in cluster3\u2009bwere refined with a site occupancy factor of 2\/3 which gave satisfactory thermal parameters. CCDC 247589 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from the Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk\/data_request\/cif."},{"key":"e_1_2_3_25_2","unstructured":"Eachtrans\u2010[CuN2O2(H2O)] moiety of3\u2009bis triply hydrogen bonded to the adjacenttrans\u2010[CuN2O2(H2O)] moiety of3\u2009athrough COO(3b)\u22c5\u22c5\u22c5H2O(3a)(2.82(2) \u00c5) and COO(3a)\u22c5\u22c5\u22c5H2N(3b)(2.86(2) \u00c5) besides COO(3a)\u22c5\u22c5\u22c5H2O(3b)(2.85(2) \u00c5). The distance between the encapsulated Cl\u2212ions in3\u2009aand3\u2009bconnected by hydrogen bonds (Cl(3a)\u22c5\u22c5\u22c5Cl(3b)17.015(6) \u00c5) is comparable with that for connection by a Cu\uf8ffOCOOcoordination bond (Cl(3a)\u22c5\u22c5\u22c5Cl(3b)16.145(6) \u00c5). Furthermore thecisangles among the encapsulated Cl\u2212ions in3\u2009aand3\u2009bare roughly close to the octahedral angle of 90\u00b0 (Cl(3a)\u2010Cl(3b)\u2010Cl(3a)=80.13(2)\u2013100.75(3)\u00b0 Cl(3b)\u2010Cl(3a)\u2010Cl(3b)=79.73(3)\u2013100.33(3)\u00b0)."},{"key":"e_1_2_3_26_2","unstructured":"Once isolated from the mother liquor a crystalline sample of3loses water molecules of solvation as revealed by the loss of surface luster. The powder X\u2010ray diffraction pattern of a dried sample of3shows small peaks indicative of the collapse of the lattice structure after the removal of solvating water molecules. Thermogravimetric (TGA) analysis shows a gradual weight loss of 16.5\u2009% up to 85\u2009\u00b0C followed by a quick weight loss of 20.1\u2009% at around 145\u2009\u00b0C (see Supporting Information). The remaining weight at 150\u2009\u00b0C is 62.5\u2009% which corresponds well with that of the Au Ag Cu and S atoms in3(62.9\u2009% calcd). This implies that the pyrolysis of organic groups and dehydration are complete in a relatively low temperature range."},{"key":"e_1_2_3_27_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200305640"},{"key":"e_1_2_3_28_2","unstructured":"A solution of AgNO3(0.15 g 0.87 mmol) in an acetate buffer solution (pH 6.2 150 mL) was added to a solution of1(0.50 g 0.87 mmol) in an acetate buffer solution (150 mL). After stirring at RT for 30 min a solution containing Cu(NO3)2\u22c53\u2009H2O (0.42 g 1.7 mmol) and NH4Cl (0.05 g) in an acetate buffer (150 mL) was added. The mixture was stirred at RT overnight concentrated to ca. 110 mL and then allowed to stand at RT for several days to give blue crystals of3(0.42 g 67\u2009% based on Au)."},{"key":"e_1_2_3_29_2","unstructured":"All crystalline samples of3obtained from different synthetic routes showed identical IR spectra. Furthermore eight crystals selected from independent synthetic crops had identical unit\u2010cell parameters and four of them gave the same X\u2010ray analytical data."},{"key":"e_1_2_3_30_2","unstructured":"\u00a0"},{"key":"e_1_2_3_31_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20010202)113:3<502::AID-ANGE502>3.0.CO;2-A"},{"key":"e_1_2_3_31_3","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20010202)40:3<486::AID-ANIE486>3.0.CO;2-P"},{"key":"e_1_2_3_32_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20010917)113:18<3572::AID-ANGE3572>3.0.CO;2-M"},{"key":"e_1_2_3_32_3","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20010917)40:18<3464::AID-ANIE3464>3.0.CO;2-M"},{"key":"e_1_2_3_33_2","doi-asserted-by":"publisher","DOI":"10.1246\/cl.2002.980"},{"key":"e_1_2_3_34_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200200551"},{"key":"e_1_2_3_34_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200200551"},{"key":"e_1_2_3_35_2","doi-asserted-by":"publisher","DOI":"10.1039\/b300887h"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fanie.200462205","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.200462205","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.200462205","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.200462205","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,9,1]],"date-time":"2023-09-01T05:58:57Z","timestamp":1693547937000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.200462205"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2005,1,3]]},"references-count":41,"journal-issue":{"issue":"7","published-print":{"date-parts":[[2005,2,4]]}},"alternative-id":["10.1002\/anie.200462205"],"URL":"https:\/\/doi.org\/10.1002\/anie.200462205","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2005,1,3]]}}}