{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T16:10:50Z","timestamp":1790007050603,"version":"4.0.1"},"reference-count":30,"publisher":"Wiley","issue":"13","license":[{"start":{"date-parts":[[2005,2,23]],"date-time":"2005-02-23T00:00:00Z","timestamp":1109116800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2005,3,18]]},"DOI":"10.1002\/anie.200462417","type":"journal-article","created":{"date-parts":[[2005,2,23]],"date-time":"2005-02-23T11:49:03Z","timestamp":1109159343000},"page":"1990-1993","source":"Crossref","is-referenced-by-count":43,"title":["Acid\u2010Initiated Stereospecific Polymerization of Isocyanopeptides"],"prefix":"10.1002","volume":"44","author":[{"given":"Gerald A.","family":"Metselaar","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jeroen J. L. M.","family":"Cornelissen","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alan E.","family":"Rowan","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Roeland J. M.","family":"Nolte","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2005,3,16]]},"reference":[{"key":"e_1_2_2_1_2","doi-asserted-by":"publisher","DOI":"10.1007\/BF01809580"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200290004"},{"key":"e_1_2_2_2_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200290005"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20020402)114:7<1187::AID-ANGE1187>3.0.CO;2-S"},{"key":"e_1_2_2_3_3","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20020402)41:7<1139::AID-ANIE1139>3.0.CO;2-9"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200351210"},{"key":"e_1_2_2_4_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200351210"},{"key":"e_1_2_2_5_2","unstructured":"\u00a0"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1039\/cs9942300011"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr990126i"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1062224"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/ma50002a007"},{"key":"e_1_2_2_10_2","unstructured":"\u00a0"},{"key":"e_1_2_2_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/ma011946b"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/pola.10713"},{"key":"e_1_2_2_13_2","unstructured":"Earlier molecular\u2010modeling studies revealed that theL L\u2010PIAA polymer has a less favorable conformation than theL D\u2010PIAA polymer due to unfavorable steric interactions between the side chainsnandn+1.[6]In the polymerization reaction a similar unfavorable interaction is probably present which prevents the polymerization reaction ofL L\u2010IAA from taking place."},{"key":"e_1_2_2_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/recl.19730920713"},{"key":"e_1_2_2_15_2","unstructured":"Under the reaction conditions a water content of 0.03\u2009% is sufficient for complete hydration of the isocyanide monomers."},{"key":"e_1_2_2_16_2","first-page":"75","volume-title":"Coordination Polymerization: A Memorial to Karl Ziegler","author":"Pino P.","year":"1975"},{"key":"e_1_2_2_17_2","unstructured":"This is indeed a remarkable result as statistically some polymer should be formed. IR spectroscopy however clearly showed that virtually no monomer is consumed. This subject is currently being studied further."},{"key":"e_1_2_2_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja035302q"},{"key":"e_1_2_2_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr0000978"},{"key":"e_1_2_2_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1099-0518(199808)36:11<1855::AID-POLA19>3.0.CO;2-D"},{"key":"e_1_2_2_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/ma021287i"},{"key":"e_1_2_2_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3757(19991102)111:21<3328::AID-ANGE3328>3.0.CO;2-Z"},{"key":"e_1_2_2_22_3","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3773(19991102)38:21<3138::AID-ANIE3138>3.0.CO;2-C"},{"key":"e_1_2_2_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00105a043"},{"key":"e_1_2_2_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/ma021432s"},{"key":"e_1_2_2_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/ma00181a050"},{"key":"e_1_2_2_26_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.280.5368.1427"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fanie.200462417","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.200462417","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,10,7]],"date-time":"2023-10-07T12:48:46Z","timestamp":1696682926000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.200462417"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2005,3,16]]},"references-count":30,"journal-issue":{"issue":"13","published-print":{"date-parts":[[2005,3,18]]}},"alternative-id":["10.1002\/anie.200462417"],"URL":"https:\/\/doi.org\/10.1002\/anie.200462417","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2005,3,16]]}}}