{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,28]],"date-time":"2026-09-28T22:09:52Z","timestamp":1790633392467,"version":"4.1.0"},"reference-count":48,"publisher":"Wiley","issue":"42","license":[{"start":{"date-parts":[[2005,10,5]],"date-time":"2005-10-05T00:00:00Z","timestamp":1128470400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2005,10,28]]},"DOI":"10.1002\/anie.200501911","type":"journal-article","created":{"date-parts":[[2005,10,5]],"date-time":"2005-10-05T04:48:39Z","timestamp":1128487719000},"page":"6867-6871","source":"Crossref","is-referenced-by-count":49,"title":["[Re\n                    <sub>12<\/sub>\n                    CS\n                    <sub>17<\/sub>\n                    (CN)\n                    <sub>6<\/sub>\n                    ]\n                    <sup>\n                      <i>n<\/i>\n                      \u2212\n                    <\/sup>\n                    (\n                    <i>n<\/i>\n                    =6, 8): A Sulfido\u2013Cyanide Rhenium Cluster with an Interstitial Carbon Atom"],"prefix":"10.1002","volume":"44","author":[{"given":"Yuri V.","family":"Mironov","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nikolai G.","family":"Naumov","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Svetlana G.","family":"Kozlova","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sung\u2010Jin","family":"Kim","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Vladimir E.","family":"Fedorov","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2005,10,25]]},"reference":[{"key":"e_1_2_3_1_2","unstructured":"\u00a0"},{"key":"e_1_2_3_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/0277-5387(95)00147-K"},{"key":"e_1_2_3_3_2","first-page":"885","volume":"68","author":"Slougui A.","year":"1995","journal-title":"Croat. Chem. Acta"},{"key":"e_1_2_3_4_2","doi-asserted-by":"publisher","DOI":"10.1007\/BF02763902"},{"key":"e_1_2_3_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja962264k"},{"key":"e_1_2_3_6_2","doi-asserted-by":"publisher","DOI":"10.1023\/A:1016053305232"},{"key":"e_1_2_3_7_2","doi-asserted-by":"publisher","DOI":"10.1246\/cl.1999.1121"},{"key":"e_1_2_3_8_2","doi-asserted-by":"publisher","DOI":"10.1039\/B205241E"},{"key":"e_1_2_3_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm980564q"},{"key":"e_1_2_3_10_2","unstructured":"\u00a0"},{"key":"e_1_2_3_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3757(19980703)110:13\/14<2043::AID-ANGE2043>3.0.CO;2-G"},{"key":"e_1_2_3_11_3","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3773(19980803)37:13\/14<1943::AID-ANIE1943>3.0.CO;2-Q"},{"key":"e_1_2_3_12_2","doi-asserted-by":"publisher","DOI":"10.1007\/BF02742011"},{"key":"e_1_2_3_13_2","doi-asserted-by":"publisher","DOI":"10.1039\/b008040n"},{"key":"e_1_2_3_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200351595"},{"key":"e_1_2_3_14_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200351595"},{"key":"e_1_2_3_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja994186h"},{"key":"e_1_2_3_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0110473"},{"key":"e_1_2_3_17_2","doi-asserted-by":"publisher","DOI":"10.1039\/b104276a"},{"key":"e_1_2_3_18_2","doi-asserted-by":"publisher","DOI":"10.1039\/b403995e"},{"key":"e_1_2_3_19_2","doi-asserted-by":"publisher","DOI":"10.1007\/BF02903545"},{"key":"e_1_2_3_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic990936c"},{"key":"e_1_2_3_21_2","unstructured":"The reaction of ReS2with KCN has been studied in the temperature range from 650 to 800\u2009\u00b0C by using different ReS2\/KCN ratios. We found that for mass ratios of ReS2\/KCN from 1:2 to 1:20 the main product of the reaction was K8[Re12CS17(CN)6]. To understand the conditions that yield [Re12CS17(CN)6]8\u2212 KCs3[Re6S8(CN)6] was used as the starting material. It was found that [Re6S8(CN)6]4\u2212transforms into [Re12CS17(CN)6]8\u2212if the temperature rises to between 700 and 800\u2009\u00b0C. Furthermore the reaction of [Re6S8Br2] with KCN at high temperature also gave the [Re12CS17(CN)6]8\u2212cluster whereas below 650\u2009\u00b0C [Re6S8(CN)6]4\u2212formed. These data indicate that [Re12CS17(CN)6]8\u2212cluster is thermodynamically stable within the 650 to 800\u2009\u00b0C range."},{"key":"e_1_2_3_22_2","unstructured":"X\u2010ray structural analyses: Bruker SMART CCD diffractometer with area detector graphite monochromator MoK\u03b1radiation (\u03bb=0.71073 \u00c5) SHELX\u201097 program[27]for structure solution (direct methods) and refinement (full\u2010matrix least\u2010squares onF\u20092).1: C7K8N6Re12S17(Mr=3260.35) crystal size 0.14\u00d70.13\u00d70.03 mm monoclinic space groupP21\/m a=9.1806(11) b=29.210(2) c=9.2006(8) \u00c5 \u03b2=119.777(1)o V=2141.5(4) \u00c53 Z=2 \u03c1calcd=5.056 g\u2009cm\u22123 \u03bc=35.381 mm\u22121 2.55<\u03b8< 28.21\u00b0 T=293(2) K face\u2010indexed absorption correction (transmission coefficient: 0.0831 0.4598). Reflections: 13\u2009011 collected 4890 unique (Rint=0.0512) 3756 observed (I>2\u03c3(I)). There were 239 parameters refined withR=0.0619 (I>2\u03c3(I)) wR2=0.1693 (all data) GOF=1.107 residual electron density: +4.889\/\u22124.827 e\u2009\u00c5\u22123.2: C7H40K6N6O20Re12S17(Mr=3542.47) crystal size 0.12\u00d70.12\u00d70.03 mm hexagonal space groupP63\/mmc a=10.8843(8) c=27.840(4) \u00c5 V=2856.3(5) \u00c53 Z=2 \u03c1calcd=4.119 g\u2009cm\u22123 \u03bc=26.427 mm\u22121 2.16<\u03b8<28.24\u00b0 T=293(2) K face\u2010indexed absorption correction (transmission coefficient: 0.1436 0.5044). Reflections: 16\u2009972 collected 1383 unique (Rint=0.0384) 1236 observed (I>2\u03c3(I)) 82 parameters refined withR=0.0263 (I>2\u03c3(I)) wR2=0.0589 (all data) GOF=1.107 residual electron density: +1.643\/\u22122.408 e\u2009\u00c5\u22123.3: C7Cs6N6Re12S17(Mr=3746.34) crystal size 0.09\u00d70.09\u00d70.01 mm hexagonal space groupP$\\bar 6$2m a=9.7270(15) c=14.629(3) \u00c5 V=1198.7(4) \u00c53 Z=1 \u03c1calcd=5.190 g\u2009cm\u22123 \u03bc=35.407 mm\u22121 2.42<\u03b8<28.18\u00b0 T=293(2) K face\u2010indexed absorption correction (transmission coefficient: 0.1428 0.6760). Reflections: 7284 collected 1105 unique (Rint=0.0672) 913 observed (I>2\u03c3(I)) 59 parameters refined withR=0.0340 (I>2\u03c3(I)) wR2=0.0915 (all data) GOF=1.046 residual electron density: +2.391\/\u22121.234 e\u2009\u00c5\u22123. Further details on the crystal structure investigation may be obtained from the Fachinformationszentrum Karlsruhe 76344 Eggenstein\u2010Leopoldshafen Germany (fax: (+49)\u20097247\u2010808\u2010666; e\u2010mail: crysdata@fiz\u2010karlsruhe.de) on quoting the depository numbers CSD\u2010415476\u2013415478."},{"key":"e_1_2_3_23_2","doi-asserted-by":"publisher","DOI":"10.1023\/A:1025575413731"},{"key":"e_1_2_3_24_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-5088(85)90417-5"},{"key":"e_1_2_3_25_2","doi-asserted-by":"publisher","DOI":"10.1002\/9783527618316.ch5f"},{"key":"e_1_2_3_26_2","unstructured":"To determine isotropic chemical shifts of carbons the13C magic\u2010angle spinning (MAS) NMR measurements were made by using a BRUKER Bio\u2010Spin Avance 400 MHz solid\u2010state NMR spectrometer. The spinning rate was 20 kHz the \u03c0\/2 pulse duration was 5 s the relaxation delay was 10 s. About 200 free induction decays were accumulated at room temperature. TMS was used as a reference. The15N NMR spectrum contained one sharp signal at 311 ppm (relative to NH3) which corresponds to coordinated cyano ligands. No signal attributable to an interstitial nitrogen atom was found. The diamagnetic properties of compounds1\u20133indicated the presence of an interstitial atom with an even number of electrons."},{"key":"e_1_2_3_27_2","unstructured":"\u00a0"},{"key":"e_1_2_3_28_2","unstructured":"Amsterdam Density Functional (ADF) program Release 2003.02 Vrije Universteit Amsterdam The Netherlands 2002;"},{"key":"e_1_2_3_29_2","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.1056"},{"key":"e_1_2_3_30_2","unstructured":"It is interesting to note that in rhenium cluster chemistry there are several types of cluster in which the rhenium atoms have a +IIIoxidation state; besides [Re12CS17(CN)6]8\u2212 there are three well\u2010known cluster complexes namely dinuclear [Re2X8]2\u2212with quadruple Re\uf8ffRe bond trigonal [Re3X12]3\u2212with double Re\uf8ffRe bonds and octahedral [Re6Q8X6]4\u2212with single Re\uf8ffRe bonds (X=halide ions)."},{"key":"e_1_2_3_31_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0020-1693(00)87518-0"},{"key":"e_1_2_3_32_2","doi-asserted-by":"publisher","DOI":"10.1246\/cl.1996.555"},{"key":"e_1_2_3_33_2","doi-asserted-by":"publisher","DOI":"10.1246\/cl.1997.967"},{"key":"e_1_2_3_34_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic970727x"},{"key":"e_1_2_3_35_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja9638519"},{"key":"e_1_2_3_36_2","unstructured":"\u00a0"},{"key":"e_1_2_3_37_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.200300069"},{"key":"e_1_2_3_38_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja035962v"},{"key":"e_1_2_3_39_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200462585"},{"key":"e_1_2_3_39_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200462585"},{"key":"e_1_2_3_40_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19941061909"},{"key":"e_1_2_3_40_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199419431"},{"key":"e_1_2_3_41_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00005a017"},{"key":"e_1_2_3_42_2","first-page":"38","author":"Perrin C.","year":"1983","journal-title":"J. Chem. Res."},{"key":"e_1_2_3_43_2","unstructured":"G. M. Sheldrick SHELXL\u201097 Program for Crystal Structure Refinement University of G\u00f6ttingen Germany 1997;"},{"key":"e_1_2_3_44_2","unstructured":"G. M. Sheldrick SHELXS\u201097 Program for Crystal Structure Solution University of G\u00f6ttingen Germany 1997."}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fanie.200501911","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.200501911","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,10,10]],"date-time":"2023-10-10T12:56:13Z","timestamp":1696942573000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.200501911"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2005,10,25]]},"references-count":48,"journal-issue":{"issue":"42","published-print":{"date-parts":[[2005,10,28]]}},"alternative-id":["10.1002\/anie.200501911"],"URL":"https:\/\/doi.org\/10.1002\/anie.200501911","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2005,10,25]]}}}