{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,2]],"date-time":"2026-10-02T12:12:08Z","timestamp":1790943128770,"version":"4.1.0"},"reference-count":71,"publisher":"Wiley","issue":"35","license":[{"start":{"date-parts":[[2005,8,24]],"date-time":"2005-08-24T00:00:00Z","timestamp":1124841600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2005,9,5]]},"DOI":"10.1002\/anie.200502140","type":"journal-article","created":{"date-parts":[[2005,8,24]],"date-time":"2005-08-24T10:18:44Z","timestamp":1124878724000},"page":"5664-5667","source":"Crossref","is-referenced-by-count":223,"title":["Versatile Direct Synthesis of Oligosubstituted Pyrroles by Cycloaddition of \u03b1\u2010Metalated Isocyanides to Acetylenes"],"prefix":"10.1002","volume":"44","author":[{"given":"Oleg V.","family":"Larionov","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Armin","family":"de Meijere","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2005,9]]},"reference":[{"key":"e_1_2_4_1_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200462252"},{"key":"e_1_2_4_1_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200462252"},{"key":"e_1_2_4_1_4","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200462069"},{"key":"e_1_2_4_1_5","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200462069"},{"key":"e_1_2_4_1_6","first-page":"1753","author":"Hoffmann H.","year":"2003","journal-title":"Synthesis"},{"key":"e_1_2_4_1_7","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20020415)114:8<1480::AID-ANGE1480>3.0.CO;2-8"},{"key":"e_1_2_4_1_8","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20020415)41:8<1422::AID-ANIE1422>3.0.CO;2-O"},{"key":"e_1_2_4_1_9","doi-asserted-by":"publisher","DOI":"10.1021\/ja026130k"},{"key":"e_1_2_4_1_10","doi-asserted-by":"publisher","DOI":"10.1002\/1521-4184(200106)334:6<183::AID-ARDP183>3.0.CO;2-U"},{"key":"e_1_2_4_1_11","doi-asserted-by":"publisher","DOI":"10.1021\/np000160o"},{"key":"e_1_2_4_1_12","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3757(19991203)111:23<3751::AID-ANGE3751>3.0.CO;2-2"},{"key":"e_1_2_4_1_13","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3773(19991203)38:23<3537::AID-ANIE3537>3.0.CO;2-R"},{"key":"e_1_2_4_1_14","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3757(19991115)111:22<3556::AID-ANGE3556>3.0.CO;2-I"},{"key":"e_1_2_4_1_15","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3773(19991115)38:22<3359::AID-ANIE3359>3.0.CO;2-K"},{"key":"e_1_2_4_1_16","doi-asserted-by":"publisher","DOI":"10.1038\/387202a0"},{"key":"e_1_2_4_2_2","doi-asserted-by":"publisher","DOI":"10.7164\/antibiotics.50.402"},{"key":"e_1_2_4_2_3","doi-asserted-by":"publisher","DOI":"10.1093\/jac\/42.1.121"},{"key":"e_1_2_4_2_4","doi-asserted-by":"publisher","DOI":"10.1016\/S0006-2952(99)00382-2"},{"key":"e_1_2_4_2_5","doi-asserted-by":"publisher","DOI":"10.1016\/j.farmac.2003.12.005"},{"key":"e_1_2_4_2_6","doi-asserted-by":"publisher","DOI":"10.1021\/jm00105a056"},{"key":"e_1_2_4_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20020517)114:10<1835::AID-ANGE1835>3.0.CO;2-C"},{"key":"e_1_2_4_3_3","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20020517)41:10<1757::AID-ANIE1757>3.0.CO;2-0"},{"key":"e_1_2_4_3_4","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.200300078"},{"key":"e_1_2_4_3_5","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3757(20000515)112:10<1847::AID-ANGE1847>3.0.CO;2-G"},{"key":"e_1_2_4_3_6","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3773(20000515)39:10<1777::AID-ANIE1777>3.0.CO;2-E"},{"key":"e_1_2_4_3_7","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3757(20000204)112:3<612::AID-ANGE612>3.0.CO;2-2"},{"key":"e_1_2_4_3_8","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3773(20000204)39:3<599::AID-ANIE599>3.0.CO;2-X"},{"key":"e_1_2_4_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja047396p"},{"key":"e_1_2_4_4_3","doi-asserted-by":"publisher","DOI":"10.1021\/ol0489088"},{"key":"e_1_2_4_4_4","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200351170"},{"key":"e_1_2_4_4_5","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200351170"},{"key":"e_1_2_4_4_6","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200390001"},{"key":"e_1_2_4_4_7","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200390064"},{"key":"e_1_2_4_4_8","doi-asserted-by":"publisher","DOI":"10.1021\/ol036180"},{"key":"e_1_2_4_4_9","doi-asserted-by":"publisher","DOI":"10.1021\/ol0267073"},{"key":"e_1_2_4_4_10","doi-asserted-by":"publisher","DOI":"10.1021\/ja0058684"},{"key":"e_1_2_4_4_11","doi-asserted-by":"publisher","DOI":"10.1021\/ja002225f"},{"key":"e_1_2_4_4_12","doi-asserted-by":"publisher","DOI":"10.1021\/ja0004736"},{"key":"e_1_2_4_5_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(01)85244-8"},{"key":"e_1_2_4_5_3","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4020(01)89069-4"},{"key":"e_1_2_4_5_4","doi-asserted-by":"publisher","DOI":"10.1021\/jo00034a011"},{"key":"e_1_2_4_5_5","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.67.1441"},{"key":"e_1_2_4_5_6","doi-asserted-by":"publisher","DOI":"10.1016\/0040-4020(95)00851-X"},{"key":"e_1_2_4_5_7","doi-asserted-by":"publisher","DOI":"10.1016\/0040-4020(96)00941-6"},{"key":"e_1_2_4_5_8","doi-asserted-by":"publisher","DOI":"10.1055\/s-1997-1360"},{"key":"e_1_2_4_5_9","doi-asserted-by":"publisher","DOI":"10.1080\/00397919808007011"},{"key":"e_1_2_4_5_10","doi-asserted-by":"publisher","DOI":"10.1021\/jo972216y"},{"key":"e_1_2_4_5_11","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4020(01)00773-6"},{"key":"e_1_2_4_6_2","doi-asserted-by":"publisher","DOI":"10.1248\/cpb.27.2857"},{"key":"e_1_2_4_7_2","doi-asserted-by":"publisher","DOI":"10.2174\/0929867043364973"},{"key":"e_1_2_4_7_3","doi-asserted-by":"publisher","DOI":"10.1111\/j.1527-3458.2003.tb00244.x"},{"key":"e_1_2_4_7_4","doi-asserted-by":"publisher","DOI":"10.1016\/S0065-2571(96)00021-0"},{"key":"e_1_2_4_8_2","unstructured":"Isocyanide cycloadditions across double bonds. Lewis acid catalysis:"},{"key":"e_1_2_4_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo00821a011"},{"key":"e_1_2_4_10_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(00)98925-1"},{"key":"e_1_2_4_11_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4020(98)01216-2"},{"key":"e_1_2_4_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19740862403"},{"key":"e_1_2_4_12_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.197407891"},{"key":"e_1_2_4_13_2","unstructured":"The isocyanide dimer11was reported to be formed in the presence of an equimolar amount of AgOAc (see ref. [8c]). The rapid dimerization observed here may be due to the strong influence of the acetylene component on the catalytic activity of AgI."},{"key":"e_1_2_4_14_2","unstructured":"Further metal compounds were tested but proved inefficient: CuOTf Cu(OTf)2 AgOTf Yb(OTf)3 PdO Ag2O GaCl3 BF3\u22c5OEt2 MgBr2 CoCl2."},{"key":"e_1_2_4_15_2","unstructured":"Commercial nanosize copper powder (Aldrich) was preactivated by heating in vacuo (0.05 mbar) at 150\u2009\u00b0C overnight and was stored under argon. The activity of thus prepared catalyst does not deteriorate within at least two weeks."},{"key":"e_1_2_4_16_2","doi-asserted-by":"publisher","DOI":"10.1016\/0010-8545(90)85016-L"},{"key":"e_1_2_4_16_3","doi-asserted-by":"publisher","DOI":"10.1021\/cr60293a001"},{"key":"e_1_2_4_16_4","first-page":"3871","author":"Seyden\u2010Penne J.","year":"1968","journal-title":"Bull. Soc. Chim. France"},{"key":"e_1_2_4_17_2","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.45.830"},{"key":"e_1_2_4_18_2","unstructured":"For some recently published transformations of pyrroles see: direct C\u2010arylation of pyrroles with free NH groups:"},{"key":"e_1_2_4_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja050279p"},{"key":"e_1_2_4_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol048367m"},{"key":"e_1_2_4_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja043047j"},{"key":"e_1_2_4_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol0476826"},{"key":"e_1_2_4_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja051875m"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fanie.200502140","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.200502140","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,10,11]],"date-time":"2023-10-11T11:03:42Z","timestamp":1697022222000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.200502140"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2005,9]]},"references-count":71,"journal-issue":{"issue":"35","published-print":{"date-parts":[[2005,9,5]]}},"alternative-id":["10.1002\/anie.200502140"],"URL":"https:\/\/doi.org\/10.1002\/anie.200502140","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2005,9]]}}}