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The final difference Fourier synthesis gave a min\/max residual electron density of \u22120.476\/+1.47 e\u2009\u00c5\u22123;"},{"key":"e_1_2_3_46_2","unstructured":"crystal data for4: C29H42SnN2 Mr=537.34 crystal dimensions 0.10\u00d70.05\u00d70.05 mm3 monoclinic space groupC2\/c a=25.209(5) b=15.139(3) c=14.682(3) \u00c5 \u03b2=94.92(3)\u00b0 V=5583(2) \u00c53 Z=8 \u03c1calcd=1.279 g\u2009cm\u22123 F(000)=2240 \u03bb=1.54178 \u00c5 T=100(2) K \u03bc(CuK\u03b1)=7.392 mm\u22121. Of the 22\u2009645 measured reflections 4000 were independent (R(int)=0.0315). The final refinements converged toR1=0.0216 forI>2\u2009\u03c3(I) wR2=0.0548 for all data. The final difference Fourier synthesis gave a min\/max residual electron density of \u22120.745\/ +0.749 e\u2009\u00c5\u22123;"},{"key":"e_1_2_3_47_2","unstructured":"data for the structures were collected on a Bruker three\u2010circle diffractometer which was equipped with a SMART 6000 CCD detector. Intensity measurements were performed on a rapidly cooled crystal in the ranges 6.54\u22642\u2009\u03b8\u2264117.94\u00b0 (3) and 6.82\u22642\u2009\u03b8\u2264117.80\u00b0 (4). The structures were solved by direct methods with SHELXS\u201097[23]and refined for all data by full\u2010matrix least squares onF2.[24]All non\u2010H atoms for3and4were refined anisotropically and all H atoms for3and4 except for the \u03b3\u2010C\uf8ffH hydrogen atoms H(3A) and H(3AA) in3(the packing diagram shows chain formation through weak intermolecular interactions between the lone pair of electrons at the Ge atom and the \u03b3\u2010C\uf8ffH hydrogen atom of another molecule) were included in geometrically idealized positions and refined with the riding model. Localization of the H(3A) and H(3AA) atoms from the electron\u2010density maps in3proved to be more accurate than fixing the atoms in the idealized positions and led to lowerR1 andwR2 values. The Sn\u2212H hydrogen atom in4was localized from the difference electron\u2010density map and refined isotropically withUijtied to the parent atom. CCDC\u2010291156 and CCDC\u2010291157 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk\/data_request\/cif."},{"key":"e_1_2_3_48_2","doi-asserted-by":"publisher","DOI":"10.1107\/S0108767390000277"},{"key":"e_1_2_3_49_2","unstructured":"G. M. Sheldrick SHELXL\u201097 Program for Crystal Structure Refinement University of G\u00f6ttingen G\u00f6ttingen (Germany) 1997."},{"key":"e_1_2_3_50_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.455583"},{"key":"e_1_2_3_51_2","unstructured":"Gaussian 03 (Revision C.02): M. J. 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