{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,2]],"date-time":"2026-06-02T16:24:17Z","timestamp":1780417457562,"version":"3.54.1"},"reference-count":35,"publisher":"Wiley","issue":"23","license":[{"start":{"date-parts":[[2007,5,2]],"date-time":"2007-05-02T00:00:00Z","timestamp":1178064000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2007,6,4]]},"DOI":"10.1002\/anie.200700619","type":"journal-article","created":{"date-parts":[[2007,5,2]],"date-time":"2007-05-02T14:15:44Z","timestamp":1178115344000},"page":"4379-4381","source":"Crossref","is-referenced-by-count":47,"title":["Highly Selective Thiiranation of 1,2\u2010Allenyl Sulfones with Br<sub>2<\/sub> and Na<sub>2<\/sub>S<sub>2<\/sub>O<sub>3<\/sub>: Mechanism and Asymmetric Synthesis of Alkylidenethiiranes"],"prefix":"10.1002","volume":"46","author":[{"given":"Chao","family":"Zhou","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chunling","family":"Fu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shengming","family":"Ma","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2007,5,24]]},"reference":[{"key":"e_1_2_2_1_2","doi-asserted-by":"publisher","DOI":"10.1002\/9783527619573.ch10"},{"key":"e_1_2_2_2_2","unstructured":"\u00a0"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo991574t"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(01)00634-7"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.200500296"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2004.05.160"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/cjoc.20040220922"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2005.05.077"},{"key":"e_1_2_2_9_2","unstructured":"\u00a0"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol034109y"},{"key":"e_1_2_2_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo049593c"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1039\/b300879g"},{"key":"e_1_2_2_13_2","unstructured":"\u00a0"},{"key":"e_1_2_2_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol006639p"},{"key":"e_1_2_2_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja034039q"},{"key":"e_1_2_2_16_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4020(01)00299-X"},{"key":"e_1_2_2_17_2","unstructured":"\u00a0"},{"key":"e_1_2_2_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo00301a006"},{"key":"e_1_2_2_19_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(00)93526-3"},{"key":"e_1_2_2_20_2","unstructured":"\u00a0"},{"key":"e_1_2_2_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00342a073"},{"key":"e_1_2_2_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00444a048"},{"key":"e_1_2_2_23_2","unstructured":"For the importance of thiiranes see:"},{"key":"e_1_2_2_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol0517269"},{"key":"e_1_2_2_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/ma047642h"},{"key":"e_1_2_2_26_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0480320"},{"key":"e_1_2_2_27_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo049857v"},{"key":"e_1_2_2_28_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr030005p"},{"key":"e_1_2_2_29_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo035467h"},{"key":"e_1_2_2_30_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo035229m"},{"key":"e_1_2_2_31_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja029292p"},{"key":"e_1_2_2_32_2","unstructured":"Crystal data for (E)\u20103\u2009m: C10H9BrO2S2 Mr=305.20 monoclinic P2(1)\/n MoK\u03b1radiation finalRindices (I>2\u03c3(I)):R1=0.0531 wR2=0.1244 a=11.4801(16) b=7.8884(11) c=12.9888(17)\u2005\u00c5 \u03b2=95.286(2)\u00b0 V=1171.3(11)\u2005\u00c53 Z=4 number of reflections (measured\/unique): 6774\/2648 (Rint=0.1155) number of observations: 1764 (I>2\u03c3(I)) 145 parameters. CCDC\u2010614240 (\u00b1\u2010(E)\u20103\u2009m) CCDC\u2010629979 ((S)\u2010(E)\u20103\u2009m) and CCDC\u2010614242 (trans\u20105\u2009l) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk\/data_request\/cif."},{"key":"e_1_2_2_33_2","unstructured":"Optically pure allenyl sulfones were synthesized by the oxidation of chiral allenyl sulfoxides withm\u2010chloroperbenzoic acid in an ice bath. 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