{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,20]],"date-time":"2026-04-20T13:04:26Z","timestamp":1776690266671,"version":"3.51.2"},"reference-count":48,"publisher":"Wiley","issue":"27","license":[{"start":{"date-parts":[[2007,5,30]],"date-time":"2007-05-30T00:00:00Z","timestamp":1180483200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2007,7,2]]},"DOI":"10.1002\/anie.200701354","type":"journal-article","created":{"date-parts":[[2007,5,30]],"date-time":"2007-05-30T08:47:57Z","timestamp":1180514877000},"page":"5206-5208","source":"Crossref","is-referenced-by-count":114,"title":["De Novo Asymmetric Synthesis of the Anthrax Tetrasaccharide by a Palladium\u2010Catalyzed Glycosylation 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in principle16can be prepared by Fischer glycosylation in practice for moderately expensive sugars likeL\u2010rhamnose a four\u2010step protocol is preferred: 1)\u2005peracylation 2)\u2005selective hydrolysis of the anomeric position with HBr 3)\u2005Ag\u2010 or Hg\u2010promoted glycosylation of the anomeric bromide and 4)\u2005LiOH global ester hydrolysis]; see Ref.\u2005[6]."},{"key":"e_1_2_2_36_2","unstructured":"\u00a0"},{"key":"e_1_2_2_37_2","doi-asserted-by":"publisher","DOI":"10.1055\/s-1992-34153"},{"key":"e_1_2_2_38_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(00)61281-9"},{"key":"e_1_2_2_39_2","unstructured":"See Ref.\u2005[7b] and"},{"key":"e_1_2_2_40_2","doi-asserted-by":"publisher","DOI":"10.1139\/v70-288"},{"key":"e_1_2_2_41_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0008-6215(01)00235-X"},{"key":"e_1_2_2_42_2","unstructured":"While both reactions worked well we had a preference for the phosphate glycosylation (5+6) 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