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Since the pioneering studies with palladium by the research group of Barry Trost in the mid\u20101980s, several other metals have been identified as excellent catalysts for the rearrangement of enyne skeletons. Moreover, the behavior of 1,n\u2010enynes may be influenced by other functional groups such as alcohols, aldehydes, ethers, alkenes, or alkynes, thus enhancing the molecular complexity of the synthesized products. Apart from the intrinsic rearrangements of 1,n\u2010enynes, several tandem reactions incorporating intramolecular trapping agents or intermolecular partners have been discovered. This Review aims to highlight the main contributions in this field of catalysis and to propose and comment on the mechanistic insights of the recent discoveries.<\/jats:p>","DOI":"10.1002\/anie.200701589","type":"journal-article","created":{"date-parts":[[2008,4,1]],"date-time":"2008-04-01T15:31:26Z","timestamp":1207063886000},"page":"4268-4315","source":"Crossref","is-referenced-by-count":999,"title":["Cycloisomerization of 1,<i>n<\/i>\u2010Enynes: Challenging Metal\u2010Catalyzed Rearrangements and Mechanistic Insights"],"prefix":"10.1002","volume":"47","author":[{"given":"V\u00e9ronique","family":"Michelet","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Patrick\u2005Y.","family":"Toullec","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jean\u2010Pierre","family":"Gen\u00eat","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2008,5,16]]},"reference":[{"key":"e_1_2_19_1_2","unstructured":"\u00a0"},{"key":"e_1_2_19_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar010068z"},{"key":"e_1_2_19_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19951070304"},{"key":"e_1_2_19_3_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199502591"},{"key":"e_1_2_19_4_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1962206"},{"key":"e_1_2_19_5_2","unstructured":"\u00a0"},{"key":"e_1_2_19_6_2","volume-title":"Green Chemistry, Theory and Practice","author":"Anastas P.","year":"1998"},{"key":"e_1_2_19_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar010065m"},{"key":"e_1_2_19_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/es032373g"},{"key":"e_1_2_19_9_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.297.5582.807"},{"key":"e_1_2_19_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr000666b"},{"key":"e_1_2_19_11_2","unstructured":"\u00a0"},{"key":"e_1_2_19_12_2","first-page":"1","author":"Chapman C. 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