{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T06:56:52Z","timestamp":1791183412225,"version":"4.1.0"},"reference-count":22,"publisher":"Wiley","issue":"9","license":[{"start":{"date-parts":[[2008,1,24]],"date-time":"2008-01-24T00:00:00Z","timestamp":1201132800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2008,2,15]]},"DOI":"10.1002\/anie.200704461","type":"journal-article","created":{"date-parts":[[2008,1,24]],"date-time":"2008-01-24T16:19:21Z","timestamp":1201191561000},"page":"1762-1765","source":"Crossref","is-referenced-by-count":160,"title":["Dinuclear {(salen)Al} Complexes Display Expanded Scope in the Conjugate Cyanation of \u03b1,\u03b2\u2010Unsaturated Imides"],"prefix":"10.1002","volume":"47","author":[{"given":"Cl\u00e9ment","family":"Mazet","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Eric\u2005N.","family":"Jacobsen","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2008,2,11]]},"reference":[{"key":"e_1_2_2_1_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja034635k"},{"key":"e_1_2_2_2_2","unstructured":"\u00a0"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja043424s"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2007.02.081"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja046653n"},{"key":"e_1_2_2_6_2","unstructured":"Typically 10\u201340 mol\u2009% of chiral ligand were used. Reaction time ranged from 8\u2005h to 6\u2005days. See ref.\u2005[2b] for details. The second generation of catalyst reported in ref.\u2005[2b] partially circumvents these limitations."},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja982683c"},{"key":"e_1_2_2_8_2","unstructured":"\u00a0"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja005867b"},{"key":"e_1_2_2_10_2","first-page":"41","author":"Ready J. M.","year":"2002","journal-title":"Angew. Chem."},{"key":"e_1_2_2_10_3","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20020415)41:8<1374::AID-ANIE1374>3.0.CO;2-8"},{"key":"e_1_2_2_11_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetasy.2003.09.024"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20001016)112:20<3750::AID-ANGE3750>3.0.CO;2-T"},{"key":"e_1_2_2_12_3","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20001016)39:20<3604::AID-ANIE3604>3.0.CO;2-9"},{"key":"e_1_2_2_13_2","unstructured":"\u00a0"},{"key":"e_1_2_2_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja984410n"},{"key":"e_1_2_2_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200503291"},{"key":"e_1_2_2_15_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200503291"},{"key":"e_1_2_2_16_2","unstructured":"SeeSupporting Informationfor a typical procedure. Data for catalysts2\u2009aand2\u2009bare not plotted because these catalysts were less enantioselective. After a reaction time of 20\u2005h catalyst2\u2009afurnished imide5\u2009ein 47\u2009% yield and 86\u2009%\u2005ee and catalyst2\u2009bafforded the same product in 24\u2009% yield and 68\u2009%\u2005ee."},{"key":"e_1_2_2_17_2","unstructured":"This particular substrate requires 48\u2005h reaction time with either the homobimetallic or the heterobimetallic systems described in references\u2005[1] and [2]."},{"key":"e_1_2_2_18_2","unstructured":"At the end of the cyanation reactions using substrates6\u2009a\u2013c only starting material and product could be identified by1H\u2005NMR spectroscopy of the crude mixture."},{"key":"e_1_2_2_19_2","unstructured":"kmono(1)=3.77\u00d710\u22128\u2009M\u22121\u2009s\u22121 kinter(2\u2009e)=3.55\u00d710\u22126\u2009M\u22121\u2009s\u22121 kintra(2\u2009e)=7.63\u2005s\u22121. SeeSupporting Informationfor details. Similar results were obtained with catalyst2\u2009cand2\u2009d."}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fanie.200704461","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.200704461","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,10,16]],"date-time":"2023-10-16T06:52:13Z","timestamp":1697439133000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.200704461"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2008,2,11]]},"references-count":22,"journal-issue":{"issue":"9","published-print":{"date-parts":[[2008,2,15]]}},"alternative-id":["10.1002\/anie.200704461"],"URL":"https:\/\/doi.org\/10.1002\/anie.200704461","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2008,2,11]]}}}