{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,15]],"date-time":"2025-10-15T17:18:57Z","timestamp":1760548737877},"reference-count":21,"publisher":"Wiley","issue":"42","license":[{"start":{"date-parts":[[2008,9,16]],"date-time":"2008-09-16T00:00:00Z","timestamp":1221523200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2008,10,6]]},"DOI":"10.1002\/anie.200802943","type":"journal-article","created":{"date-parts":[[2008,9,16]],"date-time":"2008-09-16T17:18:07Z","timestamp":1221585487000},"page":"8116-8119","source":"Crossref","is-referenced-by-count":12,"title":["The Influence of Electron\u2010Withdrawing Groups on the Chemistry of Phosphorus: Tautomerization of Bis(<i>s<\/i>\u2010triazinyl)phosphanes"],"prefix":"10.1002","volume":"47","author":[{"given":"Berthold","family":"Hoge","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Waldemar","family":"Wiebe","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2008,9,29]]},"reference":[{"key":"e_1_2_3_1_2","unstructured":"B. Hoge S. Hettel N. Rehmann K. Meerholz unpublished results."},{"key":"e_1_2_3_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200600260"},{"key":"e_1_2_3_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2004.09.041"},{"key":"e_1_2_3_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic049796j"},{"key":"e_1_2_3_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200300823"},{"key":"e_1_2_3_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jfluchem.2007.04.007"},{"key":"e_1_2_3_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo01355a603"},{"key":"e_1_2_3_8_2","unstructured":"B. Hoge W. Wiebe unpublished results."},{"key":"e_1_2_3_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19774300108"},{"key":"e_1_2_3_9_3","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19824950108"},{"key":"e_1_2_3_9_4","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19916050102"},{"key":"e_1_2_3_9_5","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19926080206"},{"key":"e_1_2_3_9_6","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.200400383"},{"key":"e_1_2_3_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200601221"},{"key":"e_1_2_3_11_2","unstructured":"Gaussian\u200903 Version\u2009B.04 M.\u2005J. Frisch G.\u2005W. Trucks H.\u2005B. Schlegel G.\u2005E. Scuseria M.\u2005A. Robb J.\u2005R. Cheeseman J.\u2005A. Montgomery \u2005Jr. T. Vreven K.\u2005N. Kudin J.\u2005C. Burant J.\u2005M. Millam S.\u2005S. Iyengar J. Tomasi V. Barone B. Mennucci M. Cossi G. Scalmani N. Rega G.\u2005A. Petersson H. Nakatsuji M. Hada M. Ehara K. Toyota R. Fukuda J. Hasegawa M. Ishida T. Nakajima Y. Honda O. Kitao H. Nakai M. Klene X. Li J.\u2005E. Knox H.\u2005P. Hratchian J.\u2005B. Cross V. Bakken C. Adamo J. Jaramillo R. Gomperts R.\u2005E. Stratmann O. Yazyev A.\u2005J. Austin R. Cammi C. Pomelli J.\u2005W. Ochterski P.\u2005Y. Ayala K. Morokuma G.\u2005A. Voth P. Salvador J.\u2005J. Dannenberg V.\u2005G. Zakrzewski S. Dapprich A.\u2005D. Daniels M.\u2005C. Strain O. Farkas D.\u2005K. Malick A.\u2005D. Rabuck K. Raghavachari J.\u2005B. Foresman J.\u2005V. Ortiz Q. Cui A.\u2005G. Baboul S. Clifford J. Cioslowski B.\u2005B. Stefanov G. Liu A. Liashenko P. Piskorz I. Komaromi R.\u2005L. Martin D.\u2005J. Fox T. Keith M.\u2005A. Al\u2010Laham C.\u2005Y. Peng A. Nanayakkara M. Challacombe P.\u2005M.\u2005W. Gill B. Johnson W. Chen M.\u2005W. Wong C. Gonzalez J.\u2005A. Pople Gaussian Inc. Wallingford CT 2003."},{"key":"e_1_2_3_12_2","unstructured":"Data collection for X\u2010ray structure determination was performed on a STOE IPDS II diffractometer using graphite\u2010monochromated MoK\u03b1radiation (71.073\u2005pm). The data were corrected for Lorentz and polarization effects. A numerical absorption correction based on crystal\u2010shape optimization was applied for all data (X\u2010Shape 2.01 Crystal Optimisation for Numerical Absorption Correction (C) 2001 STOE & Cie GmbH Darmstadt). The programs used in this work are Stoe's X\u2010Area (X\u2010Area 1.16 Stoe & Cie GmbH Darmstadt 2003) including X\u2010RED and X\u2010Shape for data reduction and numerical absorption correction (X\u2010RED32 1.03 Stoe Data Reduction Program (C) 2002 Stoe & Cie GmbH Darmstadt) and X\u2010Step32 program (X\u2010STEP32 1.06f 2000 Stoe & Cie GmbH Darmstadt) including SHELXS\u201097 (G.\u2005M. Sheldrick SHELXS\u201097 University of G\u00f6ttingen 1998) and SHELXL\u201097 ("},{"key":"e_1_2_3_12_3","unstructured":"G.\u2005M. Sheldrick SHELXL\u201097 University of G\u00f6ttingen 1997) for structure solution and refinement."},{"key":"e_1_2_3_13_2","unstructured":"The last cycles of refinement included atomic positions for all the atoms anisotropic thermal parameters for all the non\u2010hydrogen atoms and isotropic thermal parameters for all of the hydrogen atoms. Intensity data for5\u2009b C10H13N6O4P (313.23\u2005g\u2009mol\u22121) collected at 170(2)\u2005K red polyhedron orthorhombic space groupPmnb(no.\u200562);a=663.5(1) b=839.9(1) c=2420.3(4)\u2005pm V=1.3487(3)\u2005nm3 Z=4 \u03c1calcd=1.538\u2005g\u2009cm\u22123 \u03bc(MoK\u03b1)=0.232\u2005cm\u22121 F(000)=648; 20\u2009608 reflections with 3.4<2\u03b8<54.7\u00b0 1651 independent in structure solution and refinement for 158 parameters R1(I\u22652\u03c3(I))=0.049 wR2(all data)=0.136 w=1\/{\u03c32(${F{{2\\hfill \\atop {\\rm o}\\hfill}}}$) + [0.0946(${F{{2\\hfill \\atop {\\rm o}\\hfill}}}$+ 2\u2009${F{{2\\hfill \\atop {\\rm c}\\hfill}}}$)\/3]2}."},{"key":"e_1_2_3_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.200400332"},{"key":"e_1_2_3_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200601291"},{"key":"e_1_2_3_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/1099-0682(200012)2000:12<2425::AID-EJIC2425>3.0.CO;2-A"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fanie.200802943","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.200802943","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,10,16]],"date-time":"2023-10-16T04:56:46Z","timestamp":1697432206000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.200802943"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2008,9,29]]},"references-count":21,"journal-issue":{"issue":"42","published-print":{"date-parts":[[2008,10,6]]}},"alternative-id":["10.1002\/anie.200802943"],"URL":"https:\/\/doi.org\/10.1002\/anie.200802943","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2008,9,29]]}}}