{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,24]],"date-time":"2026-09-24T18:55:08Z","timestamp":1790276108804,"version":"4.1.0"},"reference-count":42,"publisher":"Wiley","issue":"13","license":[{"start":{"date-parts":[[2009,2,19]],"date-time":"2009-02-19T00:00:00Z","timestamp":1235001600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2009,3,16]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p><jats:bold>The vanadium\u2013bis(telluride) complex<\/jats:bold>, [(PNP)V(Te)<jats:sub>2<\/jats:sub>] (see picture), in which the terminal telluride units can act as leaving groups or protecting groups, is prepared by activation of elemental Te by V. The complex masks {(PNP)V<jats:sup>I<\/jats:sup>} or {(PNP)V<jats:sup>III<\/jats:sup>} sources when exposed to oxidants such as azides and diphenyldiazomethane. Isocyanides promote elimination of one Te ligand to furnish a V<jats:sup>III<\/jats:sup> complex with a terminal telluride ligand.<jats:boxed-text content-type=\"graphic\" position=\"anchor\"><jats:graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" mimetype=\"image\/gif\" position=\"anchor\" specific-use=\"enlarged-web-image\" xlink:href=\"graphic\/mcontent.gif\"><jats:alt-text>magnified image<\/jats:alt-text><\/jats:graphic><\/jats:boxed-text><\/jats:p>","DOI":"10.1002\/anie.200806022","type":"journal-article","created":{"date-parts":[[2009,2,19]],"date-time":"2009-02-19T13:31:26Z","timestamp":1235050286000},"page":"2394-2397","source":"Crossref","is-referenced-by-count":29,"title":["Tellus in, Tellus out: The Chemistry of the Vanadium Bis(telluride) Functionality"],"prefix":"10.1002","volume":"48","author":[{"given":"Uriah\u2005J.","family":"Kilgore","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jonathan\u2005A.","family":"Karty","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maren","family":"Pink","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinfeng","family":"Gao","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Daniel\u2005J.","family":"Mindiola","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2009,3,10]]},"reference":[{"key":"e_1_2_2_1_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00024a088"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00085a038"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00041a049"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1039\/c39920001670"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00074a068"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00129a021"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja971043r"},{"key":"e_1_2_2_8_2","unstructured":"\u00a0"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(96)06584-9"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(94)80226-2"},{"key":"e_1_2_2_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.19960021104"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00114a005"},{"key":"e_1_2_2_13_2","unstructured":"\u00a0"},{"key":"e_1_2_2_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200705931"},{"key":"e_1_2_2_14_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200705931"},{"key":"e_1_2_2_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/om800800g"},{"key":"e_1_2_2_16_2","unstructured":"See the Supporting Information for details."},{"key":"e_1_2_2_17_2","unstructured":"\u00a0"},{"key":"e_1_2_2_18_2","doi-asserted-by":"publisher","DOI":"10.1039\/dt9960004463"},{"key":"e_1_2_2_19_2","doi-asserted-by":"publisher","DOI":"10.1039\/a907549f"},{"key":"e_1_2_2_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3749(199910)625:10<1726::AID-ZAAC1726>3.0.CO;2-2"},{"key":"e_1_2_2_21_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(97)00377-8"},{"key":"e_1_2_2_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo00119a054"},{"key":"e_1_2_2_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00205a044"},{"key":"e_1_2_2_24_2","unstructured":"\u00a0"},{"key":"e_1_2_2_25_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(01)82103-1"},{"key":"e_1_2_2_26_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(01)00592-5"},{"key":"e_1_2_2_27_2","unstructured":"Crystal data for2: C10H20Te2 Mr=395.46 triclinic P$\\bar 1$ a=6.0203(6)\u2005\u00c5 b=6.1490(6)\u2005\u00c5 c=9.5745(9)\u2005\u00c5 \u03b1=101.704(2)\u00b0 \u03b2=90.800(2)\u00b0 \u03b3=113.446(2)\u00b0 V=316.64(5)\u2005\u00c53 Z=1 \u03c1calcd=2.074\u2005Mg\u2009m\u22123 T=150(2)\u2005K MoK\u03b1=0.71073\u2005\u00c5 absorption coefficient 4.563\u2005mm\u22121 F(000)=184 5533 reflections collected 1439 independent reflections Rint=0.0304 GoF=1.055 R=0.0209 [I>2\u03c3(I)] wR2=0.0522 [I>2\u03c3(I)]. CCDC\u2005706518 706519 706520 706521 706522 (2\u20135and8) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre viawww.ccdc.cam.ac.uk\/data_request\/cif."},{"key":"e_1_2_2_28_2","unstructured":"Crystal data for3: C10H20Te3 M=523.06 monoclinic P21\/n a=12.7214(7)\u2005\u00c5 b=5.9309(3)\u2005\u00c5 c=19.0338(11)\u2005\u00c5 \u03b2=96.5310(10)\u00b0 V=1426.77(13)\u2005\u00c53 Z=4 \u03c1calcd=2.435\u2005Mg\u2009m\u22123 T=150(2)\u2005K MoK\u03b1=0.71073\u2005\u00c5 absorption coefficient 6.058\u2005mm\u22121 F(000)=944 24\u2009037 reflections collected 3230 independent reflections Rint=0.0195 GoF=1.074 R=0.0147 [I>2\u03c3(I)] wR2=0.0319 [I>2\u03c3(I)]."},{"key":"e_1_2_2_29_2","unstructured":"A search of the Cambridge Structural Database on 10\/27\/08 using Conquest 1.10 suggests an average Te\u2013Te bond length of approximately 2.7\u2005\u00c5 for molecules containing C\u2013Te\u2013Te\u2013C moieties."},{"key":"e_1_2_2_30_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2008.01.008"},{"key":"e_1_2_2_31_2","unstructured":"Crystal data for4: C26H40NP2Te2V Mr=734.67 monoclinic P21\/c a=7.2758(4)\u2005\u00c5 b=14.7745(10)\u2005\u00c5 c=27.0582(18)\u2005\u00c5 \u03b2=95.3410(10)\u00b0 V=2896.0(3)\u2005\u00c53 Z=4 \u03c1calcd=1.685\u2005Mg\u2009m\u22123 T=150(2)\u2005K MoK\u03b1=0.71073\u2005\u00c5 absorption coefficient 2.442\u2005mm\u22121 F(000)=1440 33\u2009700 reflections collected 8801 independent reflections Rint=0.0337 GoF=1.013 R=0.0293 [I>2\u03c3(I)] wR2=0.0609 [I>2\u03c3(I)]."},{"key":"e_1_2_2_32_2","doi-asserted-by":"publisher","DOI":"10.1021\/om700715s"},{"key":"e_1_2_2_33_2","doi-asserted-by":"publisher","DOI":"10.1021\/om7008233"},{"key":"e_1_2_2_34_2","unstructured":"Crystal data for5: C46H70N3P2V\u22c5C6H12\u22c50.5C6H14 Mr=905.17 monoclinic P21\/c a=12.6324(13)\u2005\u00c5 b=36.310(4)\u2005\u00c5 c=11.6032(13)\u2005\u00c5 \u03b2=101.219(2)\u00b0 V=5220.4(10)\u2005\u00c53 Z=4 \u03c1calcd=1.152\u2005Mg\u2009m\u22123 T=123(2)\u2005K MoK\u03b1=0.71073\u2005\u00c5 absorption coefficient 0.289\u2005mm\u22121 F(000)=1972 63\u2009610 reflections collected 9229 independent reflections Rint=0.0611 GoF=1.039 R=0.0479 [I>2\u03c3(I)] wR2=0.0988 [I>2\u03c3(I)]."},{"key":"e_1_2_2_35_2","unstructured":"Few examples of vanadium bis(imide) complexes (transient or stable entities) have been reported;"},{"key":"e_1_2_2_36_2","doi-asserted-by":"publisher","DOI":"10.1515\/znb-1990-0213"},{"key":"e_1_2_2_37_2","doi-asserted-by":"publisher","DOI":"10.1021\/om00029a003"},{"key":"e_1_2_2_38_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19931050642"},{"key":"e_1_2_2_38_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199309031"},{"key":"e_1_2_2_39_2","doi-asserted-by":"publisher","DOI":"10.1039\/B711816C"},{"key":"e_1_2_2_40_2","unstructured":"Crystal data for8: C44H58N3P2Te1.09V Mr=880.58 monoclinic P21\/c a=12.439(3)\u2005\u00c5 b=18.092(4)\u2005\u00c5 c=20.004(4)\u2005\u00c5 \u03b2=106.380(4)\u00b0 V=4319.2(17)\u2005\u00c53 Z=4 \u03c1calcd=1.354\u2005Mg\u2009m\u22123 T=150(2)\u2005K MoK\u03b1=0.71073\u2005\u00c5 absorption coefficient 1.056\u2005mm\u22121 F(000)=1810 31\u2009624 reflections collected 7713 independent reflections Rint=0.0800 GoF=1.047 R=0.0574 [I>2\u03c3(I)] wR2=0.1453 [I>2\u03c3(I)]. The crystals of8were found to contain co\u2010crystals of complex C44H58N3P2Te2V in a 9:1 ratio. The Te disorder was refined with a set of restraints and constraints."}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fanie.200806022","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.200806022","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,9,28]],"date-time":"2023-09-28T23:25:48Z","timestamp":1695943548000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.200806022"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2009,3,10]]},"references-count":42,"journal-issue":{"issue":"13","published-print":{"date-parts":[[2009,3,16]]}},"alternative-id":["10.1002\/anie.200806022"],"URL":"https:\/\/doi.org\/10.1002\/anie.200806022","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2009,3,10]]}}}