{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,5]],"date-time":"2026-09-05T15:00:44Z","timestamp":1788620444059,"version":"build-2803163510"},"reference-count":46,"publisher":"Wiley","issue":"27","license":[{"start":{"date-parts":[[2009,6,2]],"date-time":"2009-06-02T00:00:00Z","timestamp":1243900800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2009,6,22]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p><jats:bold>Spot the difference<\/jats:bold>: The five\u2010coordinate iron(II) cyanoporphyrinates, which are spin\u2010crossover compounds, can be used to synthesize previously unknown six\u2010coordinate complexes. Bis(cyano) and (cyano)imidazole complexes are presented, and the five\u2010 and six\u2010coordinate (cyano)iron(II) derivatives are compared with analogous CO complexes.<jats:boxed-text content-type=\"graphic\" position=\"anchor\"><jats:graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" mimetype=\"image\/gif\" position=\"anchor\" specific-use=\"enlarged-web-image\" xlink:href=\"graphic\/mcontent.gif\"><jats:alt-text>magnified image<\/jats:alt-text><\/jats:graphic><\/jats:boxed-text><\/jats:p>","DOI":"10.1002\/anie.200901434","type":"journal-article","created":{"date-parts":[[2009,6,2]],"date-time":"2009-06-02T13:08:06Z","timestamp":1243948086000},"page":"5010-5013","source":"Crossref","is-referenced-by-count":41,"title":["Comparison of Cyanide and Carbon Monoxide as Ligands in Iron(II) Porphyrinates"],"prefix":"10.1002","volume":"48","author":[{"given":"Jianfeng","family":"Li","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bruce\u2005C.","family":"Noll","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Charles\u2005E.","family":"Schulz","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"W.\u2005Robert","family":"Scheidt","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2009,6,17]]},"reference":[{"key":"e_1_2_2_1_2","volume-title":"Hemoglobin and Myoglobin in Their Reactions with Ligands","author":"Antonini E.","year":"1971"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9258(19)83653-0"},{"key":"e_1_2_2_3_2","first-page":"7","volume-title":"Comprehensive Coordination Chemistry, Vol.\u20052","author":"Sharpe A. G.","year":"1987"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200804116"},{"key":"e_1_2_2_4_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200804116"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/bi9601971"},{"key":"e_1_2_2_6_2","doi-asserted-by":"crossref","first-page":"2258","DOI":"10.1016\/S0021-9258(18)45871-1","volume":"267","author":"Brunori M.","year":"1992","journal-title":"J. Biol. Chem."},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/bi00023a003"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1074\/jbc.M001377200"},{"key":"e_1_2_2_9_2","unstructured":"Abbreviations: Por=generalized porphyrin dianion Np=porphyrinato nitrogen Nax=axial nitrogen tpp=dianion ofmeso\u2010tetraphenylporphyrin ttp=meso\u2010tetra\u2010p\u2010tolylporphyrin oep=dianion of 2 3 7 8 12 13 17 18\u2010octaethylporphyrin 1\u2010MeIm= 1\u2010methylimidazole kryptofix\u2010222 or 222=4 7 13 16 21 24\u2010hexaoxo\u20101 10\u2010diazabicyclo[8.8.8]hexacosane."},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200805446"},{"key":"e_1_2_2_10_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200805446"},{"key":"e_1_2_2_11_2","unstructured":"CCDC\u2005723540 723541 723542 and 723543 ([K(222)][Fe(tpp)CN] at 100 296 325 and 400\u2005K) 723544 [K(222)]2[Fe(tpp)(CN)2]\u22c5PhCl 723545 [K(222)]2[Fe(tpp)(CN)2]\u22c54\u2009PhCl 723546 [K(222)]2[Fe(ttp)(CN)2] and 723547 [K(222)][Fe(tpp)CN(1\u2010MeIm)] contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre viawww.ccdc.cam.ac.uk\/data_request\/cif."},{"key":"e_1_2_2_12_2","unstructured":"Comparisons of the structures of the two spin\u2010crossover polymorphic forms at four temperatures between 100 and 400\u2005K is given in the Supporting Information."},{"key":"e_1_2_2_13_2","unstructured":"\u00a0"},{"key":"e_1_2_2_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic061463u"},{"key":"e_1_2_2_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja992219n"},{"key":"e_1_2_2_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic0108383"},{"key":"e_1_2_2_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/bi9618880"},{"key":"e_1_2_2_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/bi961889s"},{"key":"e_1_2_2_19_2","unstructured":"\u00a0"},{"key":"e_1_2_2_20_2","doi-asserted-by":"publisher","DOI":"10.1085\/jgp.12.2.273"},{"key":"e_1_2_2_21_2","doi-asserted-by":"publisher","DOI":"10.1098\/rspb.1929.0032"},{"key":"e_1_2_2_22_2","doi-asserted-by":"publisher","DOI":"10.1042\/bj0450440"},{"key":"e_1_2_2_23_2","doi-asserted-by":"publisher","DOI":"10.1042\/bj0450448"},{"key":"e_1_2_2_24_2","doi-asserted-by":"crossref","DOI":"10.1007\/978-1-4684-4934-1","volume-title":"Computational Methods for the Determination of Formation Constants","author":"Leggett D. 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In polymorph\u20052 this Fe\uf8ffCN distance is 2.068(4)\u2005\u00c5 at 400\u2005K (see the Supporting Information)."},{"key":"e_1_2_2_29_2","unstructured":"\u00a0"},{"key":"e_1_2_2_30_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00529a024"},{"key":"e_1_2_2_31_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00302a002"},{"key":"e_1_2_2_32_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00065a017"},{"key":"e_1_2_2_33_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0020-1693(97)06156-2"},{"key":"e_1_2_2_34_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00099a015"},{"key":"e_1_2_2_35_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja053148x"},{"key":"e_1_2_2_36_2","unstructured":"\u00a0"},{"key":"e_1_2_2_37_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja01041a013"},{"key":"e_1_2_2_38_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic50100a022"},{"key":"e_1_2_2_39_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic0514041"},{"key":"e_1_2_2_40_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00081a028"},{"key":"e_1_2_2_41_2","unstructured":"\u00a0"},{"key":"e_1_2_2_42_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00136a035"},{"key":"e_1_2_2_43_2","doi-asserted-by":"publisher","DOI":"10.1039\/j19700000956"},{"key":"e_1_2_2_44_2","volume-title":"Iron Porphyrins Part 3","author":"Debrunner P.","year":"1983"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fanie.200901434","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.200901434","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,9,28]],"date-time":"2023-09-28T22:35:45Z","timestamp":1695940545000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.200901434"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2009,6,17]]},"references-count":46,"journal-issue":{"issue":"27","published-print":{"date-parts":[[2009,6,22]]}},"alternative-id":["10.1002\/anie.200901434"],"URL":"https:\/\/doi.org\/10.1002\/anie.200901434","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2009,6,17]]}}}