{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,12]],"date-time":"2026-05-12T16:37:54Z","timestamp":1778603874008,"version":"3.51.4"},"reference-count":76,"publisher":"Wiley","issue":"32","license":[{"start":{"date-parts":[[2010,7,2]],"date-time":"2010-07-02T00:00:00Z","timestamp":1278028800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2010,7,26]]},"DOI":"10.1002\/anie.201000901","type":"journal-article","created":{"date-parts":[[2010,7,6]],"date-time":"2010-07-06T14:06:29Z","timestamp":1278425189000},"page":"5485-5488","source":"Crossref","is-referenced-by-count":18,"title":["Synthesis, Structure, and Reactivity of a Stabilized Phosphiranylium Salt"],"prefix":"10.1002","volume":"49","author":[{"given":"Helen","family":"Jansen","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Florian\u2005B.","family":"L\u00e4ng","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"J.\u2005Chris","family":"Slootweg","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Andreas\u2005W.","family":"Ehlers","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Martin","family":"Lutz","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Koop","family":"Lammertsma","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hansj\u00f6rg","family":"Gr\u00fctzmacher","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2010,7,22]]},"reference":[{"key":"e_1_2_2_1_2","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1351\/pac198759080993"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr00104a004"},{"key":"e_1_2_2_4_2","first-page":"277","volume-title":"Comprehensive Heterocyclic Chemistry II, Vol.\u20051A","author":"Mathey F.","year":"1997"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1016\/B978-008043952-5\/50003-6"},{"key":"e_1_2_2_6_2","unstructured":"\u00a0"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1007\/b11152"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/1099-0690(200204)2002:7<1127::AID-EJOC1127>3.0.CO;2-X"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/1522-2675(20011017)84:10<2938::AID-HLCA2938>3.0.CO;2-P"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00096a058"},{"key":"e_1_2_2_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200462862"},{"key":"e_1_2_2_11_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200462862"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/marc.1994.030150618"},{"key":"e_1_2_2_13_2","unstructured":"\u00a0"},{"key":"e_1_2_2_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20000717)112:14<2596::AID-ANGE2596>3.0.CO;2-C"},{"key":"e_1_2_2_14_3","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20000717)39:14<2478::AID-ANIE2478>3.0.CO;2-G"},{"key":"e_1_2_2_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/om020642q"},{"key":"e_1_2_2_16_2","unstructured":"\u00a0"},{"key":"e_1_2_2_17_2","doi-asserted-by":"publisher","DOI":"10.1163\/156856702760129492"},{"key":"e_1_2_2_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/om050155l"},{"key":"e_1_2_2_19_2","doi-asserted-by":"publisher","DOI":"10.1016\/0166-1280(95)90523-5"},{"key":"e_1_2_2_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/j100017a023"},{"key":"e_1_2_2_21_2","doi-asserted-by":"publisher","DOI":"10.1007\/b11151"},{"key":"e_1_2_2_22_2","unstructured":"\u00a0"},{"key":"e_1_2_2_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00099a099"},{"key":"e_1_2_2_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/om980723f"},{"key":"e_1_2_2_25_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.crci.2004.06.002"},{"key":"e_1_2_2_26_2","doi-asserted-by":"publisher","DOI":"10.1039\/b209696j"},{"key":"e_1_2_2_27_2","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19891220310"},{"key":"e_1_2_2_28_2","doi-asserted-by":"publisher","DOI":"10.1039\/ft9969201751"},{"key":"e_1_2_2_29_2","unstructured":"\u00a0"},{"key":"e_1_2_2_30_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00093a012"},{"key":"e_1_2_2_31_2","doi-asserted-by":"publisher","DOI":"10.1007\/3-540-45731-3_1"},{"key":"e_1_2_2_32_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200351388"},{"key":"e_1_2_2_32_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200351388"},{"key":"e_1_2_2_33_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3757(19990601)111:11<1724::AID-ANGE1724>3.0.CO;2-V"},{"key":"e_1_2_2_33_3","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3773(19990601)38:11<1623::AID-ANIE1623>3.0.CO;2-K"},{"key":"e_1_2_2_34_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4020(99)00783-8"},{"key":"e_1_2_2_35_2","doi-asserted-by":"publisher","DOI":"10.1039\/c39950000257"},{"key":"e_1_2_2_36_2","unstructured":"CCDC\u2005765756 (3) and 765757 (10) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre viawww.ccdc.cam.ac.uk\/data_request\/cif. For the experimental details of the X\u2010ray crystal structure determinations see the Supporting Information."},{"key":"e_1_2_2_37_2","unstructured":"\u00a0"},{"key":"e_1_2_2_38_2","doi-asserted-by":"publisher","DOI":"10.2533\/000942903777679451"},{"key":"e_1_2_2_39_2","unstructured":"J. Liedtke Dissertation ETH Z\u00fcrich Synthese und Koordinationschemie neuer polycyclischer Phosphirane Nr. 13688 2000."},{"key":"e_1_2_2_40_2","unstructured":"Gaussian\u200903 (Revision\u2009C.02): M.\u2005J. Frisch et\u2005al. see the Supporting Information."},{"key":"e_1_2_2_41_2","unstructured":"\u00a0"},{"key":"e_1_2_2_42_2","doi-asserted-by":"crossref","DOI":"10.1093\/oso\/9780198551683.001.0001","volume-title":"Atoms in Molecules: a quantum theory","author":"Bader R. F. W.","year":"1990"},{"key":"e_1_2_2_43_2","doi-asserted-by":"publisher","DOI":"10.1039\/9781847553317-00143"},{"key":"e_1_2_2_44_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19840960826"},{"key":"e_1_2_2_44_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198406271"},{"key":"e_1_2_2_45_2","unstructured":"\u00a0"},{"key":"e_1_2_2_46_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1099-0682(199812)1998:12<1847::AID-EJIC1847>3.0.CO;2-K"},{"key":"e_1_2_2_47_2","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19961290912"},{"key":"e_1_2_2_48_2","unstructured":"It is unclear whetherexo\u20104andendo\u20104are in a very slow equilibrium (not detectable on the NMR time scale) through an inversion of the central ring or are formed through an attack of MeLi form either side on the P\u2005center."},{"key":"e_1_2_2_49_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00429a020"},{"key":"e_1_2_2_50_2","unstructured":"\u00a0"},{"key":"e_1_2_2_51_2","doi-asserted-by":"publisher","DOI":"10.1039\/J19700001049"},{"key":"e_1_2_2_52_2","first-page":"1245","volume":"42","author":"Razumov A. I.","year":"1972","journal-title":"J. Gen. Chem. USSR"},{"key":"e_1_2_2_53_2","unstructured":"\u00a0"},{"key":"e_1_2_2_54_2","first-page":"3019","volume":"32","author":"Petrov K. A.","year":"1962","journal-title":"J. Gen. Chem. USSR"},{"key":"e_1_2_2_55_2","doi-asserted-by":"publisher","DOI":"10.1002\/prac.19923340407"},{"key":"e_1_2_2_56_2","unstructured":"Diphenyldisulfide is well known trapping agent for triplet phosphinidenes; see:"},{"key":"e_1_2_2_57_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19650771011"},{"key":"e_1_2_2_57_3","first-page":"437","volume":"4","year":"1965","journal-title":"Angew. Chem. Int. Ed. Engl."},{"key":"e_1_2_2_58_2","first-page":"15","volume-title":"Science of Synthesis, Vol.\u200542","author":"Slootweg J. C.","year":"2009"},{"key":"e_1_2_2_59_2","unstructured":"For NHC\u2010stabilized phosphinidenes see:"},{"key":"e_1_2_2_60_2","doi-asserted-by":"publisher","DOI":"10.1246\/cl.1997.143"},{"key":"e_1_2_2_61_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic970174q"},{"key":"e_1_2_2_62_2","unstructured":"For the related diphenylphosphenium ion [IiPr2Me2\u2192PPh2]+ see:"},{"key":"e_1_2_2_63_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3749(199905)625:5<729::AID-ZAAC729>3.0.CO;2-D"},{"key":"e_1_2_2_64_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic0488738"},{"key":"e_1_2_2_65_2","unstructured":"Energy decomposition analyses were performed on B3PW91\/6\u2010311+G(d p) optimized structures[14]using ADF2007.01 SCM Theoretical Chemistry Vrije Universiteit Amsterdam The Netherlands http:\/\/www.scm.com. See the Supporting Information for details."},{"key":"e_1_2_2_66_2","unstructured":"\u00a0"},{"key":"e_1_2_2_67_2","doi-asserted-by":"publisher","DOI":"10.1039\/b500692a"},{"key":"e_1_2_2_68_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2006.07.007"},{"key":"e_1_2_2_69_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200902344"},{"key":"e_1_2_2_69_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200902344"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fanie.201000901","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.201000901","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,3,28]],"date-time":"2024-03-28T02:00:17Z","timestamp":1711591217000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201000901"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2010,7,22]]},"references-count":76,"journal-issue":{"issue":"32","published-print":{"date-parts":[[2010,7,26]]}},"alternative-id":["10.1002\/anie.201000901"],"URL":"https:\/\/doi.org\/10.1002\/anie.201000901","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2010,7,22]]}}}