{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T14:46:52Z","timestamp":1791298012388,"version":"4.1.0"},"reference-count":44,"publisher":"Wiley","issue":"24","license":[{"start":{"date-parts":[[2011,5,12]],"date-time":"2011-05-12T00:00:00Z","timestamp":1305158400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2011,6,6]]},"DOI":"10.1002\/anie.201101606","type":"journal-article","created":{"date-parts":[[2011,5,12]],"date-time":"2011-05-12T11:53:13Z","timestamp":1305201193000},"page":"5524-5527","source":"Crossref","is-referenced-by-count":212,"title":["Mild C\uf8ffH Halogenation of Anilides and the Isolation of an Unusual Palladium(I)\u2013Palladium(II) Species"],"prefix":"10.1002","volume":"50","author":[{"given":"Robin B.","family":"Bedford","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mairi F.","family":"Haddow","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Charlotte J.","family":"Mitchell","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ruth L.","family":"Webster","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2011,5,12]]},"reference":[{"key":"e_1_2_3_1_2","unstructured":"Selected recent examples:"},{"key":"e_1_2_3_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja031543m"},{"key":"e_1_2_3_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200462884"},{"key":"e_1_2_3_3_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200462884"},{"key":"e_1_2_3_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetasy.2005.08.049"},{"key":"e_1_2_3_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja061943k"},{"key":"e_1_2_3_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2006.06.075"},{"key":"e_1_2_3_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol060747f"},{"key":"e_1_2_3_8_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2008.03.026"},{"key":"e_1_2_3_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200705613"},{"key":"e_1_2_3_9_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200705613"},{"key":"e_1_2_3_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja900200g"},{"key":"e_1_2_3_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja9049228"},{"key":"e_1_2_3_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.200900778"},{"key":"e_1_2_3_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja060232j"},{"key":"e_1_2_3_14_2","unstructured":"\u00a0"},{"key":"e_1_2_3_15_2","doi-asserted-by":"publisher","DOI":"10.1039\/c003074k"},{"key":"e_1_2_3_16_2","doi-asserted-by":"publisher","DOI":"10.1039\/c0dt00385a"},{"key":"e_1_2_3_17_2","unstructured":"For two examples of chlorination of anilides using NCS under far more forcing conditions (100\u2009\u00b0C 12\u2005h) see Ref.\u2005[1f]."},{"key":"e_1_2_3_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0176907"},{"key":"e_1_2_3_19_2","unstructured":"Using THF diethyl ether or dichloromethane as the solvent led to modest (11\u201314\u2009%) levels of competitivep\u2010bromination. 1 4\u2010Dioxane gave 61\u2009% of2\u2009aand 16\u2009% of3\u2009a whereas toluene\/1 4\u2010dioxane (1:1) gave 73\u2009% of2\u2009a 14\u2009% of3\u2009a and 5\u2009% of4\u2009a."},{"key":"e_1_2_3_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200805842"},{"key":"e_1_2_3_20_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200805842"},{"key":"e_1_2_3_21_2","unstructured":"See the Supporting Information for details."},{"key":"e_1_2_3_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo9622993"},{"key":"e_1_2_3_23_2","unstructured":"For selected recent examples see:"},{"key":"e_1_2_3_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja9077705"},{"key":"e_1_2_3_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol901049r"},{"key":"e_1_2_3_26_2","doi-asserted-by":"publisher","DOI":"10.1039\/b905717j"},{"key":"e_1_2_3_27_2","unstructured":"Recent examples:"},{"key":"e_1_2_3_28_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2008.04.006"},{"key":"e_1_2_3_29_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2010.03.011"},{"key":"e_1_2_3_30_2","doi-asserted-by":"publisher","DOI":"10.1021\/om0496535"},{"key":"e_1_2_3_31_2","unstructured":"As yet we do not know what acts as the reductant in this reaction."},{"key":"e_1_2_3_32_2","unstructured":"For recent examples see:"},{"key":"e_1_2_3_33_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja1054274"},{"key":"e_1_2_3_34_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.246"},{"key":"e_1_2_3_35_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja906935c"},{"key":"e_1_2_3_36_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja904116k"},{"key":"e_1_2_3_37_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja077866q"},{"key":"e_1_2_3_38_2","unstructured":"Attempts to explore the precise role of12have so far been hampered by the fact that it is not stable in the solid state in the absence of 1 4\u2010dioxane but rather undergoes rapid (min) decomposition. Conversely 1 4\u2010dioxane solutions of12contain varying amounts of free PTSA and therefore must also contain concomitant amounts of unidentified Pd species."},{"key":"e_1_2_3_39_2","unstructured":"For examples see:"},{"key":"e_1_2_3_40_2","first-page":"3103","author":"Rauf W.","year":"2009","journal-title":"Synlett"},{"key":"e_1_2_3_41_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja803397y"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fanie.201101606","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.201101606","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,10,16]],"date-time":"2023-10-16T08:04:16Z","timestamp":1697443456000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201101606"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2011,5,12]]},"references-count":44,"journal-issue":{"issue":"24","published-print":{"date-parts":[[2011,6,6]]}},"alternative-id":["10.1002\/anie.201101606"],"URL":"https:\/\/doi.org\/10.1002\/anie.201101606","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2011,5,12]]}}}