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However, this approach often suffers from drawbacks, such as the formation of stoichiometric amounts of metal waste, the poisoning of the metal catalysts, or the generation of toxic HCN gas. As a result, a range of \u201cnonmetallic\u201d organic cyano\u2010group sources have been explored for the cyanation of aryl halides and arene C\uf8ffH bonds. This Minireview summarizes types of nonmetallic cyano\u2010group sources and their applications in the preparation of aryl nitriles.<\/jats:p>","DOI":"10.1002\/anie.201206168","type":"journal-article","created":{"date-parts":[[2012,11,6]],"date-time":"2012-11-06T14:01:52Z","timestamp":1352210512000},"page":"11948-11959","source":"Crossref","is-referenced-by-count":354,"title":["Synthesis of Aromatic Nitriles Using Nonmetallic Cyano\u2010Group Sources"],"prefix":"10.1002","volume":"51","author":[{"given":"Jinho","family":"Kim","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hyun Jin","family":"Kim","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sukbok","family":"Chang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2012,11,6]]},"reference":[{"key":"e_1_2_6_1_2","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","volume-title":"Pharmaceutical Substance: Synthesis Patents, Applications, 4th\u2005ed.","author":"Kleemann A.","year":"2001"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar0000354"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr020045d"},{"key":"e_1_2_6_5_2","unstructured":"\u00a0"},{"key":"e_1_2_6_6_2","volume-title":"Chemistry of the Cyano Group","author":"Rappoport Z.","year":"1970"},{"key":"e_1_2_6_7_2","volume-title":"Comprehensive Organic Transformations: A Guide to Functional Group Preparations","author":"Larock R. 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