{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,4]],"date-time":"2026-09-04T09:50:34Z","timestamp":1788515434783,"version":"build-2803163510"},"reference-count":28,"publisher":"Wiley","issue":"47","license":[{"start":{"date-parts":[[2013,10,2]],"date-time":"2013-10-02T00:00:00Z","timestamp":1380672000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2013,11,18]]},"DOI":"10.1002\/anie.201305291","type":"journal-article","created":{"date-parts":[[2013,10,4]],"date-time":"2013-10-04T09:42:04Z","timestamp":1380879724000},"page":"12283-12287","source":"Crossref","is-referenced-by-count":65,"title":["Characterization of a High\u2010Spin Non\u2010Heme {FeNO}<sup>8<\/sup> Complex: Implications for the Reactivity of Iron Nitroxyl Species in Biology"],"prefix":"10.1002","volume":"52","author":[{"given":"Amy L.","family":"Speelman","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nicolai","family":"Lehnert","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2013,10,2]]},"reference":[{"key":"e_1_2_2_1_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2004.08.010"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(00)80259-3"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja994079n"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2012.05.007"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1039\/b710047g"},{"key":"e_1_2_2_6_2","unstructured":"\u00a0"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00355a014"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00008a028"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja905062w"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic400977h"},{"key":"e_1_2_2_11_2","doi-asserted-by":"publisher","DOI":"10.1039\/C1SC00582K"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja030645"},{"key":"e_1_2_2_13_2","unstructured":"Experimental details for the acquisition of crystal data and structure refinement can be found in the Supporting Information. CCDC\u2005945365 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre viawww.ccdc.cam.ac.uk\/data_request\/cif."},{"key":"e_1_2_2_14_2","unstructured":"\u00a0"},{"key":"e_1_2_2_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic102094d"},{"key":"e_1_2_2_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja100366c"},{"key":"e_1_2_2_17_2","doi-asserted-by":"publisher","DOI":"10.1002\/1099-0682(200108)2001:8<1937::AID-EJIC1937>3.0.CO;2-I"},{"key":"e_1_2_2_18_2","unstructured":"As noted previously [10a]the large\u03c4\u2005value (>1) presumably arises from the 0.364\u2005\u00c5 displacement of the Fe center from the mean plane defined by the equatorial nitrogen atoms."},{"key":"e_1_2_2_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic990070a"},{"key":"e_1_2_2_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja111693f"},{"key":"e_1_2_2_21_2","doi-asserted-by":"publisher","DOI":"10.1039\/dt9870000187"},{"key":"e_1_2_2_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic102300d"},{"key":"e_1_2_2_23_2","unstructured":"The parent complex [Fe(TMG3tren)(CH3CN)]2+shows only an irreversible reductive event at approximately \u22122.5\u2005V versus ferrocene [10c]which indicates that the reduction of1is not ligand\u2010based. This conclusion is supported by DFT calculations which show only a small change in spin density on the ligand in2as compared to1(see Table\u2005S3 in the Supporting Information). Rather the splitting in the ligand bands is indicative of changes in the covalency of the iron\u2013TMG3tren unit."},{"key":"e_1_2_2_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00107a015"},{"key":"e_1_2_2_25_2","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.20400"},{"key":"e_1_2_2_26_2","unstructured":"No experimental pKa\u2005values for biological {FeHNO}8\u2010type complexes have been reported; however DFT calculations suggest that2is less basic than the corresponding low\u2010spin (heme) complexes (see the Supporting Information)."},{"key":"e_1_2_2_27_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja909715g"},{"key":"e_1_2_2_28_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja309782m"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fanie.201305291","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.201305291","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,10,16]],"date-time":"2023-10-16T18:47:13Z","timestamp":1697482033000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201305291"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2013,10,2]]},"references-count":28,"journal-issue":{"issue":"47","published-print":{"date-parts":[[2013,11,18]]}},"alternative-id":["10.1002\/anie.201305291"],"URL":"https:\/\/doi.org\/10.1002\/anie.201305291","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2013,10,2]]}}}