{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,28]],"date-time":"2026-03-28T04:59:05Z","timestamp":1774673945188,"version":"3.50.1"},"reference-count":55,"publisher":"Wiley","issue":"9","license":[{"start":{"date-parts":[[2014,2,20]],"date-time":"2014-02-20T00:00:00Z","timestamp":1392854400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2014,2,24]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Phosphorus nitride imide, PN(NH), is of great scientific importance because it is isosteric with silica (SiO<jats:sub>2<\/jats:sub>). Accordingly, a varied structural diversity could be expected. However, only one polymorph of PN(NH) has been reported thus far. Herein, we report on the synthesis and structural investigation of the first high\u2010pressure polymorph of phosphorus nitride imide, \u03b2\u2010PN(NH); the compound has been synthesized using the multianvil technique. By adding catalytic amounts of NH<jats:sub>4<\/jats:sub>Cl as a mineralizer, it became possible to grow single crystals of \u03b2\u2010PN(NH), which allowed the first complete structural elucidation of a highly condensed phosphorus nitride from single\u2010crystal X\u2010ray diffraction data. The structure was confirmed by FTIR and <jats:sup>31<\/jats:sup>P and <jats:sup>1<\/jats:sup>H solid\u2010state NMR spectroscopy. We are confident that high\u2010pressure\/high\u2010temperature reactions could lead to new polymorphs of PN(NH) containing five\u2010fold\u2010 or even six\u2010fold\u2010coordinated phosphorus atoms and thus rivalling or even surpassing the structural variety of SiO<jats:sub>2<\/jats:sub>.<\/jats:p>","DOI":"10.1002\/anie.201309020","type":"journal-article","created":{"date-parts":[[2014,2,22]],"date-time":"2014-02-22T04:55:29Z","timestamp":1393044929000},"page":"2469-2472","source":"Crossref","is-referenced-by-count":46,"title":["A High\u2010Pressure Polymorph of Phosphorus Nitride Imide"],"prefix":"10.1002","volume":"53","author":[{"given":"Alexey","family":"Marchuk","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Florian J.","family":"Pucher","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Friedrich W.","family":"Karau","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Wolfgang","family":"Schnick","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2014,2,20]]},"reference":[{"key":"e_1_2_2_1_2","doi-asserted-by":"publisher","DOI":"10.1515\/9783110177701"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1007\/978-3-642-50076-3"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201005755"},{"key":"e_1_2_2_3_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201005755"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3757(19990614)111:12<1845::AID-ANGE1845>3.0.CO;2-4"},{"key":"e_1_2_2_4_3","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3773(19990614)38:12<1733::AID-ANIE1733>3.0.CO;2-5"},{"key":"e_1_2_2_5_2","first-page":"1","volume":"29","author":"Heaney P. 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J.","year":"1997","journal-title":"Eur. J. Solid State Chem."},{"key":"e_1_2_2_31_2","unstructured":"\u00a0"},{"key":"e_1_2_2_32_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.1684753"},{"key":"e_1_2_2_33_2","first-page":"1020","volume":"75","author":"Walker D.","year":"1990","journal-title":"Am. Mineral."},{"key":"e_1_2_2_34_2","first-page":"1092","volume":"76","author":"Walker D.","year":"1991","journal-title":"Am. Mineral."},{"key":"e_1_2_2_35_2","doi-asserted-by":"publisher","DOI":"10.1080\/01411599908224526"},{"key":"e_1_2_2_36_2","doi-asserted-by":"publisher","DOI":"10.1524\/zkri.219.6.330.34633"},{"key":"e_1_2_2_37_2","unstructured":"Crystal structure data for \u03b2\u2010PN(NH): STOE IPDS MoK\u03b1(71.073\u2005pm) 2\u03b8max=63.4\u00b0 crystal size 0.11\u00d70.07\u00d70.02\u2005mm3 monoclinic space groupP2\/c(no. 13) a=788.5(2) b=482.2(1) c=814.6(2)\u2005pm \u03b2=108.19(3)\u00b0 V=0.2946(1)\u2005nm3 Z=8 \u03c1calcd=2.706\u2005g\u2009cm\u22123 \u03bcMoK\u03b1=1.222\u2005mm\u22121 2371 measured reflections 676 of which are independent Rint=0.049 least\u2010squares refinement onF2(G.\u2005M. Sheldrick SHELXL\u201097 program for the refinement of crystal structures Universit\u00e4t G\u00f6ttingen G\u00f6ttingen (Deutschland) 1997); no absorption correction R\u2010values (all data\/Fo2\u22652\u03c3(Fo2))R1=0.0392\/0.0298 wR2=0.0785\/0.0762 GooF=1.018 for 534 observed reflections (Fo2\u22652\u03c3(Fo2)) and 64 refined parameters. Further details on crystal structure investigations may be obtained from the Fachinformationszentrum Karlsruhe 76344 Eggenstein\u2010Leopoldshafen Germany (fax: (+49)\u20097247\u2010808\u2010666; e\u2010mail: crysdata@fiz\u2010karlsruhe.de) on quoting the depository number CSD\u2010426003."},{"key":"e_1_2_2_38_2","first-page":"9","volume":"79","author":"Downs R. T.","year":"1994","journal-title":"Am. 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