{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T19:43:54Z","timestamp":1791402234020,"version":"4.3.3"},"reference-count":80,"publisher":"Wiley","issue":"6","license":[{"start":{"date-parts":[[2014,1,22]],"date-time":"2014-01-22T00:00:00Z","timestamp":1390348800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2014,2,3]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The synthesis of structurally well\u2010defined, monodisperse carbon nanotube (CNT) sidewall segments poses a challenge in materials science. The synthesis of polyphenylene cylinders that comprise typical benzene connectivity to resemble precursors of [9,9] and [15,15]\u2005CNTs is now reported, and the products were characterized by X\u2010ray crystallography. To investigate the oxidative cyclodehydrogenation of ring\u2010strained molecules as a final step towards a bottom\u2010up synthesis of CNT sidewall segments, phenylene\u2010extended cyclic <jats:italic>p<\/jats:italic>\u2010hexaphenylbenzene trimers ([3]CHPB) were prepared, and NMR studies revealed a strain\u2010induced 1,2\u2010phenyl shift. It was further shown that an increase in ring size leads to selectively dehydrogenated macrocycles. Larger homologues are envisioned to give smooth condensation reactions toward graphenic sidewalls and should be used in the future as seeds for CNT formation.<\/jats:p>","DOI":"10.1002\/anie.201309104","type":"journal-article","created":{"date-parts":[[2014,1,22]],"date-time":"2014-01-22T16:32:04Z","timestamp":1390408324000},"page":"1525-1528","source":"Crossref","is-referenced-by-count":151,"title":["Concise Synthesis of 3D \u03c0\u2010Extended Polyphenylene Cylinders"],"prefix":"10.1002","volume":"53","author":[{"given":"Florian E.","family":"Golling","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Martin","family":"Quernheim","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Manfred","family":"Wagner","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tomohiko","family":"Nishiuchi","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Klaus","family":"M\u00fcllen","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2014,1,22]]},"reference":[{"key":"e_1_2_2_1_2","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr990322p"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1097789"},{"key":"e_1_2_2_4_2","first-page":"554","volume":"22","author":"Pisula W.","year":"2010","journal-title":"Chem. Mater."},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1102896"},{"key":"e_1_2_2_6_2","unstructured":"\u00a0"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3757(19981002)110:19<2843::AID-ANGE2843>3.0.CO;2-0"},{"key":"e_1_2_2_7_3","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3773(19981016)37:19<2696::AID-ANIE2696>3.0.CO;2-E"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201006593"},{"key":"e_1_2_2_8_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201006593"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/ma901142g"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja307697j"},{"key":"e_1_2_2_11_2","unstructured":"\u00a0"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19971091507"},{"key":"e_1_2_2_12_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199716041"},{"key":"e_1_2_2_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja017394u"},{"key":"e_1_2_2_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja056782j"},{"key":"e_1_2_2_15_2","doi-asserted-by":"publisher","DOI":"10.1038\/nmat2427"},{"key":"e_1_2_2_16_2","unstructured":"\u00a0"},{"key":"e_1_2_2_17_2","doi-asserted-by":"publisher","DOI":"10.1039\/b906026j"},{"key":"e_1_2_2_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201210238"},{"key":"e_1_2_2_18_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201210238"},{"key":"e_1_2_2_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja062026h"},{"key":"e_1_2_2_20_2","doi-asserted-by":"publisher","DOI":"10.1039\/b516264e"},{"key":"e_1_2_2_21_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1704"},{"key":"e_1_2_2_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja407842z"},{"key":"e_1_2_2_23_2","unstructured":"\u00a0"},{"key":"e_1_2_2_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr050554q"},{"key":"e_1_2_2_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr050553y"},{"key":"e_1_2_2_26_2","unstructured":"\u00a0"},{"key":"e_1_2_2_27_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja807126u"},{"key":"e_1_2_2_28_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200902617"},{"key":"e_1_2_2_28_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200902617"},{"key":"e_1_2_2_29_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201005734"},{"key":"e_1_2_2_29_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201005734"},{"key":"e_1_2_2_30_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200905659"},{"key":"e_1_2_2_30_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200905659"},{"key":"e_1_2_2_31_2","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms1505"},{"key":"e_1_2_2_32_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja2020668"},{"key":"e_1_2_2_33_2","doi-asserted-by":"publisher","DOI":"10.1246\/cl.2011.423"},{"key":"e_1_2_2_34_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo301024g"},{"key":"e_1_2_2_35_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201108167"},{"key":"e_1_2_2_35_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201108167"},{"key":"e_1_2_2_36_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja300001g"},{"key":"e_1_2_2_37_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja305723j"},{"key":"e_1_2_2_38_2","doi-asserted-by":"publisher","DOI":"10.1002\/asia.201200187"},{"key":"e_1_2_2_39_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3sc50645b"},{"key":"e_1_2_2_40_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3sc22181d"},{"key":"e_1_2_2_41_2","unstructured":"\u00a0"},{"key":"e_1_2_2_42_2","volume-title":"Fragments of Fullerenes and Carbon Nanotubes","year":"2011"},{"key":"e_1_2_2_43_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00820a058"},{"key":"e_1_2_2_44_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19870990926"},{"key":"e_1_2_2_44_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198708921"},{"key":"e_1_2_2_45_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19891011215"},{"key":"e_1_2_2_45_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198916801"},{"key":"e_1_2_2_46_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19961082227"},{"key":"e_1_2_2_46_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199626691"},{"key":"e_1_2_2_47_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cplett.2010.04.067"},{"key":"e_1_2_2_48_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja305769v"},{"key":"e_1_2_2_49_2","unstructured":"\u00a0"},{"key":"e_1_2_2_50_2","doi-asserted-by":"publisher","DOI":"10.1021\/nl1010178"},{"key":"e_1_2_2_51_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1655"},{"key":"e_1_2_2_52_2","unstructured":"\u00a0"},{"key":"e_1_2_2_53_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja209461g"},{"key":"e_1_2_2_54_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja907802g"},{"key":"e_1_2_2_55_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201203227"},{"key":"e_1_2_2_56_2","doi-asserted-by":"publisher","DOI":"10.1039\/b413842b"},{"key":"e_1_2_2_57_2","unstructured":"CCDC\u2005966737 (4) and 966738 (9) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre viawww.ccdc.cam.ac.uk\/data_request\/cif."},{"key":"e_1_2_2_58_2","unstructured":"\u00a0"},{"key":"e_1_2_2_59_2","doi-asserted-by":"publisher","DOI":"10.1039\/b922175a"},{"key":"e_1_2_2_60_2","doi-asserted-by":"publisher","DOI":"10.1021\/jz3014826"},{"key":"e_1_2_2_61_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2cp42712e"},{"key":"e_1_2_2_62_2","unstructured":"\u00a0"},{"key":"e_1_2_2_63_2","doi-asserted-by":"publisher","DOI":"10.1002\/jlac.19123940202"},{"key":"e_1_2_2_64_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo0526744"},{"key":"e_1_2_2_65_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol901331p"},{"key":"e_1_2_2_66_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2cc33892k"},{"key":"e_1_2_2_67_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja309599m"},{"key":"e_1_2_2_68_2","doi-asserted-by":"publisher","DOI":"10.1246\/cl.130153"},{"key":"e_1_2_2_69_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3935(20010101)202:2<215::AID-MACP215>3.0.CO;2-T"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fanie.201309104","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.201309104","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,10,17]],"date-time":"2023-10-17T07:23:05Z","timestamp":1697527385000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201309104"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2014,1,22]]},"references-count":80,"journal-issue":{"issue":"6","published-print":{"date-parts":[[2014,2,3]]}},"alternative-id":["10.1002\/anie.201309104"],"URL":"https:\/\/doi.org\/10.1002\/anie.201309104","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2014,1,22]]}}}