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Reaction of the pnictogenboranes H<jats:sub>2<\/jats:sub>EBH<jats:sub>2<\/jats:sub>\u22c5NMe<jats:sub>3<\/jats:sub> (E=P, As) with monohalideboranes lead to the cationic chain compounds [Me<jats:sub>3<\/jats:sub>N\u22c5BH<jats:sub>2<\/jats:sub>EH<jats:sub>2<\/jats:sub>BH<jats:sub>2<\/jats:sub>\u22c5NMe<jats:sub>3<\/jats:sub>][X] (E=P, As; X=AlCl<jats:sub>4<\/jats:sub>, I) and [Me<jats:sub>3<\/jats:sub>N\u22c5BH<jats:sub>2<\/jats:sub>PH<jats:sub>2<\/jats:sub>BH<jats:sub>2<\/jats:sub>PH<jats:sub>2<\/jats:sub>BH<jats:sub>2<\/jats:sub>\u22c5NMe<jats:sub>3<\/jats:sub>][X] (X=I, VCl<jats:sub>4<\/jats:sub>(thf)<jats:sub>2<\/jats:sub>), respectively. All of the compounds have been characterized by X\u2010ray structure analysis, NMR spectroscopy, IR spectroscopy, and mass spectrometry. DFT calculations elucidate the reaction pathway, the high thermodynamic stability, the charge distribution within the chain and confirm the observed solid\u2010state structures.<\/jats:p>","DOI":"10.1002\/anie.201310519","type":"journal-article","created":{"date-parts":[[2014,3,3]],"date-time":"2014-03-03T18:28:38Z","timestamp":1393871318000},"page":"3727-3730","source":"Crossref","is-referenced-by-count":53,"title":["Cationic Chains of Phosphanyl\u2010 and Arsanylboranes"],"prefix":"10.1002","volume":"53","author":[{"given":"Christian","family":"Marquardt","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Christine","family":"Thoms","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Andreas","family":"Stauber","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"G\u00e1bor","family":"Bal\u00e1zs","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Michael","family":"Bodensteiner","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Manfred","family":"Scheer","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2014,3,3]]},"reference":[{"key":"e_1_2_2_1_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19820940706"},{"key":"e_1_2_2_1_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198204921"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19870990507"},{"key":"e_1_2_2_2_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198704191"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr00020a010"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr00029a005"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr00083a012"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3cc44571b"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/asia.200700229"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19810931125"},{"key":"e_1_2_2_8_3","first-page":"967","volume":"20","year":"1981","journal-title":"Angew. 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