{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,16]],"date-time":"2026-10-16T18:46:59Z","timestamp":1792176419407,"version":"4.4.0"},"reference-count":49,"publisher":"Wiley","issue":"18","license":[{"start":{"date-parts":[[2014,3,25]],"date-time":"2014-03-25T00:00:00Z","timestamp":1395705600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2014,4,25]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Main\u2010group\u2010element catalysts are a desirable alternative to transition\u2010metal catalysts because of natural abundance and cost. However, the examples are very limited. Catalytic cycles involving a redox process and E\u2010ligand cooperation (E=main\u2010group element), which are often found in catalytic cycles of transition\u2010metal catalysts, have not been reported. Herein theoretical investigations of a catalytic hydrogenation of azobenzene with ammonia\u2013borane using a trivalent phosphorus compound, which was experimentally proposed to occur through P<jats:sup>III<\/jats:sup>\/P<jats:sup>V<\/jats:sup> redox processes via an unusual pentavalent dihydridophosphorane, were performed. DFT and ONIOM(CCSD(T):MP2) calculations disclosed that this catalytic reaction occurs through a P\u2010O cooperation mechanism, which resembles the metal\u2010ligand cooperation mechanism of transition\u2010metal catalysts.<\/jats:p>","DOI":"10.1002\/anie.201311104","type":"journal-article","created":{"date-parts":[[2014,3,25]],"date-time":"2014-03-25T13:16:41Z","timestamp":1395753401000},"page":"4633-4637","source":"Crossref","is-referenced-by-count":70,"title":["Catalytic Transfer Hydrogenation by a Trivalent Phosphorus Compound: Phosphorus\u2010Ligand Cooperation Pathway or P<sup>III<\/sup>\/P<sup>V<\/sup> Redox Pathway?"],"prefix":"10.1002","volume":"53","author":[{"given":"Guixiang","family":"Zeng","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Satoshi","family":"Maeda","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tetsuya","family":"Taketsugu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shigeyoshi","family":"Sakaki","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2014,3,25]]},"reference":[{"key":"e_1_2_2_1_2","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature08634"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar2001759"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201108320"},{"key":"e_1_2_2_4_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201108320"},{"key":"e_1_2_2_5_2","unstructured":"\u00a0"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja053247a"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200805982"},{"key":"e_1_2_2_7_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200805982"},{"key":"e_1_2_2_8_2","unstructured":"\u00a0"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja808656t"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200805595"},{"key":"e_1_2_2_10_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200805595"},{"key":"e_1_2_2_11_2","unstructured":"\u00a0"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1749"},{"key":"e_1_2_2_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201200273"},{"key":"e_1_2_2_14_2","doi-asserted-by":"publisher","DOI":"10.1016\/B978-0-08-097774-4.00136-4"},{"key":"e_1_2_2_15_2","first-page":"1","volume-title":"Topics in Current Chem.: Frustrated Lewis Pairs I","author":"Stephan D. 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