{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,19]],"date-time":"2026-09-19T01:17:18Z","timestamp":1789780638698,"version":"4.0.1"},"reference-count":39,"publisher":"Wiley","issue":"29","license":[{"start":{"date-parts":[[2014,5,30]],"date-time":"2014-05-30T00:00:00Z","timestamp":1401408000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2014,7,14]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>A new and selective one\u2010step synthesis was developed for the first activation stage of white phosphorus by organic radicals. The reactions of NaCp<jats:sup>R<\/jats:sup> with P<jats:sub>4<\/jats:sub> in the presence of CuX or FeBr<jats:sub>3<\/jats:sub> leads to the clean formation of organic substituted P<jats:sub>4<\/jats:sub> butterfly compounds Cp<jats:sup>R<\/jats:sup><jats:sub>2<\/jats:sub>P<jats:sub>4<\/jats:sub> (Cp<jats:sup>R<\/jats:sup>: Cp<jats:sup>BIG<\/jats:sup>=C<jats:sub>5<\/jats:sub>(4\u2010<jats:italic>n<\/jats:italic>BuC<jats:sub>6<\/jats:sub>H<jats:sub>4<\/jats:sub>)<jats:sub>5<\/jats:sub> (<jats:bold>1\u2009a<\/jats:bold>), Cp\u2032\u2032\u2032=C<jats:sub>5<\/jats:sub>H<jats:sub>2<\/jats:sub><jats:italic>t<\/jats:italic>Bu<jats:sub>3<\/jats:sub> (<jats:bold>1\u2009b<\/jats:bold>), Cp*=C<jats:sub>5<\/jats:sub>Me<jats:sub>5<\/jats:sub> (<jats:bold>1\u2009c<\/jats:bold>) und Cp<jats:sup>4<jats:italic>i<\/jats:italic>Pr<\/jats:sup>=C<jats:sub>5<\/jats:sub>H<jats:italic>i<\/jats:italic>Pr<jats:sub>4<\/jats:sub> (<jats:bold>1\u2009d<\/jats:bold>)). The reaction proceeds via the activation of P<jats:sub>4<\/jats:sub> by Cp<jats:sup>R<\/jats:sup> radicals mediated by transition metals. The newly formed organic derivatives of P<jats:sub>4<\/jats:sub> have been comprehensively characterized by NMR spectroscopy and X\u2010ray crystallography.<\/jats:p>","DOI":"10.1002\/anie.201403295","type":"journal-article","created":{"date-parts":[[2014,5,30]],"date-time":"2014-05-30T21:30:10Z","timestamp":1401485410000},"page":"7639-7642","source":"Crossref","is-referenced-by-count":90,"title":["Selective Functionalization of P<sub>4<\/sub> by Metal\u2010Mediated C\uf8ffP Bond 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