{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T10:06:45Z","timestamp":1791194805745,"version":"4.1.0"},"reference-count":145,"publisher":"Wiley","issue":"29","license":[{"start":{"date-parts":[[2014,6,18]],"date-time":"2014-06-18T00:00:00Z","timestamp":1403049600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2014,7,14]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    A novel copper\u2010catalyzed one\u2010pot functionalization of homopropargylic alcohols that involves trifluoromethylation, aryl migration, and formation of a carbonyl moiety has been developed. This reaction constitutes the first direct conversion of homopropargylic alcohols into CF\n                    <jats:sub>3<\/jats:sub>\n                    \u2010containing 3\u2010butenal or 3\u2010buten\u20101\u2010one derivatives in a regioselective manner. Mechanistic studies indicate that the 1,4\u2010aryl migration proceeds through a radical pathway.\n                  <\/jats:p>","DOI":"10.1002\/anie.201403383","type":"journal-article","created":{"date-parts":[[2014,6,18]],"date-time":"2014-06-18T10:39:33Z","timestamp":1403087973000},"page":"7629-7633","source":"Crossref","is-referenced-by-count":151,"title":["Copper\u2010Catalyzed One\u2010Pot Trifluoromethylation\/Aryl Migration\/Carbonyl Formation with Homopropargylic Alcohols"],"prefix":"10.1002","volume":"53","author":[{"given":"Pin","family":"Gao","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yong\u2010Wen","family":"Shen","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ran","family":"Fang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xin\u2010Hua","family":"Hao","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zi\u2010Hang","family":"Qiu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fan","family":"Yang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiao\u2010Biao","family":"Yan","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qiang","family":"Wang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiang\u2010Jun","family":"Gong","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xue\u2010Yuan","family":"Liu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yong\u2010Min","family":"Liang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2014,6,18]]},"reference":[{"key":"e_1_2_3_1_2","unstructured":"\u00a0"},{"key":"e_1_2_3_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/352760393X"},{"key":"e_1_2_3_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200460441"},{"key":"e_1_2_3_3_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200460441"},{"key":"e_1_2_3_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200600449"},{"key":"e_1_2_3_4_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200600449"},{"key":"e_1_2_3_5_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1131943"},{"key":"e_1_2_3_6_2","doi-asserted-by":"publisher","DOI":"10.1039\/B610213C"},{"key":"e_1_2_3_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/jm800219f"},{"key":"e_1_2_3_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/9781444312096"},{"key":"e_1_2_3_9_2","first-page":"10","volume":"90","author":"Ritter S. 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