{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,2,5]],"date-time":"2026-02-05T13:22:42Z","timestamp":1770297762648,"version":"3.49.0"},"reference-count":44,"publisher":"Wiley","issue":"29","license":[{"start":{"date-parts":[[2014,6,4]],"date-time":"2014-06-04T00:00:00Z","timestamp":1401840000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2014,7,14]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Unprecedented functionalized products with an \u03b7<jats:sup>4<\/jats:sup>\u2010P<jats:sub>5<\/jats:sub> ring are obtained by the reaction of [Cp*Fe(\u03b7<jats:sup>5<\/jats:sup>\u2010P<jats:sub>5<\/jats:sub>)] (<jats:bold>1<\/jats:bold>; Cp*=\u03b7<jats:sup>5<\/jats:sup>\u2010C<jats:sub>5<\/jats:sub>Me<jats:sub>5<\/jats:sub>) with different nucleophiles. With LiCH<jats:sub>2<\/jats:sub>SiMe<jats:sub>3<\/jats:sub> and LiNMe<jats:sub>2<\/jats:sub>, the monoanionic products [Cp*Fe(\u03b7<jats:sup>4<\/jats:sup>\u2010P<jats:sub>5<\/jats:sub>CH<jats:sub>2<\/jats:sub>SiMe<jats:sub>3<\/jats:sub>)]<jats:sup>\u2212<\/jats:sup> and [Cp*Fe(\u03b7<jats:sup>4<\/jats:sup>\u2010P<jats:sub>5<\/jats:sub>NMe<jats:sub>2<\/jats:sub>)]<jats:sup>\u2212<\/jats:sup>, respectively, are formed. The reaction of <jats:bold>1<\/jats:bold> with NaNH<jats:sub>2<\/jats:sub> leads to the formation of the trianionic compound [{Cp*Fe(\u03b7<jats:sup>4<\/jats:sup>\u2010P<jats:sub>5<\/jats:sub>)}<jats:sub>2<\/jats:sub>N]<jats:sup>3\u2212<\/jats:sup>, whereas the reaction with LiPH<jats:sub>2<\/jats:sub> yields [Cp*Fe(\u03b7<jats:sup>4<\/jats:sup>\u2010P<jats:sub>5<\/jats:sub>PH<jats:sub>2<\/jats:sub>)]<jats:sup>\u2212<\/jats:sup> as the main product, with {[Cp*Fe(\u03b7<jats:sup>4<\/jats:sup>\u2010P<jats:sub>5<\/jats:sub>)]<jats:sub>2<\/jats:sub>PH}<jats:sup>2\u2212<\/jats:sup> as a byproduct. The calculated energy profile of the reactions provides a rationale for the formation of the different products.<\/jats:p>","DOI":"10.1002\/anie.201403581","type":"journal-article","created":{"date-parts":[[2014,6,4]],"date-time":"2014-06-04T08:33:31Z","timestamp":1401870811000},"page":"7643-7646","source":"Crossref","is-referenced-by-count":63,"title":["Functionalization of a <i>cyclo<\/i>\u2010P<sub>5<\/sub> Ligand by Main\u2010Group Element Nucleophiles"],"prefix":"10.1002","volume":"53","author":[{"given":"Eric","family":"M\u00e4dl","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mikhail V.","family":"Butovskii","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"G\u00e1bor","family":"Bal\u00e1zs","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Eugenia V.","family":"Peresypkina","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Alexander V.","family":"Virovets","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Michael","family":"Seidl","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Manfred","family":"Scheer","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2014,6,4]]},"reference":[{"key":"e_1_2_2_1_2","doi-asserted-by":"publisher","DOI":"10.1038\/1681039b0"},{"key":"e_1_2_2_2_2","unstructured":"\u00a0"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja01133a543"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja01644a047"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/9780470985663.ch10"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200602482"},{"key":"e_1_2_2_6_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200602482"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/aoc.1202"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(00)81725-8"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(00)94710-5"},{"key":"e_1_2_2_10_2","first-page":"59","volume":"99","author":"Scherer J.","year":"1987","journal-title":"Angew. 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