{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T21:05:36Z","timestamp":1792011936958,"version":"4.4.0"},"reference-count":64,"publisher":"Wiley","issue":"33","license":[{"start":{"date-parts":[[2014,6,11]],"date-time":"2014-06-11T00:00:00Z","timestamp":1402444800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/100005156","name":"Alexander von Humboldt Foundation","doi-asserted-by":"crossref","id":[{"id":"10.13039\/100005156","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2014,8,11]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Through catalytic hydrogen transfer reactions, a new biorefining method results in the isolation of depolymerized lignin\u2014a non\u2010pyrolytic lignin bio\u2010oil\u2014in addition to pulps that are amenable to enzymatic hydrolysis. Compared with organosolv lignin, the lignin bio\u2010oil is highly susceptible to further hydrodeoxygenation under low\u2010severity conditions and therefore establishes a unique platform for lignin valorization by heterogeneous catalysis. Overall, the potential of a catalytic biorefining method designed from the perspective of lignin utilization is reported.<\/jats:p>","DOI":"10.1002\/anie.201403747","type":"journal-article","created":{"date-parts":[[2014,6,11]],"date-time":"2014-06-11T12:59:06Z","timestamp":1402491546000},"page":"8634-8639","source":"Crossref","is-referenced-by-count":425,"title":["Catalytic Biorefining of Plant Biomass to Non\u2010Pyrolytic Lignin Bio\u2010Oil and Carbohydrates through Hydrogen Transfer Reactions"],"prefix":"10.1002","volume":"53","author":[{"given":"Paola","family":"Ferrini","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Roberto","family":"Rinaldi","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2014,6,11]]},"reference":[{"key":"e_1_2_2_1_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1218930"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr900354u"},{"key":"e_1_2_2_3_2","unstructured":"\u00a0"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201107020"},{"key":"e_1_2_2_4_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201107020"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja106101f"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201305342"},{"key":"e_1_2_2_6_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201305342"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201001293"},{"key":"e_1_2_2_7_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201001293"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1200437"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1515\/HF.2009.097"},{"key":"e_1_2_2_10_2","unstructured":"\u00a0"},{"key":"e_1_2_2_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja4119412"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja3085912"},{"key":"e_1_2_2_13_2","doi-asserted-by":"publisher","DOI":"10.1039\/C3GC42138D"},{"key":"e_1_2_2_14_2","unstructured":"\u00a0"},{"key":"e_1_2_2_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201200040"},{"key":"e_1_2_2_16_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2013.09.009"},{"key":"e_1_2_2_17_2","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201000299"},{"key":"e_1_2_2_18_2","unstructured":"\u00a0"},{"key":"e_1_2_2_19_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201108306"},{"key":"e_1_2_2_19_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201108306"},{"key":"e_1_2_2_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja309915e"},{"key":"e_1_2_2_21_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200900404"},{"key":"e_1_2_2_21_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200900404"},{"key":"e_1_2_2_22_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3gc41150h"},{"key":"e_1_2_2_23_2","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201100699"},{"key":"e_1_2_2_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201304776"},{"key":"e_1_2_2_24_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201304776"},{"key":"e_1_2_2_25_2","unstructured":"R. Rinaldi P. Ferrini European patent application pending 2014."},{"key":"e_1_2_2_26_2","unstructured":"\u00a0"},{"key":"e_1_2_2_27_2","doi-asserted-by":"publisher","DOI":"10.1002\/bit.20453"},{"key":"e_1_2_2_28_2","doi-asserted-by":"publisher","DOI":"10.1007\/s00253-009-1883-1"},{"key":"e_1_2_2_29_2","unstructured":"We chose 2\u2010PrOH as a solvent and a hydrogen donor because primary alcohols (e.g. methanol and ethanol) were found to deactivate Raney Ni when used as the solvent and hydrogen donor. Interestingly in the presence of 2\u2010PrOH methanol (at concentrations as high as 10\u2005vol\u2009%) partially inhibits Raney Ni. However the catalyst is not deactivated. For further information see Ref.\u2005[13]."},{"key":"e_1_2_2_30_2","unstructured":"For the catalytic biorefining of poplar wood in the presence of Raney Ni in 2\u2010PrOH\/water (7:3 v\/v) at 180\u2009\u00b0C approximately 5\u2005mol\u2009% of the 2\u2010PrOH content were converted into acetone. This value corresponds to about 5\u2005mol of acetone per kg of poplar wood."},{"key":"e_1_2_2_31_2","unstructured":"\u00a0"},{"key":"e_1_2_2_32_2","first-page":"169","volume":"72","author":"Aziz S.","year":"1989","journal-title":"Tappi J."},{"key":"e_1_2_2_33_2","doi-asserted-by":"publisher","DOI":"10.15376\/biores.8.1.1456-1477"},{"key":"e_1_2_2_34_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.carres.2012.07.017"},{"key":"e_1_2_2_35_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2ee21855k"},{"key":"e_1_2_2_36_2","unstructured":"\u00a0"},{"key":"e_1_2_2_37_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1246748"},{"key":"e_1_2_2_38_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201104123"},{"key":"e_1_2_2_38_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201104123"},{"key":"e_1_2_2_39_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4GC00168K"},{"key":"e_1_2_2_40_2","unstructured":"M. K\u00e4ldstr\u00f6m N. Meine C. Fares F. Sch\u00fcth R. Rinaldi Green Chem.\u00ad2014 DOI:;"},{"key":"e_1_2_2_41_2","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201100770"},{"key":"e_1_2_2_42_2","unstructured":"F. Sch\u00fcth R. Rinaldi N. Meine M. K\u00e4ldstr\u00f6m J. Hilgert M.\u2005D.\u2005K. Rechulski Catal. Today\u00ad2014 DOI:."},{"key":"e_1_2_2_43_2","unstructured":"\u00a0"},{"key":"e_1_2_2_44_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja029035k"},{"key":"e_1_2_2_45_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja1095304"},{"key":"e_1_2_2_46_2","doi-asserted-by":"publisher","DOI":"10.1021\/ac303529v"},{"key":"e_1_2_2_47_2","doi-asserted-by":"publisher","DOI":"10.1038\/nprot.2012.064"},{"key":"e_1_2_2_48_2","doi-asserted-by":"publisher","DOI":"10.1201\/EBK1574444865-c5"},{"key":"e_1_2_2_49_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2011.04.021"},{"key":"e_1_2_2_50_2","doi-asserted-by":"publisher","DOI":"10.3390\/ma6010359"},{"key":"e_1_2_2_51_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3gc36958g"},{"key":"e_1_2_2_52_2","unstructured":"\u00a0"},{"key":"e_1_2_2_53_2","doi-asserted-by":"publisher","DOI":"10.1039\/C0EE00341G"},{"key":"e_1_2_2_54_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201107390"},{"key":"e_1_2_2_54_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201107390"},{"key":"e_1_2_2_55_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201205230"},{"key":"e_1_2_2_55_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201205230"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fanie.201403747","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.201403747","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,10,17]],"date-time":"2023-10-17T07:14:02Z","timestamp":1697526842000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201403747"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2014,6,11]]},"references-count":64,"journal-issue":{"issue":"33","published-print":{"date-parts":[[2014,8,11]]}},"alternative-id":["10.1002\/anie.201403747"],"URL":"https:\/\/doi.org\/10.1002\/anie.201403747","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2014,6,11]]}}}