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Powder neutron and synchrotron X\u2010ray diffraction revealed that this compound adopts the ideal cubic perovskite structure <jats:styled-content>${\\left( {Pm\\bar 3m} \\right)}$<jats:inline-graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" xlink:href=\"graphic\/tex2gif-ueqn-1.gif\" xlink:title=\"equation image\"\/><\/jats:styled-content> with O<jats:sup>2\u2212<\/jats:sup>\/H<jats:sup>\u2212<\/jats:sup> disorder. Surprisingly, despite the non\u2010bonding nature between Cr\u20053d\u2005t<jats:sub>2g<\/jats:sub> orbitals and the H\u20051s orbital, it exhibits G\u2010type spin ordering at T<jats:sub>N<\/jats:sub>\u2248380\u2005K, which is higher than that of RCrO<jats:sub>3<\/jats:sub> (R=rare earth) and any chromium oxides. The enhanced <jats:italic>T<\/jats:italic><jats:sub>N<\/jats:sub> in SrCrO<jats:sub>2<\/jats:sub>H with four Cr\u2010O\u2010Cr bonds in comparison with RCr<jats:sup>3+<\/jats:sup>O<jats:sub>3<\/jats:sub> with six Cr\u2010O\u2010Cr bonds is reasonably explained by the tolerance factor. The present result offers an effective strategy to tune octahedral tilting in perovskites and to improve physical and chemical properties through mixed anion chemistry.<\/jats:p>","DOI":"10.1002\/anie.201405453","type":"journal-article","created":{"date-parts":[[2014,8,12]],"date-time":"2014-08-12T20:35:23Z","timestamp":1407875723000},"page":"10377-10380","source":"Crossref","is-referenced-by-count":96,"title":["Direct Synthesis of Chromium Perovskite Oxyhydride with a High Magnetic\u2010Transition Temperature"],"prefix":"10.1002","volume":"53","author":[{"given":"C\u00e9dric","family":"Tassel","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yoshihiro","family":"Goto","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yoshinori","family":"Kuno","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"James","family":"Hester","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mark","family":"Green","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yoji","family":"Kobayashi","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hiroshi","family":"Kageyama","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2014,8,12]]},"reference":[{"key":"e_1_2_3_1_2","doi-asserted-by":"publisher","DOI":"10.1142\/3605"},{"key":"e_1_2_3_2_2","doi-asserted-by":"publisher","DOI":"10.1038\/nnano.2013.192"},{"key":"e_1_2_3_3_2","doi-asserted-by":"publisher","DOI":"10.1038\/332814a0"},{"key":"e_1_2_3_4_2","doi-asserted-by":"publisher","DOI":"10.1038\/35010082"},{"key":"e_1_2_3_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp025961"},{"key":"e_1_2_3_6_2","unstructured":"\u00a0"},{"key":"e_1_2_3_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm034756j"},{"key":"e_1_2_3_8_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jeurceramsoc.2011.12.001"},{"key":"e_1_2_3_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm803322d"},{"key":"e_1_2_3_10_2","unstructured":"\u00a0"},{"key":"e_1_2_3_11_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-4596(84)90226-3"},{"key":"e_1_2_3_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic971339y"},{"key":"e_1_2_3_13_2","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms1913"},{"key":"e_1_2_3_14_2","unstructured":"\u00a0"},{"key":"e_1_2_3_15_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1068321"},{"key":"e_1_2_3_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic101613b"},{"key":"e_1_2_3_17_2","doi-asserted-by":"publisher","DOI":"10.1038\/nmat3302"},{"key":"e_1_2_3_18_2","unstructured":"\u00a0"},{"key":"e_1_2_3_19_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature06382"},{"key":"e_1_2_3_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja991573i"},{"key":"e_1_2_3_21_2","unstructured":"\u00a0"},{"key":"e_1_2_3_22_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.253.5018.421"},{"key":"e_1_2_3_23_2","doi-asserted-by":"publisher","DOI":"10.1143\/JPSJ.81.034704"},{"key":"e_1_2_3_24_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.4794067"},{"key":"e_1_2_3_25_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jnucmat.2012.01.001"},{"key":"e_1_2_3_26_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201206203"},{"key":"e_1_2_3_26_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201206203"},{"key":"e_1_2_3_27_2","doi-asserted-by":"publisher","DOI":"10.1016\/0038-1098(67)90088-9"},{"key":"e_1_2_3_28_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.actamat.2005.04.001"},{"key":"e_1_2_3_29_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.1708325"},{"key":"e_1_2_3_30_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm800375d"},{"key":"e_1_2_3_31_2","unstructured":"\u00a0"},{"key":"e_1_2_3_32_2","first-page":"1000","volume":"102","author":"McGuire T. 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