{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,28]],"date-time":"2026-09-28T17:31:52Z","timestamp":1790616712505,"version":"4.1.0"},"reference-count":45,"publisher":"Wiley","issue":"48","license":[{"start":{"date-parts":[[2014,9,26]],"date-time":"2014-09-26T00:00:00Z","timestamp":1411689600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2014,11,24]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Chlorosilicates represent important intermediates in S<jats:sub>N<\/jats:sub>2 reactions of chlorosilanes. They can be stabilized by the introduction of electron\u2010withdrawing substituents. Salts of various (pentafluoroethyl)chlorosilicates have been isolated and structurally characterized.<\/jats:p>","DOI":"10.1002\/anie.201406311","type":"journal-article","created":{"date-parts":[[2014,9,26]],"date-time":"2014-09-26T07:57:20Z","timestamp":1411718240000},"page":"13269-13272","source":"Crossref","is-referenced-by-count":32,"title":["Synthesis of Chlorosilicates"],"prefix":"10.1002","volume":"53","author":[{"given":"Simon","family":"Steinhauer","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tobias","family":"B\u00f6ttcher","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nico","family":"Schwarze","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Beate","family":"Neumann","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hans\u2010Georg","family":"Stammler","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Berthold","family":"Hoge","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2014,9,26]]},"reference":[{"key":"e_1_2_3_1_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo070076e"},{"key":"e_1_2_3_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.200890003"},{"key":"e_1_2_3_3_2","unstructured":"For example:"},{"key":"e_1_2_3_4_2","doi-asserted-by":"publisher","DOI":"10.1039\/c1dt10898k"},{"key":"e_1_2_3_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200700910"},{"key":"e_1_2_3_5_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200700910"},{"key":"e_1_2_3_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19951280307"},{"key":"e_1_2_3_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19905820125"},{"key":"e_1_2_3_8_2","unstructured":"\u00a0"},{"key":"e_1_2_3_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp300251t"},{"key":"e_1_2_3_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp040743x"},{"key":"e_1_2_3_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00087a050"},{"key":"e_1_2_3_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/j100057a007"},{"key":"e_1_2_3_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00337a011"},{"key":"e_1_2_3_14_2","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2614(81)80362-4"},{"key":"e_1_2_3_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19532730317"},{"key":"e_1_2_3_16_2","doi-asserted-by":"publisher","DOI":"10.1039\/j19690000859"},{"key":"e_1_2_3_17_2","unstructured":"\u00a0"},{"key":"e_1_2_3_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp040743x"},{"key":"e_1_2_3_19_2","doi-asserted-by":"publisher","DOI":"10.1016\/0168-1176(90)85130-T"},{"key":"e_1_2_3_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00290a005"},{"key":"e_1_2_3_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic50202a012"},{"key":"e_1_2_3_22_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-2860(92)80222-4"},{"key":"e_1_2_3_23_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(02)01856-9"},{"key":"e_1_2_3_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201402655"},{"key":"e_1_2_3_25_2","unstructured":"Chloride ion affinity is defined as the negative free enthalpy for the addition of the chloride ion to the Lewis acid with higher positive values indicating higher Lewis acidity. In Table\u20051 the free enthalpy of chloride addition is given for easier comparison with the solvation enthalpies."},{"key":"e_1_2_3_26_2","unstructured":"\u00a0"},{"key":"e_1_2_3_27_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19885630106"},{"key":"e_1_2_3_28_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1227859"},{"key":"e_1_2_3_29_2","unstructured":"Gaussian\u200903 Revision\u2009C.02 M.\u2005J. Frisch G.\u2005W. Trucks H.\u2005B. Schlegel G.\u2005E. Scuseria M.\u2005A. Robb J.\u2005R. Cheeseman J.\u2005A. Montgomery \u2005Jr. T. Vreven K.\u2005N. Kudin J.\u2005C. Burant J.\u2005M. Millam S.\u2005S. Iyengar J. Tomasi V. Barone B. Mennucci M. Cossi G. Scalmani N. Rega G.\u2005A. Petersson H. Nakatsuji M. Hada M. Ehara K. Toyota R. Fukuda J. Hasegawa M. Ishida T. Nakajima Y. Honda O. Kitao H. Nakai M. Klene X. Li J.\u2005E. Knox H.\u2005P. Hratchian J.\u2005B. Cross V. Bakken C. Adamo J. Jaramillo R. Gomperts R.\u2005E. Stratmann O. Yazyev A.\u2005J. Austin R. Cammi C. Pomelli J.\u2005W. Ochterski P.\u2005Y. Ayala K. Morokuma G.\u2005A. Voth P. Salvador J.\u2005J. Dannenberg V.\u2005G. Zakrzewski S. Dapprich A.\u2005D. Daniels M.\u2005C. Strain O. Farkas D.\u2005K. Malick A.\u2005D. Rabuck K. Raghavachari J.\u2005B. Foresman J.\u2005V. Ortiz Q. Cui A.\u2005G. Baboul S. Clifford J. Cioslowski B.\u2005B. Stefanov G. Liu A. Liashenko P. Piskorz I. Komaromi R.\u2005L. Martin D.\u2005J. Fox T. Keith M.\u2005A. Al\u2010Laham C.\u2005Y. Peng A. Nanayakkara M. Challacombe P.\u2005M.\u2005W. Gill B. Johnson W. Chen M.\u2005W. Wong C. Gonzalez and J.\u2005A. Pople Gaussian Inc. Wallingford CT 2004."},{"key":"e_1_2_3_30_2","unstructured":"Chloride ion affinity is given for [Si(CF3)3Cl2]\u2212with two axial CF3groups. The conformer with two axial chlorine atoms is calculated to be 9.8\u2005kJ\u2009mol\u22121less stable. Details on the relative energy of the conformers of all (trifluoromethyl)chlorosilicates are given in the Supporting Information. The difference in the structure in the crystal of [PNP][Si(C2F5)3Cl2] might be due to the higher steric demand of the C2F5group."},{"key":"e_1_2_3_31_2","first-page":"65","volume-title":"NMR Basic Principles and Progress","author":"Marsmann H.","year":"1981"},{"key":"e_1_2_3_32_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201308059"},{"key":"e_1_2_3_32_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201308059"},{"key":"e_1_2_3_33_2","unstructured":"\u00a0"},{"key":"e_1_2_3_34_2","doi-asserted-by":"publisher","DOI":"10.1039\/c4cc02583k"},{"key":"e_1_2_3_35_2","unstructured":"CCDC\u2005965803 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre viawww.ccdc.cam.ac.uk\/data_request\/cif."},{"key":"e_1_2_3_36_2","doi-asserted-by":"publisher","DOI":"10.1107\/S0108767307043930"},{"key":"e_1_2_3_36_3","unstructured":"CCDC\u20051006707 and 1006708 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre viawww.ccdc.cam.ac.uk\/data_request\/cif."},{"key":"e_1_2_3_37_2","unstructured":"\u00a0"},{"key":"e_1_2_3_38_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201400291"},{"key":"e_1_2_3_38_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201400291"},{"key":"e_1_2_3_39_2","unstructured":"B. Hoge S. Steinhauer J. Bader N. Ignat\u2019ev 20th Symposium on Fluorine Chemistry Kyoto Japan 2012;"},{"key":"e_1_2_3_40_2","unstructured":"B. Hoge S. Steinhauer and N. Ignat\u2019ev 6th European Silicon Days Lyon France 2012;"},{"key":"e_1_2_3_41_2","unstructured":"N. Schwarze B. Kurscheid S. Steinhauer B. Neumann H.\u2010G. Stammler N. Ignat\u2019ev B. Hoge in preparation."}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fanie.201406311","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.201406311","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,10,16]],"date-time":"2023-10-16T20:06:13Z","timestamp":1697486773000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201406311"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2014,9,26]]},"references-count":45,"journal-issue":{"issue":"48","published-print":{"date-parts":[[2014,11,24]]}},"alternative-id":["10.1002\/anie.201406311"],"URL":"https:\/\/doi.org\/10.1002\/anie.201406311","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2014,9,26]]}}}