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The catalytic efficiency under 100\u2005mW\u2009cm<jats:sup>\u22122<\/jats:sup> full\u2010spectrum irradiation at room temperature turns out to be comparable to that of thermally (70\u2009\u00b0C) driven reactions. The yields obtained with other Pd nanocrystals, such as nanocubes and octahedrons, are lower. The nanostructures reported here have sufficient plasmonic cross\u2010sections for light harvesting in a broad spectral range owing to the reduced shape symmetry, which increases the solution temperature for the reaction by the photothermal effect. They possess a large quantity of atoms at corners and edges where local heat is more efficiently generated, thus providing active sites for the reaction. Taken together, these factors drastically enhance the hydrogenation reaction by light illumination.<\/jats:p>","DOI":"10.1002\/anie.201407785","type":"journal-article","created":{"date-parts":[[2014,10,19]],"date-time":"2014-10-19T22:51:43Z","timestamp":1413759103000},"page":"2425-2430","source":"Crossref","is-referenced-by-count":99,"title":["Efficient Coupling of Solar Energy to Catalytic Hydrogenation by Using Well\u2010Designed Palladium Nanostructures"],"prefix":"10.1002","volume":"54","author":[{"given":"Ran","family":"Long","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhoulv","family":"Rao","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Keke","family":"Mao","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu","family":"Li","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chao","family":"Zhang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qiliang","family":"Liu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chengming","family":"Wang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhi\u2010Yuan","family":"Li","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaojun","family":"Wu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yujie","family":"Xiong","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2014,10,19]]},"reference":[{"key":"e_1_2_2_1_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr400609m"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1215864"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja038804c"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja058217m"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja109856y"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201308541"},{"key":"e_1_2_2_6_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201308541"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201107846"},{"key":"e_1_2_2_7_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201107846"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/nl0495256"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200603068"},{"key":"e_1_2_2_9_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200603068"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja311739v"},{"key":"e_1_2_2_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200800073"},{"key":"e_1_2_2_11_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200800073"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/nl0716000"},{"key":"e_1_2_2_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja204557m"},{"key":"e_1_2_2_14_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1032"},{"key":"e_1_2_2_15_2","doi-asserted-by":"publisher","DOI":"10.1038\/nmat3454"},{"key":"e_1_2_2_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja310501y"},{"key":"e_1_2_2_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja400527a"},{"key":"e_1_2_2_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/nl0508826"},{"key":"e_1_2_2_19_2","doi-asserted-by":"publisher","DOI":"10.1039\/C2EE02866B"},{"key":"e_1_2_2_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/cg8002433"},{"key":"e_1_2_2_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr100275d"},{"key":"e_1_2_2_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/smll.201200243"},{"key":"e_1_2_2_23_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201103002"},{"key":"e_1_2_2_23_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201103002"},{"key":"e_1_2_2_24_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3ta00478c"},{"key":"e_1_2_2_25_2","volume-title":"Handbook of X\u2010Ray Photoelectron Spectroscopy","author":"Wanger C. 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