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First, the lipophilic complex (dabco\u2010C<jats:sub>18<\/jats:sub>)[Mn(N)(CN)<jats:sub>4<\/jats:sub>(dabco\u2010C<jats:sub>18<\/jats:sub>)] (<jats:bold>1<\/jats:bold>; dabco\u2010C<jats:sub>18<\/jats:sub><jats:sup>+<\/jats:sup>=1,4\u2010diazabicyclo[2,2,2]octane\u2010(CH<jats:sub>2<\/jats:sub>)<jats:sub>17<\/jats:sub>\uf8ffCH<jats:sub>3<\/jats:sub> cation), was synthesized. <jats:bold>1<\/jats:bold> has a lipophilic alkyl tail part and a tetracyanometallate head group, which can be used for an expansion to two\u2010dimensional coordination networks. Second, <jats:bold>1<\/jats:bold> and 1,2\u2010dipalmitoyl\u2010<jats:italic>sn<\/jats:italic>\u2010glycero\u20103\u2010phosphocholine were mixed to prepare the liposomes. Finally, CPsomes were obtained by the addition of transition\u2010metal ions (<jats:bold>M<\/jats:bold>) to form unilamellar faceted liposomes with plain CP raft domains with Mn\uf8ffCN\uf8ff<jats:bold>M<\/jats:bold> linkages. The concentration of <jats:bold>1<\/jats:bold> influences the size of the CP raft domains and the shape of the CPsomes. The synthesis of coordination polymers in lipid bilayers is a novel approach for the construction of artificial architectures as raft domains, for example, in cell membranes.<\/jats:p>","DOI":"10.1002\/anie.201408101","type":"journal-article","created":{"date-parts":[[2014,12,7]],"date-time":"2014-12-07T15:43:33Z","timestamp":1417967013000},"page":"1139-1143","source":"Crossref","is-referenced-by-count":13,"title":["Sequential Synthesis of Coordination 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